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Seeking efficient visible-light-driven photocatalysts for water splitting to produce H-2 has attracted much attention. Chemical doping is an effective strategy to enhance photocatalytic performance. Herein, we reported phosphorus-doped covalent triazine-based frameworks (CTFs) for photocatalytic H-2 evolution. Phosphorus-doped CTFs were fabricated by a facile thermal treatment using easily available red phosphorus as the external phosphorus species. The introduction of phosphorus atoms into the frameworks modified the optical and electronic property of CTFs, thus promoting the generation, separation, and migration of photoinduced electron-hole pairs. Consequently, the photocatalytic H-2-production efficiency of phosphorus-doped CTFs was greatly improved, which was 4.5, 3.9, and 1.8 times as high as that of undoped CTFs and phosphorus-doped g-C3N4 calcined from melamine and urea, respectively.
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ACS APPLIED MATERIALS & INTERFACES
ISSN: 1944-8244
Year: 2018
Issue: 48
Volume: 10
Page: 41415-41421
8 . 4 5 6
JCR@2018
8 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:284
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 91
SCOPUS Cited Count: 85
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3