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author:

Wang, Shanchi (Wang, Shanchi.) [1] | Cai, Jingsheng (Cai, Jingsheng.) [2] | Mao, Jiajun (Mao, Jiajun.) [3] | Li, Shuhui (Li, Shuhui.) [4] | Shen, Jiali (Shen, Jiali.) [5] | Gao, Shouwei (Gao, Shouwei.) [6] | Huang, Jianying (Huang, Jianying.) [7] (Scholars:黄剑莹) | Wang, Xiaoqin (Wang, Xiaoqin.) [8] | Parkin, Ivan P. (Parkin, Ivan P..) [9] | Lai, Yuekun (Lai, Yuekun.) [10] (Scholars:赖跃坤)

Indexed by:

EI Scopus SCIE

Abstract:

We present a facile and environmentally friendly way to successfully build partially reduced titanium dioxide nanoparticles integrated with reduced graphene oxide composite nanosheets (RGO/TiO2-x) through an environmental solvothermal method at relatively low temperature. The Ti3+ self-doping of TiO2-x is conducive to enhance its visible light absorption, and the existence of RGO as the electron receiver makes the electrons on TiO2-x transport better to its surface, effectively promoting the separation of electrons and holes. Experiments on photocatalytic degradation of methylene blue dye and phenol colorless organic pollutant by visible light demonstrate that the RGO/TiO2-x assemblies exhibit the highest photocatalytic activity, and that methylene blue solution concentration of used in the experiment is 40 mg L-1, which was more higher than the concentration (10 mg L-1) used in many of reported articles. Compared to the pure TiO2 and TiO2-x, the photodegradation efficiency of methylene blue and phenol can be increased to 100% within 120 min and 150 min under visible light. Moreover, the mineralization rates of MB, such as the total organic carbon (TOC) degradation rate, can reach to 75.7%, 86.6% and 89.4% for m-RGO/TiO2-x, respectively. And the reaction efficiency of RGO/TiO2-x is basically not much changed after 4th cycles, suggesting its excellent photocatalytic stability.

Keyword:

Photoelectrochemical activity Reduced graphene oxide Ti3+ self-doping TiO2 nanoparticle Visible-light photocatalyst

Community:

  • [ 1 ] [Wang, Shanchi]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 2 ] [Cai, Jingsheng]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 3 ] [Mao, Jiajun]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 4 ] [Li, Shuhui]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 5 ] [Shen, Jiali]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 6 ] [Gao, Shouwei]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 7 ] [Wang, Xiaoqin]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 8 ] [Lai, Yuekun]Soochow Univ, Coll Text & Clothing Engn, Natl Engn Lab Modern Silk, Suzhou 215123, Peoples R China
  • [ 9 ] [Huang, Jianying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 10 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 11 ] [Parkin, Ivan P.]UCL, Mat Chem Res Ctr, Dept Chem, London, England

Reprint 's Address:

  • 赖跃坤

    [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2019

Volume: 467

Page: 45-55

6 . 1 8 2

JCR@2019

6 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 91

SCOPUS Cited Count: 85

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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