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Abstract:
A triazole-stabilized fluorescence sensor is developed for copper detection in the study. Tris-(benzyltriazolylmethyeamine (TBTA) is used to improve the sensitivity and stability for the sensing system. A series of comparative experiments are performed with and without TBTA. In the presence of TBTA, the fluorescence decrease ratio is enhanced from 2.46 to 118.25; the detection limit is reduced from 67 nM to 3.6 nM; the higher selectivity toward copper compared to the other metal ions is verified, including K+, Ca2+, Cd (2+), Zn2+, Mg2+, Mn2+, Pb2+, Hg2+, Fe3+ and Cr3+. Besides, the sensing system is successfully applied for copper determination in complex tea samples and chicken feed samples with the recovery range of 91.67-116.8%. A good consistency between the presented sensor and the flame atom absorbance spectrometry (FAAS) is confirmed by the low relative errors with the range from -2.39% to 7.02%.
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FOOD CHEMISTRY
ISSN: 0308-8146
Year: 2020
Volume: 317
7 . 5 1 4
JCR@2020
8 . 5 0 0
JCR@2023
ESI Discipline: AGRICULTURAL SCIENCES;
ESI HC Threshold:116
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 20
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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