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Intermittent Ultrasonic-Assisted CO2 Replacement for CH4 Extraction from Hydrate-Bearing Clay-Silt Sediments Scopus
期刊论文 | 2025 | Energy and Fuels
Abstract&Keyword Cite Version(1)

Abstract :

Natural gas hydrate (NGH) mining via CH4/CO2 exchange integrates CH4 extraction with CO2 geological sequestration, thereby facilitating the achievement of carbon neutrality. However, the relatively low replacement cost remains a significant bottleneck that hinders its large-scale application. In this study, we investigated the potential of intermittent ultrasonic assistance to enhance CH4/CO2 replacement in hydrate-bearing sediments. The effects of ultrasonic power, experimental pressure, and temperature, as well as initial water and hydrate saturations, were systematically analyzed. Results demonstrated that both CH4 recovery and CO2 sequestration rates exhibited an increasing trend with higher ultrasonic power. Specifically, at 100% ultrasonic power, the CH4 recovery and CO2 sequestration rates reached 79.06% and 55.94%, respectively. Additionally, both rates increased as the pressure decreased and the temperature rose. Notably, ultrasonic assistance significantly improved CH4/CO2 replacement even under conditions where the experimental pressure exceeded the CH4 hydrate phase boundary, or the temperature was below the freezing point. Increased initial water saturation was found to be beneficial for the ultrasonic-assisted CH4/CO2 replacement, whereas a higher hydrate saturation negatively impacted the process. These findings provide valuable insights into enhancing CH4/CO2 swapping and contribute to the advancement of NGH mining and CO2 geological sequestration technologies. © 2025 American Chemical Society.

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GB/T 7714 Mu, L. , Zeng, J. , Lin, X. et al. Intermittent Ultrasonic-Assisted CO2 Replacement for CH4 Extraction from Hydrate-Bearing Clay-Silt Sediments [J]. | Energy and Fuels , 2025 .
MLA Mu, L. et al. "Intermittent Ultrasonic-Assisted CO2 Replacement for CH4 Extraction from Hydrate-Bearing Clay-Silt Sediments" . | Energy and Fuels (2025) .
APA Mu, L. , Zeng, J. , Lin, X. , Liu, M. , Cui, Q. . Intermittent Ultrasonic-Assisted CO2 Replacement for CH4 Extraction from Hydrate-Bearing Clay-Silt Sediments . | Energy and Fuels , 2025 .
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Intermittent Ultrasonic-Assisted CO2 Replacement for CH4 Extraction from Hydrate-Bearing Clay-Silt Sediments SCIE
期刊论文 | 2025 , 39 (17) , 7990-8000 | ENERGY & FUELS
新工科背景下传热学课程教学改革与实践探索
期刊论文 | 2025 , (6) , 41-44 | 当代教育实践与教学研究(电子刊)
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Abstract :

在新工科建设的背景下,工程教育面临跨学科融合、创新能力培养等新需求.传热学作为工科学生的基础课程之一,承担着培养学生理论与实践结合能力的重要职责.然而,传统的传热学课程存在教学内容陈旧、教学方法单一、理论与实践脱节、学生创新能力和跨学科思维不足等问题,难以适应新工科要求.针对这些问题,提出了课程内容优化、教学方法创新、实践教学强化等教学改革措施,并通过实践探索了改革的效果.结果表明,这些措施显著提升了学生的学习兴趣和综合能力,符合新工科人才培养的需求.

Keyword :

传热学 传热学 实践探索 实践探索 教学改革 教学改革 新工科 新工科

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GB/T 7714 穆亮 , 崔勍焱 . 新工科背景下传热学课程教学改革与实践探索 [J]. | 当代教育实践与教学研究(电子刊) , 2025 , (6) : 41-44 .
MLA 穆亮 et al. "新工科背景下传热学课程教学改革与实践探索" . | 当代教育实践与教学研究(电子刊) 6 (2025) : 41-44 .
APA 穆亮 , 崔勍焱 . 新工科背景下传热学课程教学改革与实践探索 . | 当代教育实践与教学研究(电子刊) , 2025 , (6) , 41-44 .
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Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter SCIE
期刊论文 | 2025 , 39 (8) , 3752-3764 | ENERGY & FUELS
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Abstract :

The recovery of CH4 from coalbed gas (CBG) is significant for improving energy utilization and mitigating the greenhouse effect. In this study, CH4 was separated from CBG by forming sII hydrate with 5.56 mol % 1,3-dioxolane (DIOX) solution assisted by an eco-friendly promoter sodium lauroyl glutamate (SLG). The effects of SLG concentration, initial pressure and temperature, stirring rate, and CBG composition were systematically investigated. The results revealed that the addition of SLG notably diminished the hydrate induction time and reaction durations. The presence of 500 ppm of SLG decreased the CH4 concentration to 15.50 mol % from the initial 30.23 mol %, and the CH4 recovery and separation factor reached 81.70% and 3.34, respectively. Comparative analyses with other eco-friendly surfactants highlighted the substantial advantages of SLG. The CH4 concentration in the residual gas first decreased and then increased with the augmentation of the initial pressure, temperature, and stirring rate. An inverse pattern was observed in the variations of CH4 recovery and separation factor. This indicated that there existed an optimal initial pressure, temperature, and stirring rate for CBG separation. The CH4 content in the hydrate was increased to 91.59% after a fourth-stage enrichment, meeting the standards for the direct injection of CBG into natural gas pipelines. These findings provide valuable insights for CH4 separation from CBG by forming sII hydrate with eco-friendly promoters.

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GB/T 7714 Mu, Liang , Zhu, Xiaohai , Lai, Jintao et al. Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter [J]. | ENERGY & FUELS , 2025 , 39 (8) : 3752-3764 .
MLA Mu, Liang et al. "Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter" . | ENERGY & FUELS 39 . 8 (2025) : 3752-3764 .
APA Mu, Liang , Zhu, Xiaohai , Lai, Jintao , Zeng, Jiguang , Cui, Qingyan . Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter . | ENERGY & FUELS , 2025 , 39 (8) , 3752-3764 .
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Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter EI
期刊论文 | 2025 , 39 (8) , 3752-3764 | Energy and Fuels
Methane Recovery from Coalbed Gas by Forming sII Hydrate with the Aid of a Novel Eco-Friendly Promoter Scopus
期刊论文 | 2025 , 39 (8) , 3752-3764 | Energy and Fuels
Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries EI
期刊论文 | 2024 , 126 | Gas Science and Engineering
Abstract&Keyword Cite

Abstract :

Natural gas hydrates (NGH) as a potential energy resource gain much attention, the depressurization-assisted CH4/CO2 replacement is a combined method proposed recently for NGH mining. This work experimentally investigated the depressurization-assisted CH4/CO2 replacement behavior in the muddy-silt slurries, and the effect of depressurization moment, amplitude and frequency was systematically examined. The results revealed that the depressurization after replacement significantly promoted reaction within a short period. The CH4 replacement ratio was increased by delaying the depressurization moment and increasing the depressurization magnitude. The maximum CH4 replacement ratio reached 61.28% at the depressurization moment of 48 h and 274.15 K. Additionally, the CH4 replacement ratio was further increased in the secondary depressurization event compared to that at the primary depressurization. This research indicated that the depressurization was beneficial for CO2 sequestration when the replacement pressure is higher than CO2 hydrate equilibrium pressure. While it did not facilitate CO2 sequestration when the replacement pressure is close to CO2 hydrate equilibrium pressure. The free water consumption decreased with the increase of the depressurization moment, amplitude and frequency. These findings would contribute to the development of the depressurization-assisted CO2/CH4 replacement in the future. © 2024 Elsevier B.V.

Keyword :

Carbon dioxide Carbon dioxide Energy resources Energy resources Gas hydrates Gas hydrates Hydration Hydration Mining Mining Potential energy Potential energy Silt Silt

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GB/T 7714 Mu, Liang , Zhao, Huixing , Li, Xianlong et al. Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries [J]. | Gas Science and Engineering , 2024 , 126 .
MLA Mu, Liang et al. "Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries" . | Gas Science and Engineering 126 (2024) .
APA Mu, Liang , Zhao, Huixing , Li, Xianlong , Zeng, Jiguang , Cui, Qingyan . Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries . | Gas Science and Engineering , 2024 , 126 .
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Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries Scopus
期刊论文 | 2024 , 38 (16) , 15103-15115 | Energy and Fuels
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Abstract :

The gas-hydrate-sediment-water multiphase flow is often involved in drilling and exploitation of natural gas hydrate (NGH) reservoirs in seabed due to its weak cementation; therefore, understanding hydrate formation and decomposition in sediment-contained slurries is important. In this work, CH4 hydrate formation and decomposition in clay-silt slurries was explored, the effects of clay type and content, stirring rate, additives, experimental temperature, and pressure were systematically investigated. The presence of clay notably accelerated CH4 hydrate formation in slurries, and the montmorillonite exhibited a more obvious promotion effect than kaolinite. As the stirring rate increased, the induction time and reaction time were shortened, while the gas consumption rate and water conversion increased. The addition of 500 ppm sodium dodecyl sulfate (SDS) and 1.0 wt % fulvic acid (FA) significantly reduced the induction time and increased hydrate formation rate. During the interaction of SDS and sediment, CH4 hydrate formed in the slurries instantaneously. The CH4 hydrate decomposition rate in slurries increased as the experimental temperature increased or the pressure decreased. The temperature had a limited impact on the decomposition time above freezing point, while it was significant below freezing point. The presence of clay notably decreased the CH4 hydrate decomposition rate in slurries. Compared to the clay-free system, the ΔTd values (temperature decreased during hydrate decomposition) in the montmorillonite systems were decreased, while they were increased in the kaolinite systems. The findings provide valuable insights for the exploitation of marine NGH. © 2024 American Chemical Society.

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GB/T 7714 Mu, L. , Lai, J. , Li, X. et al. Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries [J]. | Energy and Fuels , 2024 , 38 (16) : 15103-15115 .
MLA Mu, L. et al. "Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries" . | Energy and Fuels 38 . 16 (2024) : 15103-15115 .
APA Mu, L. , Lai, J. , Li, X. , Zhao, H. , Zeng, J. , Cui, Q. . Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries . | Energy and Fuels , 2024 , 38 (16) , 15103-15115 .
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Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter Scopus
期刊论文 | 2024 , 308 | Energy
Abstract&Keyword Cite

Abstract :

The existence of organic matters in naturally hydrate-bearing sediments would notably impact the CH4 extraction from reservoirs via CO2 swapping. In this work, the depressurization-assisted flue gas replacement was explored with artificial hydrate-bearing clay-silt sediments containing organic matter. The effect of organic matter type and content, depressurization moment and amplitude was systematically investigated. The results showed that the replacement was promoted at 5.0 wt% sulfonated lignin (SL) before depressurization, while it was inhibited at a lower SL content and this inhibition was weakened after depressurization. The CH4 replacement ratio and CO2 sequestration ratio increased as the fulvic acid (FA) content increased. For the organic matter-contained systems, the earlier depressurization moment was conducted, the higher CH4 recovery was obtained. The CH4 replacement ratio increased with the increase of depressurization amplitude, which reached 71.48 % in the 3.0 wt% FA system at the depressurization amplitude of 3.0 MPa. Aspen simulation revealed that the energy consumption was mainly caused by compression, there exist an optimum injection pressure of flue gas for the energy return on investment. The findings provide useful information for the depressurization-assisted flue gas replacement and would contribute to the actual NGH exploitation in the future. © 2024 Elsevier Ltd

Keyword :

CH4 hydrate CH4 hydrate Clay-silt sediment Clay-silt sediment Depressurization-assisted Depressurization-assisted Flue gas replacement Flue gas replacement Organic matter Organic matter

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GB/T 7714 Mu, L. , Zhao, H. , Zeng, J. et al. Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter [J]. | Energy , 2024 , 308 .
MLA Mu, L. et al. "Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter" . | Energy 308 (2024) .
APA Mu, L. , Zhao, H. , Zeng, J. , Zhu, X. , Lai, J. , Cui, Q. . Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter . | Energy , 2024 , 308 .
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Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter SCIE
期刊论文 | 2024 , 308 | ENERGY
Abstract&Keyword Cite Version(2)

Abstract :

The existence of organic matters in naturally hydrate-bearing sediments would notably impact the CH4 extraction from reservoirs via CO2 swapping. In this work, the depressurization-assisted flue gas replacement was explored with artificial hydrate-bearing clay-silt sediments containing organic matter. The effect of organic matter type and content, depressurization moment and amplitude was systematically investigated. The results showed that the replacement was promoted at 5.0 wt% sulfonated lignin (SL) before depressurization, while it was inhibited at a lower SL content and this inhibition was weakened after depressurization. The CH4 replacement ratio and CO2 sequestration ratio increased as the fulvic acid (FA) content increased. For the organic matter-contained systems, the earlier depressurization moment was conducted, the higher CH4 recovery was obtained. The CH4 replacement ratio increased with the increase of depressurization amplitude, which reached 71.48 % in the 3.0 wt% FA system at the depressurization amplitude of 3.0 MPa. Aspen simulation revealed that the energy consumption was mainly caused by compression, there exist an optimum injection pressure of flue gas for the energy return on investment. The findings provide useful information for the depressurization-assisted flue gas replacement and would contribute to the actual NGH exploitation in the future.

Keyword :

CH 4 hydrate CH 4 hydrate Clay-silt sediment Clay-silt sediment Depressurization-assisted Depressurization-assisted Flue gas replacement Flue gas replacement Organic matter Organic matter

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GB/T 7714 Mu, Liang , Zhao, Huixing , Zeng, Jiguang et al. Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter [J]. | ENERGY , 2024 , 308 .
MLA Mu, Liang et al. "Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter" . | ENERGY 308 (2024) .
APA Mu, Liang , Zhao, Huixing , Zeng, Jiguang , Zhu, Xiaohai , Lai, Jintao , Cui, Qingyan . Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter . | ENERGY , 2024 , 308 .
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Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter Scopus
期刊论文 | 2024 , 308 | Energy
Insight into the depressurization-assisted flue gas replacement behavior with the artificial hydrate-bearing clay-silt sediment containing organic matter EI
期刊论文 | 2024 , 308 | Energy
Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries SCIE
期刊论文 | 2024 , 126 | GAS SCIENCE AND ENGINEERING
Abstract&Keyword Cite Version(2)

Abstract :

Natural gas hydrates (NGH) as a potential energy resource gain much attention, the depressurization-assisted CH 4 /CO 2 replacement is a combined method proposed recently for NGH mining. This work experimentally investigated the depressurization-assisted CH 4 /CO 2 replacement behavior in the muddy-silt slurries, and the effect of depressurization moment, amplitude and frequency was systematically examined. The results revealed that the depressurization after replacement significantly promoted reaction within a short period. The CH 4 replacement ratio was increased by delaying the depressurization moment and increasing the depressurization magnitude. The maximum CH 4 replacement ratio reached 61.28% at the depressurization moment of 48 h and 274.15 K. Additionally, the CH 4 replacement ratio was further increased in the secondary depressurization event compared to that at the primary depressurization. This research indicated that the depressurization was beneficial for CO 2 sequestration when the replacement pressure is higher than CO 2 hydrate equilibrium pressure. While it did not facilitate CO 2 sequestration when the replacement pressure is close to CO 2 hydrate equilibrium pressure. The free water consumption decreased with the increase of the depressurization moment, amplitude and frequency. These findings would contribute to the development of the depressurization-assisted CO 2 /CH 4 replacement in the future.

Keyword :

CH4 production CH4 production CO2 replacement CO2 replacement Depressurization Depressurization Hydrate Hydrate Muddy silt Muddy silt

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GB/T 7714 Mu, Liang , Zhao, Huixing , Li, Xianlong et al. Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries [J]. | GAS SCIENCE AND ENGINEERING , 2024 , 126 .
MLA Mu, Liang et al. "Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries" . | GAS SCIENCE AND ENGINEERING 126 (2024) .
APA Mu, Liang , Zhao, Huixing , Li, Xianlong , Zeng, Jiguang , Cui, Qingyan . Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries . | GAS SCIENCE AND ENGINEERING , 2024 , 126 .
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Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries EI
期刊论文 | 2024 , 126 | Gas Science and Engineering
Experimental investigation on the depressurization-assisted CH4/CO2 replacement behavior in the muddy silt slurries Scopus
期刊论文 | 2024 , 126 | Gas Science and Engineering
Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries SCIE
期刊论文 | 2024 , 38 (16) , 15103-15115 | ENERGY & FUELS
Abstract&Keyword Cite Version(2)

Abstract :

The gas-hydrate-sediment-water multiphase flow is often involved in drilling and exploitation of natural gas hydrate (NGH) reservoirs in seabed due to its weak cementation; therefore, understanding hydrate formation and decomposition in sediment-contained slurries is important. In this work, CH4 hydrate formation and decomposition in clay-silt slurries was explored, the effects of clay type and content, stirring rate, additives, experimental temperature, and pressure were systematically investigated. The presence of clay notably accelerated CH4 hydrate formation in slurries, and the montmorillonite exhibited a more obvious promotion effect than kaolinite. As the stirring rate increased, the induction time and reaction time were shortened, while the gas consumption rate and water conversion increased. The addition of 500 ppm sodium dodecyl sulfate (SDS) and 1.0 wt % fulvic acid (FA) significantly reduced the induction time and increased hydrate formation rate. During the interaction of SDS and sediment, CH4 hydrate formed in the slurries instantaneously. The CH4 hydrate decomposition rate in slurries increased as the experimental temperature increased or the pressure decreased. The temperature had a limited impact on the decomposition time above freezing point, while it was significant below freezing point. The presence of clay notably decreased the CH4 hydrate decomposition rate in slurries. Compared to the clay-free system, the Delta T d values (temperature decreased during hydrate decomposition) in the montmorillonite systems were decreased, while they were increased in the kaolinite systems. The findings provide valuable insights for the exploitation of marine NGH.

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GB/T 7714 Mu, Liang , Lai, Jintao , Li, Xianlong et al. Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries [J]. | ENERGY & FUELS , 2024 , 38 (16) : 15103-15115 .
MLA Mu, Liang et al. "Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries" . | ENERGY & FUELS 38 . 16 (2024) : 15103-15115 .
APA Mu, Liang , Lai, Jintao , Li, Xianlong , Zhao, Huixing , Zeng, Jiguang , Cui, Qingyan . Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries . | ENERGY & FUELS , 2024 , 38 (16) , 15103-15115 .
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Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries Scopus
期刊论文 | 2024 , 38 (16) , 15103-15115 | Energy and Fuels
Methane Hydrate Formation and Decomposition Process in Clay-Silt Slurries EI
期刊论文 | 2024 , 38 (16) , 15103-15115 | Energy and Fuels
High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions SCIE
期刊论文 | 2024 , 290 | ENERGY
Abstract&Keyword Cite Version(2)

Abstract :

Although the hydrate-based coal bed gas (CBG) separations have been investigated, the obtained CH4 recovery ratios were not quite satisfactory. To further improve CH4 extraction, this study developed a high-efficiency CBG recovery method via hydrate formation in emulsions facilitated by an excellent anti-agglomerant. Thermodynamic promoters were introduced to lower operating pressure and the hydrate equilibrium conditions were determined. Then the effect of water-cut (40-100 vol%), initial pressure, experimental temperature, stirring rate and feed gas composition was investigated. The CH4 concentration in equilibrium gas first decreased then increased as the water-cut increased. Specifically, it decreased from 30.16 mol% to 8.23 mol% in the 60 vol% water-cut emulsions and CH4 recovery reached 88.02 % at 274.15 K and an initial pressure of 3.0 MPa, marking the highest CH4 recovery achieved in CBG separation thus far. The CH4 recovery was increased at low temperature while decreased at high pressure conditions. After a second-stage separation, the CH4 concentration in equilibrium gas decreased to 1.64 mol% from 30.16 mol%, signifying a remarkable 94.56 % recovery of CH4 from feed gas. The CH4 contents after a three-stage enrichment exceeded 87 mol%. This study furnishes valuable insights for CH4 recovery from CBG utilizing hydrate-based separation technology.

Keyword :

Coal bed gas Coal bed gas Emulsion Emulsion Hydrate Hydrate Methane recovery Methane recovery Separation Separation

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GB/T 7714 Mu, Liang , Zhou, Ziqi , Zhao, Huixing et al. High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions [J]. | ENERGY , 2024 , 290 .
MLA Mu, Liang et al. "High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions" . | ENERGY 290 (2024) .
APA Mu, Liang , Zhou, Ziqi , Zhao, Huixing , Zhu, Xiaohai , Cui, Qingyan . High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions . | ENERGY , 2024 , 290 .
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High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions Scopus
期刊论文 | 2024 , 290 | Energy
High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions EI
期刊论文 | 2024 , 290 | Energy
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