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author:

Liu, Yuchuan (Liu, Yuchuan.) [1] | Guan, Xu (Guan, Xu.) [2] | Huang, Baobing (Huang, Baobing.) [3] (Scholars:黄宝冰) | Wei, Qiaohua (Wei, Qiaohua.) [4] (Scholars:魏巧华) | Xie, Zailai (Xie, Zailai.) [5] (Scholars:谢在来)

Indexed by:

Scopus SCIE

Abstract:

Oxygen electrocatalysis, especially oxygen evolution reaction (OER), is a central process during the actual application of rechargeable metal-air battery. It is still challenging to develop ideal electrocatalysts to substitute the commercial noble metal-based materials. In this work, we have constructed a new material, CoP nanoparticles, which are encapsulated by a biomolecule-derived N, P-codoped carbon nanosheets via a simple and facile one-step strategy. The as-prepared material releases a high electrocatalytic activity and stability for OER, with an overpotential of 310 mV to achieve 10 mA/cm(2) in 1 M KOH. Importantly, we found that the phosphoric acid can not only introduce phosphorus dopant into 2D N-doped carbon nanosheets and play a role of pore-forming agent, but also participate in the formation of active center (cobalt phosphide). Moreover, the coverage of N, P-doped carbon can prevent the CoP nanoparticles from corrosion under the harsh reaction medium to achieve high and stable activity. We believe that our strategy can offer a novel pathway to synthesize new transition metal-based catalysts for electrocatalysis or other heterogeneous catalysis.

Keyword:

biomolecule carbon nanosheets CoP OER one-step strategy

Community:

  • [ 1 ] [Liu, Yuchuan]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China
  • [ 2 ] [Guan, Xu]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China
  • [ 3 ] [Huang, Baobing]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China
  • [ 4 ] [Wei, Qiaohua]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China
  • [ 5 ] [Xie, Zailai]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China

Reprint 's Address:

  • 魏巧华 谢在来

    [Wei, Qiaohua]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China;;[Xie, Zailai]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou, Peoples R China

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Source :

FRONTIERS IN CHEMISTRY

ISSN: 2296-2646

Year: 2020

Volume: 7

5 . 2 2 1

JCR@2020

3 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 21

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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