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author:

Liu, J. (Liu, J..) [1] (Scholars:刘杰) | Liu, C. (Liu, C..) [2] | Ma, A. (Ma, A..) [3] | Da, Z. (Da, Z..) [4] | Zheng, H. (Zheng, H..) [5] (Scholars:郑辉东)

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Scopus

Abstract:

Several Pt-θ-Al2O3 catalysts with similar ultra-low Cl contents were utilized to evaluate the influence of dechlorination temperature on propane dehydrogenation reaction. The Pt-θ-Al2O3 catalyst treated at a highest dechlorination temperature showed a lowest propane rate and propylene selectivity. The scanning transmission electron microscopy showed that the dispersions of Pt nanoparticles decreased with an increasing dechlorination temperature. The temperature-programmed reduction analysis showed that higher dechlorination temperature could lead to strong interactions between the metal and support, making it difficult to reduce Pt nanoparticles. The temperature-programmed oxidation analysis indicated that more coke was deposited on the metal for catalyst treated at higher dechlorination temperature. The Raman spectra and the H/C ratio showed that more side-reactions, e.g., cracking and severe deep dehydrogenation reactions, occurred on catalysts treated at higher dechlorination temperatures. Thus, the lower the dispersion of Pt nanoparticles was, the stronger the metal-support interactions and increased side-reactions would be, leading to lower catalytic activity for Pt-θ-Al2O3 treated with higher dechlorination temperature.

Keyword:

Dechlorination temperature; Metal-support interactions; Propane dehydrogenation reaction; Pt nanoparticles; θ-Al2O3

Community:

  • [ 1 ] [Liu, J.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Liu, J.]SINOPEC Research Institute of Petroleum Processing, Beijing, 100083, China
  • [ 3 ] [Liu, C.]SINOPEC Research Institute of Petroleum Processing, Beijing, 100083, China
  • [ 4 ] [Ma, A.]SINOPEC Research Institute of Petroleum Processing, Beijing, 100083, China
  • [ 5 ] [Da, Z.]SINOPEC Research Institute of Petroleum Processing, Beijing, 100083, China
  • [ 6 ] [Zheng, H.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Da, Z.]SINOPEC Research Institute of Petroleum ProcessingChina

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Source :

China Petroleum Processing and Petrochemical Technology

ISSN: 1008-6234

CN: 11-4012/TE

Year: 2018

Issue: 4

Volume: 20

Page: 1-7

0 . 6

JCR@2018

0 . 6 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:170

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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