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author:

Lyu, Haixia (Lyu, Haixia.) [1] (Scholars:吕海霞) | Hu, Kai (Hu, Kai.) [2] | Chu, Qinghua (Chu, Qinghua.) [3] | Su, Zhiping (Su, Zhiping.) [4] | Xie, Zenghong (Xie, Zenghong.) [5] (Scholars:谢增鸿)

Indexed by:

Scopus SCIE

Abstract:

In this paper, an ionic liquid mediated molecularly imprinted polymer (IL-MIP) was prepared, in which synthesis system 1-butyl-3-methylimidazolium tetrafluoroborate (IL) was introduced to improve its selectivity and adsorption for the target. The structures of the prepared materials were characterized by SEM, BET, (CNMR)-C-13 and FTIR, and the adsorption performance of the resultant IL-MIP for BPA and its analogues (phenol, 4-NP, 4-CAP and 1-naphthol) in strong polar media were investigated in detail. The experimental data showed that the adsorption capacities of IL-MIP and molecularly imprinted polymer (MIP) for Bisphenol A (BPA) were 116.16 mg/g and 87.30 mg/g, with imprinting factor of 3.77 and 2.72, respectively. In addition, several other competitive analogues with different polarities (phenol, 4-NP, 4-CAP and 1-naphthol) were chosen to evaluate the selectivity of IL-MIP and the experimental results demonstrated that the synthesized IL-MIP displayed selectivity toward BPA and against analogue molecules. This work provided a simple and effective method to selectively extract BPA from aqueous medium or strong polar organic solvent.

Keyword:

BPA Ionic liquid Molecular imprinted polymer

Community:

  • [ 1 ] [Lyu, Haixia]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Hu, Kai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Chu, Qinghua]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Su, Zhiping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Xie, Zenghong]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Lyu, Haixia]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fujian Prov Univ, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 吕海霞 谢增鸿

    [Lyu, Haixia]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China;;[Xie, Zenghong]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

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Source :

MICROCHEMICAL JOURNAL

ISSN: 0026-265X

Year: 2020

Volume: 158

4 . 8 2 1

JCR@2020

4 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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