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author:

Fan, Gongduan (Fan, Gongduan.) [1] (Scholars:范功端) | Luo, Jing (Luo, Jing.) [2] | Prieto, Israel de Jesus Lopez (Prieto, Israel de Jesus Lopez.) [3] | Lin, Rujing (Lin, Rujing.) [4] | Zheng, Xiaomei (Zheng, Xiaomei.) [5] | Hong, Liang (Hong, Liang.) [6]

Indexed by:

Scopus SCIE

Abstract:

The synthesis conditions of zeolitic imidazolate framework-8 (ZIF-8) have been optimized by a response surface method using central composite design (CCD) to obtain the high adsorption capability for the Pb(II) removal in aqueous solution. The physic-chemical properties of the as-prepared ZIF-8, such as morphology, structure and chemical composition, were characterized by field emission scanning electron microscopy (FE-SEM), powder X-ray diffraction (XRD) and energy-dispersive X-ray photoelectron spectroscopy (XPS), respectively. The adsorption capability, influence factors, isotherms, thermodynamics, kinetics and mechanism of Pb(II) in aqueous solutions were investigated. The optimal parameters of which have the highest adsorption capability for Pb(II) were 200 mL of water as the solvent, and the molar mass ratio of 2-methylimidazole and Zn(NO3)(2)center dot 6H(2)O was 45.63. At this condition, the as-prepared ZIF-8 was a pure hexagonal three-dimensional crystal structure. The equilibrium adsorption capacity up to 668 mg/g for 300 mg/L of initial Pb(II) solutions and the adsorption was a spontaneous process. The largest adsorption capacity from Langmuir isotherm model was 686.25 mg/g. The adsorption kinetics followed the pseudo-second-order model. The equilibrium adsorption time and the optimal adsorption pH was 4 h and 6.0-7.0, respectively. The ZIF-8 still kept well adsorption effect after three times of usage. Therefore, this study showed that ZIF-8 is a promising sorbent for removing environmental pollutants.

Keyword:

Adsorption capability Influence factor Lead Response surface methodology Zeolitic imidazolate framework-8 (ZIF-8)

Community:

  • [ 1 ] [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Luo, Jing]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Lin, Rujing]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Zheng, Xiaomei]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Hong, Liang]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Fan, Gongduan]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Fan, Gongduan]Univ Arizona, Dept Chem & Environm Engn, 1133 E James E Rogers Way,Harshbarger 108, Tucson, AZ 85721 USA
  • [ 8 ] [Prieto, Israel de Jesus Lopez]Univ Arizona, Dept Chem & Environm Engn, 1133 E James E Rogers Way,Harshbarger 108, Tucson, AZ 85721 USA

Reprint 's Address:

  • 范功端

    [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China;;[Fan, Gongduan]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China;;[Fan, Gongduan]Univ Arizona, Dept Chem & Environm Engn, 1133 E James E Rogers Way,Harshbarger 108, Tucson, AZ 85721 USA

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Source :

DESALINATION AND WATER TREATMENT

ISSN: 1944-3994

Year: 2018

Volume: 135

Page: 141-156

1 . 2 3 4

JCR@2018

1 . 0 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:170

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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