Indexed by:
Abstract:
Several Pt-θ-Al2O3 catalysts with similar ultra-low Cl contents were utilized to evaluate the influence of dechlorination temperature on propane dehydrogenation reaction. The Pt-θ-Al2O3 catalyst treated at a highest dechlorination temperature showed a lowest propane rate and propylene selectivity. The scanning transmission electron microscopy showed that the dispersions of Pt nanoparticles decreased with an increasing dechlorination temperature. The temperature-programmed reduction analysis showed that higher dechlorination temperature could lead to strong interactions between the metal and support, making it difficult to reduce Pt nanoparticles. The temperature-programmed oxidation analysis indicated that more coke was deposited on the metal for catalyst treated at higher dechlorination temperature. The Raman spectra and the H/C ratio showed that more side-reactions, e.g., cracking and severe deep dehydrogenation reactions, occurred on catalysts treated at higher dechlorination temperatures. Thus, the lower the dispersion of Pt nanoparticles was, the stronger the metal-support interactions and increased side-reactions would be, leading to lower catalytic activity for Pt-θ-Al2O3 treated with higher dechlorination temperature.
Keyword:
Reprint 's Address:
Email:
Source :
China Petroleum Processing and Petrochemical Technology
ISSN: 1008-6234
CN: 11-4012/TE
Year: 2018
Issue: 4
Volume: 20
Page: 1-7
0 . 6
JCR@2018
0 . 6 0 0
JCR@2023
ESI Discipline: ENGINEERING;
ESI HC Threshold:170
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: