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[期刊论文]

Fast synthesis of Cu@zeolitic imidazolate framework-8 (ZIF-8) derived Cu/ZnO catalysts via a facile mechanical grinding method for CO2 hydrogenation to methanol

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author:

Chen, Fei (Chen, Fei.) [1] | Liu, Siyu (Liu, Siyu.) [2] | Huang, Hao (Huang, Hao.) [3] | Unfold

Indexed by:

Scopus SCIE

Abstract:

Direct conversion of CO2 with renewable H2 to produce methanol provides a promising way for CO2 utilization and H2 storage. Cu/ZnO catalysts are active, but their activities depend on the preparation methods. Here, we reported a facile mechanical grinding method for the fast synthesis of Cu@zeolitic imidazolate framework-8 (ZIF-8) derived Cu/ZnO catalysts applied in CO2 hydrogenation to methanol. The confinement in ZIF-8 cages led to the formation of metal oxide particles with controlled crystallite sizes after pyrolysis in air. ZnO derived from ZIF-8 with ultrahigh specific surface area offered high CuO dispersion, obtaining higher Cu0 surface area and smaller Cu crystallite size after reduction. The effects of the Cu/(Cu + Zn) molar ratio and alcohol types during catalyst preparation on the textural properties of final catalysts were systemically studied. The resultant catalyst exhibited high activity with STY of methanol up to 128.7 g kgcat-1 h-1 at 200 degrees C, much higher than that of catalysts prepared by the conventional impregnation and coprecipitation methods and commercial Cu/ZnO. The present work offers an efficient method for optimizing Cu/ZnO catalysts for CO2 hydrogenation to methanol.

Community:

  • [ 1 ] [Chen, Fei]Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
  • [ 2 ] [Liu, Siyu]Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
  • [ 3 ] [Liu, Zhongyi]Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
  • [ 4 ] [Chen, Fei]Zhengzhou Univ, Pingyuan Lab, Zhengzhou 450001, Peoples R China
  • [ 5 ] [Liu, Siyu]Zhengzhou Univ, Pingyuan Lab, Zhengzhou 450001, Peoples R China
  • [ 6 ] [Liu, Zhongyi]Zhengzhou Univ, Pingyuan Lab, Zhengzhou 450001, Peoples R China
  • [ 7 ] [Peng, Xiaobo]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst, Gongye Rd 523, Fuzhou 350002, Peoples R China
  • [ 8 ] [Zhang, Zhenzhou]Zhengzhou Univ, Sch Chem Engn, State Key Lab Coking Coal Resources Green Exploita, Zhengzhou 450001, Peoples R China
  • [ 9 ] [Liu, Zhongyi]Zhengzhou Univ, Sch Chem Engn, State Key Lab Coking Coal Resources Green Exploita, Zhengzhou 450001, Peoples R China
  • [ 10 ] [Zhang, Zhenzhou]Zhengzhou Univ, Engn Res Ctr Adv Funct Mat Mfg, Sch Chem Engn, Minist Educ, Zhengzhou 450001, Peoples R China
  • [ 11 ] [Huang, Hao]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 12 ] [Wang, Bo]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 13 ] [Liu, Zhihao]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 14 ] [Jiang, Xiuyun]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 15 ] [Xiang, Wenjie]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 16 ] [Yang, Guohui]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 17 ] [Tsubaki, Noritatsu]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
  • [ 18 ] [Yang, Guohui]Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
  • [ 19 ] [Liu, Guangbo]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

Reprint 's Address:

  • 彭小波

    [Liu, Zhongyi]Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China;;[Liu, Zhongyi]Zhengzhou Univ, Pingyuan Lab, Zhengzhou 450001, Peoples R China;;[Peng, Xiaobo]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst, Gongye Rd 523, Fuzhou 350002, Peoples R China;;[Zhang, Zhenzhou]Zhengzhou Univ, Sch Chem Engn, State Key Lab Coking Coal Resources Green Exploita, Zhengzhou 450001, Peoples R China;;[Liu, Zhongyi]Zhengzhou Univ, Sch Chem Engn, State Key Lab Coking Coal Resources Green Exploita, Zhengzhou 450001, Peoples R China;;[Zhang, Zhenzhou]Zhengzhou Univ, Engn Res Ctr Adv Funct Mat Mfg, Sch Chem Engn, Minist Educ, Zhengzhou 450001, Peoples R China;;[Tsubaki, Noritatsu]Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan

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Source :

CHEMICAL SCIENCE

ISSN: 2041-6520

Year: 2024

Issue: 5

Volume: 16

Page: 2273-2286

7 . 6 0 0

JCR@2023

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

30 Days PV: 3

Online/Total:214/10269029
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