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Abstract：
A new inorganic-organic hybrid polyoxoniobate, H16K24Na26[Cu-3(en)(6)][(beta-H4Nb52O150)(2)]center dot 88H(2)O (1) (en = ethylenediamine), decorated with [Cu(en)(2)](2+) complex, has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR, and Uv-vis. Crystal structure analysis shows that 1 contains a ＂S＂-shaped {[Cu-3(en)(6)](beta center dot H4Nb52O150)(2)} polyoxoanion which is built from novel high-nuclearity {[Cu-3(en)(6)](beta center dot H4Nb52O150)} fragments. The compound 1 shows effective catalytic activity for hydrolytic decomposition of nerve agent simulant of dimethyl methylphosphonate (DMMP).
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INORGANIC CHEMISTRY COMMUNICATIONS
ISSN： 1387-7003
Year： 2020
Volume： 113
2 . 4 9 5
JCR@2020
4 . 4 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：160
JCR Journal Grade：2
CAS Journal Grade：4
Cited Count：
WoS CC Cited Count： 10
SCOPUS Cited Count： 7
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 0
Affiliated Colleges：
