A new dimeric isopolyoxoniobate {β-H4Nb52O150} decorated with copper(II)-ethylenediamine for hydrolytic decomposition of chemical warfare agent simulant DMMP - Details

author：

Wu, Y.-L. (Wu, Y.-L..) ^[1] | Sun, Y.-Q. (Sun, Y.-Q..) ^[2] | Li, X.-X. (Li, X.-X..) ^[3] | Zheng, S.-T. (Zheng, S.-T..) ^[4]

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Abstract：

A　new　inorganic-organic　hybrid　polyoxoniobate,　H16K24Na26[Cu3(en)6][(β-H4Nb52O150)2]·88H2O　(1)　(en　=　ethylenediamine),　decorated　with　[Cu(en)2]2+　complex,　has　been　hydrothermally　synthesized　and　structurally　characterized　by　single-crystal　X-ray　diffraction,　IR,　and　Uv-vis.　Crystal　structure　analysis　shows　that　1　contains　a　“S”-shaped　{[Cu3(en)6](β-H4Nb52O150)2}　polyoxoanion　which　is　built　from　novel　high-nuclearity　{[Cu(en)2](β-H4Nb52O150)}　fragments.　The　compound　1　shows　effective　catalytic　activity　for　hydrolytic　decomposition　of　nerve　agent　simulant　of　dimethyl　methylphosphonate　(DMMP).　©　2020　Elsevier　B.V.

Keyword：

Copper complex; Crystal structure; Hydrolytic decomposition; Isopolyoxoniobate

Community：

[ 1 ] [Wu, Y.-L.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 4 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address：

[Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

sunyq@fzu.edu.cn

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Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2020

Volume： 113

2 . 4 9 5

JCR@2020

4 . 4 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：2

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 7

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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