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学者姓名：张孟佳
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Abstract ：
Incorporation of ionic liquids into metal-organic frameworks (MOFs) offers a new platform to construct heterogeneous bifunctional catalytic systems for the chemical capture and conversion of CO2 with epoxides. Herein, an imidazolium-based ionic liquid decorated UiO-66 type MOF (P3[BCMIm]Br@UiO-66) was successfully constructed via solvothermal assembly of the carboxyl-functionalized imidazolium ionic liquid ligand, terephthalic acid ligand and Zr(iv) ions. It exhibits the highest catalytic activity upon the cycloaddition of CO2 (98.2% conversion of propylene oxide and 99% selectivity to propylene carbonate) under optimized conditions (2.2 Mpa CO2, 1.0 wt%, 110 °C, reaction time 2 h). Notably, P3[BCMIm]Br@UiO-66 outperformed the original UiO-66 materials and [BCMIm]Br. P3[BCMIm]Br@UiO-66 retained its good catalytic performance for up to five recycling runs with only a little loss in catalytic activity. Furthermore, several additional coupling reactions were investigated with other epoxides as substrates. © 2024 The Royal Society of Chemistry.
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| GB/T 7714 | Lin, J. , Luo, J. , Zhang, M. et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates [J]. | Catalysis Science and Technology , 2024 , 14 (16) : 4496-4505 . |
| MLA | Lin, J. et al. "Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates" . | Catalysis Science and Technology 14 . 16 (2024) : 4496-4505 . |
| APA | Lin, J. , Luo, J. , Zhang, M. , Zhang, L. , Cai, G. , Zou, J. et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates . | Catalysis Science and Technology , 2024 , 14 (16) , 4496-4505 . |
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Through the method of solvent-free confined encapsulation, , dibromo-p-diphenyl- p-diphenyl and 4,4 '-bipyridine , 4 '-bipyridine were adsorbed into the UiO-67-67 material, , and then in situ polymerized into the polymer ionic liquid PBpy-Br.-Br. The composite PBpy-Br@UiO-67-Br@UiO-67 contains three kinds of active centers: : Br-, - , Zr-OH/Zr-OH2-OH/Zr-OH2 and N heterocyclic. The structure was characterized by X-ray-ray diffraction(XRD), ( XRD ), Fourier transform infrared(FTIR) ( FTIR ) spectroscopy, , scanning electron microscopy(SEM), ( SEM ), 13 C nuclear magnetic resonance spectrometry(13C ( 13 C NMR), ), Brunauer-Emmett-Teller(BET)-Emmett-Teller ( BET ) analysis and thermogravimetric analysis(TGA). ( TGA ) . The composite was applied to catalyze the cycloaddition reaction of CO2 and epichlorohydrin. On the basis of single factor experiments, , the optimal reaction conditions determined by response surface optimization were 100 degrees C, , p CO2 =0.1 MPa, , PBpy-Br@UiO-67-Br@UiO-67 mass fraction of 0.22% and 22 h. Under the optimum reaction conditions, , the yield of cyclochlorocarbonate reached 99.6%, , and the conversion decreased by only 2.3% after 5 cycles. When the composite was used to catalyze other epoxides, , a conversion of over 50% was obtained. PBpy-Br@UiO-67-Br@UiO-67 has milder reaction conditions and higher catalytic efficiency, , which provides a new catalytic system for CO2 2 fixation and conversion.
Keyword ：
Carbon dioxide cycloaddition reaction Carbon dioxide cycloaddition reaction Metal-organic framework Metal-organic framework Poly ionic liquid Poly ionic liquid Solvent-free confined encapsulation Solvent-free confined encapsulation UiO-67 UiO-67
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| GB/T 7714 | Zhang, Mengjia , Zou, Nan , Luo, Jiamei et al. Catalytic Performance of Zr-MOF-MOF Supported Poly Ionic Liquid for CO2 Cycloaddition Reaction [J]. | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE , 2024 , 45 (10) . |
| MLA | Zhang, Mengjia et al. "Catalytic Performance of Zr-MOF-MOF Supported Poly Ionic Liquid for CO2 Cycloaddition Reaction" . | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 45 . 10 (2024) . |
| APA | Zhang, Mengjia , Zou, Nan , Luo, Jiamei , Zhong, Xionghui , Li, Ling . Catalytic Performance of Zr-MOF-MOF Supported Poly Ionic Liquid for CO2 Cycloaddition Reaction . | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE , 2024 , 45 (10) . |
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通过无溶剂限域封装,将二溴对二甲苯和4,4'-联吡啶吸附至UiO-67材料微孔中,并原位聚合成聚离子液体PBpy-Br,得到兼具Br-,Zr-OH/Zr-OH2和N杂环3种活性中心的复合材料PBpy-Br@UiO-67.采用X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、13C核磁共振波谱(13C NMR)、比表面积分析(BET)和热重分析(TGA)等手段对材料进行了表征,并将其应用于催化CO2与环氧氯丙烷的环加成反应中.在单因素实验基础上,通过响应面优化确定的最佳反应条件为反应温度100 ℃、pCO2=0.1 MPa、催化剂用量(质量分数)0.22％以及反应时间22 h.在该条件下,环氧氯丙烷转化率达99.6％,催化剂循环使用5次后,转化率仅下降2.3％.此外,对PBpy-Br@UiO-67的普适性进行了研究,将其用于催化其它环氧化物与CO2反应,转化率均在50％以上.研究结果表明,PBpy-Br@UiO-67催化剂具有反应条件温和及催化效率高的特点,为CO2的固定与转化提供了新催化体系.
Keyword ：
UiO-67 UiO-67 二氧化碳环加成反应 二氧化碳环加成反应 无溶剂限域封装 无溶剂限域封装 聚离子液体 聚离子液体 金属有机框架 金属有机框架
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| GB/T 7714 | 张孟佳 , 邹南 , 罗佳美 et al. Zr-MOF固载聚离子液体对CO2环加成反应的催化性能 [J]. | 高等学校化学学报 , 2024 , 45 (10) : 1-11 . |
| MLA | 张孟佳 et al. "Zr-MOF固载聚离子液体对CO2环加成反应的催化性能" . | 高等学校化学学报 45 . 10 (2024) : 1-11 . |
| APA | 张孟佳 , 邹南 , 罗佳美 , 钟雄辉 , 李玲 . Zr-MOF固载聚离子液体对CO2环加成反应的催化性能 . | 高等学校化学学报 , 2024 , 45 (10) , 1-11 . |
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Abstract ：
Incorporation of ionic liquids into metal-organic frameworks (MOFs) offers a new platform to construct heterogeneous bifunctional catalytic systems for the chemical capture and conversion of CO2 with epoxides. Herein, an imidazolium-based ionic liquid decorated UiO-66 type MOF (P3[BCMIm]Br@UiO-66) was successfully constructed via solvothermal assembly of the carboxyl-functionalized imidazolium ionic liquid ligand, terephthalic acid ligand and Zr(iv) ions. It exhibits the highest catalytic activity upon the cycloaddition of CO2 (98.2% conversion of propylene oxide and 99% selectivity to propylene carbonate) under optimized conditions (2.2 Mpa CO2, 1.0 wt%, 110 degrees C, reaction time 2 h). Notably, P3[BCMIm]Br@UiO-66 outperformed the original UiO-66 materials and [BCMIm]Br. P3[BCMIm]Br@UiO-66 retained its good catalytic performance for up to five recycling runs with only a little loss in catalytic activity. Furthermore, several additional coupling reactions were investigated with other epoxides as substrates.
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| GB/T 7714 | Lin, Jianghui , Luo, Jiamei , Zhang, Mengjia et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates [J]. | CATALYSIS SCIENCE & TECHNOLOGY , 2024 , 14 (16) : 4496-4505 . |
| MLA | Lin, Jianghui et al. "Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates" . | CATALYSIS SCIENCE & TECHNOLOGY 14 . 16 (2024) : 4496-4505 . |
| APA | Lin, Jianghui , Luo, Jiamei , Zhang, Mengjia , Zhang, Lei , Cai, Guohui , Zou, Jiahua et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates . | CATALYSIS SCIENCE & TECHNOLOGY , 2024 , 14 (16) , 4496-4505 . |
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Abstract ：
文章在分析化工原理实验考核现状的基础上，基于OBE理念制定了化工原理实验课程目标，对化工原理实验预习、实验操作、实验报告、期末笔试等四个教学环节的考核内容进行重新设计，以期达到以考促教、以考促学的目的，同时支撑工程教育专业认证中毕业要求指标点的达成。
Keyword ：
OBE理念 OBE理念 化工原理实验 化工原理实验 工程教育认证 工程教育认证 考核 考核 能力培养 能力培养
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| GB/T 7714 | 张孟佳 , 王晓达 , 蔡国辉 et al. 支撑工程教育专业认证的化工原理实验考核内容设计 [J]. | 化工高等教育 , 2023 , 40 (05) : 111-115,156 . |
| MLA | 张孟佳 et al. "支撑工程教育专业认证的化工原理实验考核内容设计" . | 化工高等教育 40 . 05 (2023) : 111-115,156 . |
| APA | 张孟佳 , 王晓达 , 蔡国辉 , 施小芳 , 叶长燊 , 李玲 . 支撑工程教育专业认证的化工原理实验考核内容设计 . | 化工高等教育 , 2023 , 40 (05) , 111-115,156 . |
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本发明属于聚合物材料合成技术领域，公开了一种含咪唑基有机聚合物材料的制备及应用，具体内容是以含咪唑基的化合物和二乙烯基苯单体通过聚合反应制备一种含咪唑基的有机聚合物材料。该材料将具有CO2吸附和活化功能的咪唑基团大量固载到聚合物骨架上，并达到均匀分布的效果。该聚合物材料具有较好的稳定性，且合成过程简单，绿色环保。本发明将制备的含咪唑基的聚合物材料作为催化剂应用于二氧化碳与甲醇合成碳酸二甲酯的反应，在较为温和的反应条件下即表现出优异的催化性能。
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| GB/T 7714 | 李玲 , 钟雄辉 , 李政 et al. 一种含咪唑基有机聚合物材料的制备及应用 : CN202210733656.9[P]. | 2022-06-27 00:00:00 . |
| MLA | 李玲 et al. "一种含咪唑基有机聚合物材料的制备及应用" : CN202210733656.9. | 2022-06-27 00:00:00 . |
| APA | 李玲 , 钟雄辉 , 李政 , 林江慧 , 张孟佳 . 一种含咪唑基有机聚合物材料的制备及应用 : CN202210733656.9. | 2022-06-27 00:00:00 . |
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文章首先分析了5W2H分析法在高校实验室安全管理中应用的思路，然后论述了5W2H分析法在高校实验室安全管理中应用的流程，包括明确安全管理意义（Why），落实安全管理责任主体（Who）；制定安全管理职责（What），履行安全管理义务（When&Where）；制定安全管理评判标准（How much），形成反馈激励机制（How）。
Keyword ：
5W2H分析法 5W2H分析法 实验室安全管理 实验室安全管理 高校 高校
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| GB/T 7714 | 张孟佳 , 施小芳 , 吴乃昕 et al. 5W2H分析法在高校实验室安全管理中的应用 [J]. | 西部素质教育 , 2022 , 8 (08) : 166-168 . |
| MLA | 张孟佳 et al. "5W2H分析法在高校实验室安全管理中的应用" . | 西部素质教育 8 . 08 (2022) : 166-168 . |
| APA | 张孟佳 , 施小芳 , 吴乃昕 , 李玲 . 5W2H分析法在高校实验室安全管理中的应用 . | 西部素质教育 , 2022 , 8 (08) , 166-168 . |
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Abstract ：
心理因素对高校实验室安全管理会产生一定的影响。文章在分析一线实验人员认知特点和心理状态的基础上，探讨了影响其安全行为模式和安全行为态度的因素，并有针对性地给出了相应的建议，为高校制定有效的安全管理制度、提高实验室安全管理执行力提供参考。
Keyword ：
安全心理 安全心理 安全行为 安全行为 执行力 执行力
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| GB/T 7714 | 吴乃昕 , 施小芳 , 张孟佳 et al. 加强实验室安全管理举措执行力的心理因素探讨 [J]. | 化工高等教育 , 2022 , 39 (03) : 136-139 . |
| MLA | 吴乃昕 et al. "加强实验室安全管理举措执行力的心理因素探讨" . | 化工高等教育 39 . 03 (2022) : 136-139 . |
| APA | 吴乃昕 , 施小芳 , 张孟佳 , 陈晓彦 , 李玲 . 加强实验室安全管理举措执行力的心理因素探讨 . | 化工高等教育 , 2022 , 39 (03) , 136-139 . |
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In this account, we summarize recent work on the direct introduction of the SCF (3) group by using [(bpy)CuSCF3] as trifluoromethylthiolating reagent. A number of efficient and convenient strategies have been disclosed for the synthesis of trifluoromethylthiolated compounds, including trifluoromethylthiolation of aryl, alkenyl, and alkyl halides, and arylboronic acids. These reactions afford various trifluoromethyl sulfides in good yields. Introduction Synthesis of [(bpy)CuSCF3] Trifluoromethylthiolation of Aryl Halides Trifluoromethylthiolation of Alkenyl Halides Trifluoromethylthiolation of Alkyl Halides Miscellaneous Conclusion
Keyword ：
copper copper fluorine fluorine trifluoromethylthiolating reagent trifluoromethylthiolating reagent trifluoromethylthiolation trifluoromethylthiolation
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| GB/T 7714 | Huang, Yangjie , Zhang, Mengjia , Lin, Qi et al. [(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds [J]. | SYNLETT , 2021 , 32 (02) : 109-118 . |
| MLA | Huang, Yangjie et al. "[(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds" . | SYNLETT 32 . 02 (2021) : 109-118 . |
| APA | Huang, Yangjie , Zhang, Mengjia , Lin, Qi , Weng, Zhiqiang . [(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds . | SYNLETT , 2021 , 32 (02) , 109-118 . |
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The tandem synthesis of 2-trifluoromethylthio-(seleno)-substituted benzofurans using palladium-catalyzed conditions is reported. Trifluoromethylthio(seleno)lation of 2-(2,2-dibromovinyl)phenols with (bpy)CuSCF3 or [(bpy)-CuSeCF3](2) furnishes several 2-trifluoromethylthio(seleno)-lated benzofurans in acceptable to good yield. Mechanistic investigations were performed to elucidate the reaction pathway, which was involved in the formation of a 2-bromobenzofuran species. The scope of this protocol was further extended to the preparation of 2-trifluoromethylthio(seleno)lated benzothiophenes and indoles.
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| GB/T 7714 | Zhang, Mengjia , Weng, Zhiqiang . Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles [J]. | ORGANIC LETTERS , 2019 , 21 (15) : 5838-5842 . |
| MLA | Zhang, Mengjia et al. "Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles" . | ORGANIC LETTERS 21 . 15 (2019) : 5838-5842 . |
| APA | Zhang, Mengjia , Weng, Zhiqiang . Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles . | ORGANIC LETTERS , 2019 , 21 (15) , 5838-5842 . |
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