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author:

Liu Jie (Liu Jie.) [1] (Scholars:刘杰) | Liu Changcheng (Liu Changcheng.) [2] | Ma Aizeng (Ma Aizeng.) [3] | Da Zhijian (Da Zhijian.) [4] | Zheng Huidong (Zheng Huidong.) [5] (Scholars:郑辉东)

Indexed by:

SCIE

Abstract:

Several Pt-theta-Al2O3 catalysts with similar ultra-low Cl contents were used to investigate the influence of dechlorination temperature on propane dehydrogenation reaction. The Pt-theta-Al2O3 catalyst treated at a highest dechlorination temperature showed a lowest propane rate and propylene selectivity. The scanning transmission electron microscopy showed that the dispersions of Pt nanoparticles decreased with an increasing dechlorination temperature. The temperature-programmed reduction analysis showed that higher dechlorination temperature could lead to strong interactions between the metal and support, making it difficult to reduce Pt nanoparticles. The temperature-programmed oxidation analysis implied that more coke was deposited on the metal for catalyst treated at higher dechlorination temperature. The Raman spectra and the H/C ratio showed that more side-reactions, such as cracking and severe deep dehydrogenation reactions, occurred on catalysts treated at higher dechlorination temperatures. Therefore, the lower the dispersion of Pt nanoparticles was, the stronger the metal-support interactions and increased side-reactions would be, resulting in lower catalytic activity for Pt-theta-Al2O3 treated with higher dechlorination temperature.

Keyword:

dechlorination temperature metal-support interactions propane dehydrogenation reaction Pt nanoparticles theta-Al2O3

Community:

  • [ 1 ] [Liu Jie]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Zheng Huidong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Liu Jie]SINOPEC Res Inst Petr Proc, Beijing 100083, Peoples R China
  • [ 4 ] [Liu Changcheng]SINOPEC Res Inst Petr Proc, Beijing 100083, Peoples R China
  • [ 5 ] [Ma Aizeng]SINOPEC Res Inst Petr Proc, Beijing 100083, Peoples R China
  • [ 6 ] [Da Zhijian]SINOPEC Res Inst Petr Proc, Beijing 100083, Peoples R China

Reprint 's Address:

  • 郑辉东

    [Zheng Huidong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China;;[Da Zhijian]SINOPEC Res Inst Petr Proc, Beijing 100083, Peoples R China

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Source :

CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY

ISSN: 1008-6234

CN: 11-4012/TE

Year: 2018

Issue: 4

Volume: 20

Page: 1-7

0 . 6

JCR@2018

0 . 6 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:170

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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