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author:

Ye, Lin (Ye, Lin.) [1] | Wen, Zhenhai (Wen, Zhenhai.) [2] | Li, Zhaohui (Li, Zhaohui.) [3] (Scholars:李朝晖) | Huang, Haitao (Huang, Haitao.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Charge carriers separation and surface catalytic reactions are two crucial steps in photocatalytic processes; the rational design of photocatalysts by taking these two factors into consideration is thus of great importance to advance the associated performance. Herein, a self-sacrificial strategy is developed to fabricate a ternary nanostructure photocatalyst, forming a hierarchical architecture of In(OH)(3) nanocube decorated NiS-ZnIn2S4 (ZIS) hybrid nanosheets (ZIS/In(OH)(3)-NiS). Such a unique structure provides the hybrid photocatalyst with a facilitated path for efficiently separating the charge carrier and abundant sites for catalytic reactions. Systematic characterizations that reveal the strong electronic interactions in the ternary ZIS/In(OH)(3)-NiS leads to fast electron transfer from excited ZnIn2S4 to NiS nanosheets, which provide catalytic sites for hydrogen evolution reaction. The comprehensive photocatalysis studies demonstrate that ZnIn2S4/In(OH)(3)-NiS exhibits ultrahigh photocatalytic activity toward hydrogen generation with a high rate of 7010 mu mol g(-1) h(-1), which ranks as one of the highest among ZnIn2S4-based photocatalysts reported so far. This work provides an attractive and effective way to develop high-activity photocatalysts without using precious metal cocatalysts. The investigation brings us one step closer to understanding the structure-determining properties of nanohybrid architecture, and provides a valuable reference to develop cost-effective and practical photocatalysts for a variety of applications.

Keyword:

cocatalysts H-2 evolution photocatalysts visble light ZnIn2S4

Community:

  • [ 1 ] [Ye, Lin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Ye, Lin]Hong Kong Polytech Univ, Dept Appl Phys, Hung Hom, Kowloon, Hong Kong, Peoples R China
  • [ 4 ] [Huang, Haitao]Hong Kong Polytech Univ, Dept Appl Phys, Hung Hom, Kowloon, Hong Kong, Peoples R China
  • [ 5 ] [Li, Zhaohui]Fuzhou Univ, Coll Chem & Chem Engn, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 李朝晖

    [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Huang, Haitao]Hong Kong Polytech Univ, Dept Appl Phys, Hung Hom, Kowloon, Hong Kong, Peoples R China;;[Li, Zhaohui]Fuzhou Univ, Coll Chem & Chem Engn, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

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Source :

SOLAR RRL

ISSN: 2367-198X

Year: 2020

Issue: 8

Volume: 4

8 . 5 8 2

JCR@2020

6 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 49

SCOPUS Cited Count: 45

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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