Synthesis, Structure, and Optical Limiting Properties of an Axial Substituted Bis(8-oxide quinoline)zirconium Phthalocyanine - Details

author：

You Ming-Hua (You Ming-Hua.) ^[1] | Fang Xin (Fang Xin.) ^[2] (Scholars：方昕) | Lin Mei-Jin (Lin Mei-Jin.) ^[3] (Scholars：林梅金)

Indexed by：

Scopus SCIE CSCD

Abstract：

A　novel　bis(8-oxide　quinoline)zironium　phthalocyanine　[(OQ)(2)ZrPc]　with　two　8-oxide　quinolone　anions　at　the　same　axial　positions　has　been　successfully　synthesized　and　its　chemical　structure　has　been　assigned　by　the　H-1　NMR,　MS　and　two-dimensional　correlation　infrared　(2D-IR)　spectroscopy　as　well　as　by　single-crystal　X-ray　structural　analysis.　It　possessed　a　moderately　effective　nonlinear　absorption　coefficient　beta(eff)　of　6.69x　10(-14)　cm/GW　at　532　nm　in　DMF　solution,　implying　it　is　a　promising　candidate　for　nonlinear　optical　materials.

Keyword：

axial substitution optical limiting properties phthalocyanines single-crystal structure zirconium complex

Community：

[ 1 ] [You Ming-Hua]Fuzhou Univ, Coll Zhicheng, Fuzhou 350002, Fujian, Peoples R China
[ 2 ] [You Ming-Hua]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
[ 3 ] [Fang Xin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
[ 4 ] [Lin Mei-Jin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China