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author:

Cui, Qingyan (Cui, Qingyan.) [1] (Scholars:崔勍焱) | Wang, Shuqin (Wang, Shuqin.) [2] | Wei, Qiang (Wei, Qiang.) [3] | Mu, Liang (Mu, Liang.) [4] (Scholars:穆亮) | Yu, Guanglin (Yu, Guanglin.) [5] | Zhang, Tao (Zhang, Tao.) [6] | Zhou, Yasong (Zhou, Yasong.) [7]

Indexed by:

Scopus SCIE

Abstract:

A series of Zr incorporated small crystal size Y zeolites were successfully synthesized by a direct hydrothermal method, and the corresponding NiW catalysts were prepared for the hydrocracking of vacuum gas oil (VGO). The synthesized zeolites and prepared catalysts were characterized by XRD, SEM, FTIR, Pyridine FTIR, H-2-TPR and TEM techniques. The results show that the synthesized zeolites have uniform morphology and small crystal size, while Zr4+ incorporated into the framework of Y zeolite has been confirmed by XRD and FTIR. The amount of acid sites of xZrY zeolite slightly increases compared with that of Y zeolite by Pyridine FTIR. Moreover, the Zr4+ incorporation into Y zeolite can increase the W species reducibility, modulate the length and stacking of WS2 phase, and enhance the W species dispersion on the catalyst surface by H-2-TPR and TEM, which favor to improve the hydrogenation activity of the catalyst to tune the balance between cracking activity and hydrogenation/dehydrogenation activity. Hence, the catalyst containing xZrY zeolite exhibits not only higher yield and selectivity of middle distillate but also slightly higher conversion of VGO compared with the catalyst containing Y zeolite.

Keyword:

Hydrocracking catalyst Hydrogenation activity Middle distillate Small crystal size Y zeolite Zr-incorporation

Community:

  • [ 1 ] [Cui, Qingyan]Fuzhou Univ, Coll Chem Engn, Fuzhou, Fujian, Peoples R China
  • [ 2 ] [Mu, Liang]Fuzhou Univ, Coll Chem Engn, Fuzhou, Fujian, Peoples R China
  • [ 3 ] [Cui, Qingyan]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 4 ] [Wei, Qiang]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 5 ] [Yu, Guanglin]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 6 ] [Zhou, Yasong]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 7 ] [Wang, Shuqin]PetroChina Co Ltd, Petrochem Res Inst, Beijing, Peoples R China
  • [ 8 ] [Zhang, Tao]PetroChina Co Ltd, Petrochem Res Inst, Beijing, Peoples R China

Reprint 's Address:

  • 崔勍焱 待查

    [Cui, Qingyan]Fuzhou Univ, Coll Chem Engn, Fuzhou, Fujian, Peoples R China;;[Zhou, Yasong]Fuzhou Univ, Coll Chem Engn, Fuzhou, Fujian, Peoples R China;;[Cui, Qingyan]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China;;[Zhou, Yasong]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

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Source :

FUEL

ISSN: 0016-2361

Year: 2019

Volume: 237

Page: 597-605

5 . 5 7 8

JCR@2019

6 . 7 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:150

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 47

SCOPUS Cited Count: 46

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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