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author:

Luo, Yu (Luo, Yu.) [1] | Shi, Yixiang (Shi, Yixiang.) [2] | Chen, Yanbo (Chen, Yanbo.) [3] | Li, Wenying (Li, Wenying.) [4] | Jiang, Lilong (Jiang, Lilong.) [5] (Scholars:江莉龙) | Cai, Ningsheng (Cai, Ningsheng.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

To improve the energy-to-CH4 efficiency and enhance renewable power utilization, we investigate direct Power-to-Methane at low inlet H-2 content (25 vol%) in solid oxide electrolysis cell (SOEC). The synergy of the pressurized operation and the electricity input effectively enhances CH4 yield by one-order of magnitude from 2.8% to 28.7% and the CO2-to-CH4 ratio from 4.4% to 39.5% in the H-2-reduced case, where the ratio of H-2 consumption to total energy consumption decreases to 41% and the energy-to-CH4 efficiency increases to 53%. We develop a multiphysics tubular SOEC model to understand the intrinsic coupling between electrochemistry and heterogeneous catalytic chemistry. From the perspective of performance enhancement, geometry optimization, and thermal design, inhibiting CH4 production in the inlet gas-controlled zone and promoting CH4 production synergistically in both the electrochemistry-controlled zone and the temperature-controlled zone is the key to improve the energy-to-CH4 efficiency.

Keyword:

CO2 electrochemical reduction direct power-to-methane (P2M) multiphysics model pressurization solid oxide electrolysis cell (SOEC)

Community:

  • [ 1 ] [Luo, Yu]Tsinghua Univ, Dept Energy & Power Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
  • [ 2 ] [Shi, Yixiang]Tsinghua Univ, Dept Energy & Power Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
  • [ 3 ] [Chen, Yanbo]Tsinghua Univ, Dept Energy & Power Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
  • [ 4 ] [Cai, Ningsheng]Tsinghua Univ, Dept Energy & Power Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
  • [ 5 ] [Luo, Yu]Fuzhou Univ, NERC CFC, Sch Chem Engn, Fuzhou, Fujian, Peoples R China
  • [ 6 ] [Jiang, Lilong]Fuzhou Univ, NERC CFC, Sch Chem Engn, Fuzhou, Fujian, Peoples R China
  • [ 7 ] [Li, Wenying]Tsinghua Univ, Sichuan Energy Internet Res Inst, Chengdu, Sichuan, Peoples R China

Reprint 's Address:

  • [Shi, Yixiang]Tsinghua Univ, Dept Energy & Power Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China

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Source :

AICHE JOURNAL

ISSN: 0001-1541

Year: 2020

Issue: 5

Volume: 66

3 . 9 9 3

JCR@2020

3 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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