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学者姓名：郭进
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Abstract ：
在自主设计的长度和内径均为25 cm的圆柱形容器中,开展了不同掺氢比(x)的氢气-甲烷-空气泄爆实验.实验结果表明:X对容器内部超压有显著影响,容器内共出现三类压力峰值(p1、p2、p3).p1是泄放速率超过了燃烧产物生成率导致的,并出现在x＜0.9的实验中,其幅值几乎不受x的影响;P2由声学振荡产生并且出现在0.45≤x≤0.9的实验中;p3是火焰燃烧面积达到最大值产生,仅出现在X=1的情况下.声学振荡造成的超压峰值随着x单调增加,在发生声学振荡时,火焰表面会出现周期性的细小胞格,并且声学振荡的频率与细小胞格出现的频率相近.X＜0.3时,容器内只存在一个压力峰值p1;X＞0.3时,容器内最大超压随着x单调增加.x＞0.15时,外部爆炸的最大超压也随着x的增加而增加.
Keyword ：
声学振荡 声学振荡 外部爆炸 外部爆炸 掺氢比 掺氢比 火焰传播 火焰传播 爆炸超压 爆炸超压
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| GB/T 7714 | 王昊哲 , 郭进 , 吴佳晗 et al. 掺氢比对氢气-甲烷-空气燃爆特性的影响 [J]. | 工程热物理学报 , 2025 , 46 (2) : 669-678 . |
| MLA | 王昊哲 et al. "掺氢比对氢气-甲烷-空气燃爆特性的影响" . | 工程热物理学报 46 . 2 (2025) : 669-678 . |
| APA | 王昊哲 , 郭进 , 吴佳晗 , 张瀚文 , 张苏 . 掺氢比对氢气-甲烷-空气燃爆特性的影响 . | 工程热物理学报 , 2025 , 46 (2) , 669-678 . |
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This paper investigates the pressure evolution and flame propagation behavior during the vented explosion of H2/air mixtures with hydrogen concentrations(C) ranging from 9 % to 27 %. The experiments were conducted in a 1 m3 vessel equipped with a vent covered by a 4-mm thick hinged aluminum panel. The results reveal three distinct internal pressure peaks during the vented explosion: P1 (the first pressure peak), P2 (the second pressure peak), and P3 (the third pressure peak). When C exceeds 12 %, P2 replaces P3 as the highest-pressure peak within the vessel. As C increases from 9 % to 27 %, P1 becomes less distinguishable in the pressure profiles. The maximum pressure formula proposed by Cubbage and Marshall accurately predicts the maximum explosion overpressure (Pmax) within the vessel. In the external pressure profiles, a maximum external pressure peak (Pext) is observed. As C increases, Pext rises from 4.8 kPa at C = 15 % to 49.9 kPa at C = 27 %. Additionally, as C increases, the maximum external flame speed increases from 170 m/s at C = 21 % to 236 m/s at C = 27 %. When C increases from 18 % to 27 %, the maximum external flame length(Lmax)increases from 1.5 m to 2.0 m. During the inertia-free venting experiments, the fireball, synchronized with the external explosion, assumes a mushroom shape. When hinged panels are used, the fireball becomes progressively flatter at the vent as C decreases.
Keyword ：
Flame Flame Hinged panel Hinged panel Hydrogen concentration Hydrogen concentration Pressure peak Pressure peak Vented explosion Vented explosion
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| GB/T 7714 | Wu, Zelong , Zhuang, Yanzhen , Guo, Jin . Effects of hydrogen concentration on flame propagation and pressure evolution during vented H2/air explosions in a vessel with a hinged panel [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2025 , 128 : 1-9 . |
| MLA | Wu, Zelong et al. "Effects of hydrogen concentration on flame propagation and pressure evolution during vented H2/air explosions in a vessel with a hinged panel" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 128 (2025) : 1-9 . |
| APA | Wu, Zelong , Zhuang, Yanzhen , Guo, Jin . Effects of hydrogen concentration on flame propagation and pressure evolution during vented H2/air explosions in a vessel with a hinged panel . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2025 , 128 , 1-9 . |
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为了氢气‑甲烷混合燃料的安全使用，利用内径和长度皆为300 mm的圆柱形密闭容器进行爆炸实验，研究了掺氢比（XH2=0~100%）和当量比（Φ=0.6~1.4）对火焰演化和爆炸压力特性的影响，并采用CHEMKIN软件分析了氢气‑甲烷‑空气预混气体的层流燃烧速度及其敏感性。结果表明，在当量比（Φ）不变的情况下，随着掺氢比（XH2）的增加，最大爆炸压力（pmax）、最大压力上升速率（（dp/dt）max）、爆炸指数（KG）以及层流燃烧速度增大，到达最大压力和最大压力上升速率的时间（tA和tB）逐渐缩短。点火后，火焰表面由最初的较为光滑，逐步形成蜂窝状的火焰胞格结构。在相同当量比（Φ）下，随着掺氢比（XH2）的增加，从点火到爆炸结束的时间大幅缩短，且在同一时刻，火焰半径增大，火焰表面皱褶增多。反应敏感性计算结果表明，基元反应H+O2⇌O+OH（R38）和H+CH3（+M）⇌CH4（+M）（R52）对层流燃烧速度的影响最大；关键自由基（H·、O·、OH·）的最大摩尔分数与层流燃烧速度正相关，且掺氢比（XH2）的增加，使得关键自由基的最大摩尔分数显著增大；基元反应R38和R84是影响关键自由基生成速率（ROP）的最主要反应。
Keyword ：
化学动力学分析 化学动力学分析 层流燃烧速度 层流燃烧速度 掺氢甲烷 掺氢甲烷 火焰 火焰 爆炸压力 爆炸压力
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| GB/T 7714 | 梅亮 , 郭进 , 黄时凯 et al. 密闭容器内氢气‑甲烷‑空气的爆炸特性 [J]. | 含能材料 , 2025 : 1-12 . |
| MLA | 梅亮 et al. "密闭容器内氢气‑甲烷‑空气的爆炸特性" . | 含能材料 (2025) : 1-12 . |
| APA | 梅亮 , 郭进 , 黄时凯 , 王金贵 , 高毅 . 密闭容器内氢气‑甲烷‑空气的爆炸特性 . | 含能材料 , 2025 , 1-12 . |
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Explosion venting technology is an effective means of reducing explosive hazards, and hydrogen volume fraction (chi) is one of the important parameters affecting its effectiveness. The vent covers, as a key part of the explosion venting application, consist of two types: inertia-free (e.g., membranes) and inertial (e.g., panels). chi has been extensively studied using inertial-free vent covers, but very limited work has been done using an inertial vent cover. Hence, the effects of chi, ranging from 0 to 1.0, on the vented H-2/CH4/air explosion were studied in a chamber with a hinged aluminum panel, and the explosion overpressure during venting was simulated by FLACS software. The results show that the flame bubble becomes larger and brighter with increasing chi. However, the time for the flame to travel through the vent (t(out)) and the opening angle of the hinged panel at the time of t(out) constantly decreases as chi increases from 0 to 1.0. In the tests with chi <= 0.6, p(3) caused by acoustically enhanced combustion becomes the pressure peak with the highest amplitude in the internal pressure profile, but the pressure peak p(2) induced by the external explosion dominates the internal pressure trace for chi > 0.6. In comparison to the H-2/CH4/air deflagration experiments using an inertialess vent cover, the shape of the external fireball is quite similar for smaller chi in the current study with an inertial vent panel. However, the use of the inertial vent panel results in a more flattened external fireball for larger chi. The highest amplitude of the external pressure peak (p(ext)) and the maximum reduced overpressure (p(red)) increase with increasing chi. Whether the studies are performed with inertial and inertialess vent covers or FLACS simulations, the formation time (Delta t) of p(ext )decreases linearly with increasing chi, but p(red) increases linearly with S-2(l). The explosion overpressure simulated by FLACS is relatively close to the experimental results, and in particular, the simulated p(red) agrees very well with the experimental value.
Keyword ：
Flame propagation Flame propagation H-2/CH4/Air explosion H-2/CH4/Air explosion Hinged vent panel Hinged vent panel Hydrogen volume fraction Hydrogen volume fraction Overpressure Overpressure
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| GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction [J]. | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 94 . |
| MLA | Huang, Shikai et al. "Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction" . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES 94 (2025) . |
| APA | Huang, Shikai , Guo, Jin , Mei, Liang , Wang, Fang , Wang, Changjian , Lin, Jin . Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 94 . |
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The effects of ignition position and hydrogen concentration on the pressure build-up and flame evolution during H2/air deflagrations were studied in a 1-m3 vessel with hinged aluminum vent panel. Three ignition positions were tested: TI (top ignition), CI (central ignition), and BI (bottom ignition), with hydrogen concentrations ranging from 12 vol% to 27 vol%. Explosion overpressure was simulated using the CFD software FLACS and validated against experimental data. Results revealed that Helmholtz oscillations occurred only for 12-18 vol% H2/air mixtures at TI. Three overpressure peaks inside the vessel were identified: P1, P2, and Pvib, caused by the opening of the aluminum panel, interplay between the external explosion and the venting process, and flame-acoustic oscillations, respectively. Compared to inertia-free venting, the aluminum panel significantly increased P1 at TI. For CI, the panel enhances the external explosion, but it weakens the explosion at BI. When hydrogen concentration exceeded 18 vol%, the maximum explosion overpressure (Pmax) at all ignition positions increased with increasing hydrogen concentration. An external overpressure peak, Pext, was observed at all ignition positions for hydrogen concentration above 18 vol%. For TI, an additional overpressure peak, Popen, caused by the propagation of the flame wave after the aluminum panel opening, was recorded. The maximum external overpressure (Pe-max) increased with hydrogen concentration. The simulated values of Pmax and Pe-max closely matched the experimental data for CI. However, simulations overestimated the experimental results for hydrogen concentration above 18 vol% at TI and BI. Additionally, the vent panel obstructed external flame propagation.
Keyword ：
Hydrogen concentration Hydrogen concentration Hydrogen deflagration Hydrogen deflagration Ignition position Ignition position Vent panel Vent panel
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| GB/T 7714 | Li, Jialin , Zhang, Fan , Guo, Jin et al. Study on the deflagrations of H2/air in a 1-m3 vessel with a hinged aluminum vent panel: Effects of hydrogen concentration and ignition position [J]. | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 98 . |
| MLA | Li, Jialin et al. "Study on the deflagrations of H2/air in a 1-m3 vessel with a hinged aluminum vent panel: Effects of hydrogen concentration and ignition position" . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES 98 (2025) . |
| APA | Li, Jialin , Zhang, Fan , Guo, Jin , Wu, Zelong , Wu, Binhua . Study on the deflagrations of H2/air in a 1-m3 vessel with a hinged aluminum vent panel: Effects of hydrogen concentration and ignition position . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 98 . |
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To investigate the microwave heating mechanism of composite minerals, a circumferential stirring model based on the Arbitrary Lagrangian-Eulerian (ALE) method was established by COMSOL Multiphysics software. This model aims to study the temperature rise characteristics of mineral models with different component structures and proportions. The results show that the heating efficiency and uniformity of the mineral are higher in the stirred heating model with a 5 cm copper disc rotating at (π/3) rad/s compared to the non-stirred heating model; The different component structures of the composite mineral result in different electromagnetic wave distributions, which induces the microwave heating efficiency of the py-rite-enclosed calcite model is lower than the calcite-enclosed pyrite model; In the calcite-en-closed pyrite model, the variation of pyrite thickness changes the phase of electromagnetic wave, leading to the displacement of hot and cold spots in the mineral. Furthermore, when comparing the pyrite thicker and thinner than the penetration depth, there is a significant disparity in the incident electromagnetic wave intensity, resulting in noticeable differences in electric field strength; At the same component proportion, the overall electric field of heterogeneous minerals is lower and more stable, and the electric field intensity between components is closer than in composite homogeneous minerals; With the proportion of pyrite increases, the temperature variation of heterogeneous minerals after 30 s microwave heating can be divided into three regions: small peak region (0-10%), large peak region (10% - 50%), and stable region (50% - 75%), and the temperature differences between components gradually decrease. © 2024 China University of Mining and Technology. All rights reserved.
Keyword ：
Calcite Calcite Circular waveguides Circular waveguides Efficiency Efficiency Electric fields Electric fields Electromagnetic waves Electromagnetic waves Microwave heating Microwave heating Mining Mining Pyrites Pyrites
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| GB/T 7714 | Long, Shengyi , Hong, Yidu , Sun, Xiaowan et al. Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model [J]. | Journal of China University of Mining and Technology , 2024 , 53 (2) : 318-333 . |
| MLA | Long, Shengyi et al. "Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model" . | Journal of China University of Mining and Technology 53 . 2 (2024) : 318-333 . |
| APA | Long, Shengyi , Hong, Yidu , Sun, Xiaowan , Yang, Fuqiang , Guo, Jin , Nie, Wen . Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model . | Journal of China University of Mining and Technology , 2024 , 53 (2) , 318-333 . |
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Although ammonia-hydrogen blended fuel has become a research hotspot, it is essential to recognize that adding hydrogen to ammonia increases the potential explosion hazard before considering the development of ammoniahydrogen fuel. In this study, the effect of vent area on vented deflagrations of ammonia-hydrogen-air mixtures is investigated in a 1-m-long horizontal rectangular duct with a right end opening at an initial temperature of 293 K and an initial pressure of 101 kPa. A dimensionless vent coefficient K-v is used to define the vent area in this work to clarify the evolution of flame structures and overpressure inside and outside the duct. For a specific K-v, the amplitude of the maximum internal explosion overpressure (P-max) monitored at the left end of the duct (LE) has a greater difference compared with other pressure monitoring points. The maximum amplitude of P(max )is always reached at the LE for K-v <= 3.2, while the difference in the maximum amplitude of P(max )between different monitoring points decreased significantly for K-v > 3.2. With the increasing of K(v )from 2.2 to 20.1, P(max )obtained at the right end of the duct (RE) and the center of the duct increases monotonously, but P(max )monitored at the LE shows a non-monotonic increasing trend. A spike structure of penetrating flame bubbles resulting from negative pressure balance is only observed inside the duct for K-v <= 5.6. Two types of oscillations (Helmholtz and Acoustic oscillations) can be distinguished in some tests, and only acoustic oscillations of overpressure can be clearly found in tests with K-v > 7.8. With the increasing of K(v )from 2.2 to 20.1, the shape of the external fireball will change significantly. As Kv increases from 2.2 to 5.6, the external fireball shapes are always mushroom-shaped. However, the shapes of the fireball become elongated for K-v > 7.8, and even the external fireball presents a jet shape for K-v = 20.1. With the increasing of K-v from 2.2 to 20.1, The maximum external overpressure increases first, thereafter decreases, and finally increases.
Keyword ：
Ammonia-hydrogen-air mixtures Ammonia-hydrogen-air mixtures External explosion External explosion Flame behavior Flame behavior Overpressure Overpressure Vent area Vent area
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| GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct [J]. | FUEL , 2024 , 362 . |
| MLA | Huang, Shikai et al. "Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct" . | FUEL 362 (2024) . |
| APA | Huang, Shikai , Guo, Jin , Mei, Liang , Yang, Zexuan , Wang, Hongyan , Li, Yiming . Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct . | FUEL , 2024 , 362 . |
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Although ammonia as a carbon-free fuel is regarded as an energy source worthy of significant development, how to address the shortcomings of its poor combustion properties has been a hot topic of research. Hydrogen enrichment is a promising solution to improve the combustion properties of ammonia, but at the same time, the potential explosion risk will inevitably be raised. In this paper, the effects of hydrogen volumetric fraction (chi) in NH3/H-2 on the NH3/H-2/air deflagrations were experimentally investigated in a rectangular duct with an end-opening at an initial pressure and temperature of 101 kPa and 298 K, where chi was varied from 0.1 to 0.9. Results demonstrate that flame propagation and overpressure profiles inside and outside the chamber depend on chi. Buoyancy plays a significant role in flame propagation at chi = 0.1. More prominent deformation of the flame front propagating toward the closed end (CE) was observed in the experiments with higher chi s. Helmholtz oscillations of the flame occurred in all tests, which resulted in pressure oscillations with a decreasing frequency as chi was increased. Acoustically enhanced combustion of NH3/H-2/air remained at the CE, appeared when chi >= 0.7, and acoustic-type oscillations of the internal explosion overpressure and a pressure peak of p(2) formed in these tests. The amplitude of p(2) dropped as chi varied from 0.7 to 0.9. A proportional relationship between the highest explosion overpressure inside the chamber (p(max)) and the square of the laminar burning velocity of NH3/H-2/air (s(l)(2)). When chi >= 0.3, a dominant pressure peak (p(ext)) caused by the external explosion appeared in the external overpressure profiles, and its amplitude increased as chi varied from 0.3 to 0.9.
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| GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions [J]. | ENERGY & FUELS , 2024 , 38 (10) : 9110-9119 . |
| MLA | Huang, Shikai et al. "Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions" . | ENERGY & FUELS 38 . 10 (2024) : 9110-9119 . |
| APA | Huang, Shikai , Guo, Jin , Mei, Liang , Yang, Zexuan . Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions . | ENERGY & FUELS , 2024 , 38 (10) , 9110-9119 . |
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In this work, the coupling of explosion venting (vent size) and inerting (N2) on H2/air deflagration was investigated. Experiments were carried out in a vertical rectangular duct with an upper opening at an initial temperature and pressure of 280 K and 101 kPa, and a vent coefficient Kv was employed to replace the vent size to elucidate its effect on pressure buildup and flame propagation during H2/N2/air deflagration. In the present study, the internal pressure profile is monitored by three pressure sensors, PS1-3, which are installed at the bottom, center, and top of the duct, respectively, and the external pressure profile is obtained by PS4. The results show that the maximum internal overpressure (pmax) recorded by PS1-3 all increase with increasing Kv, but pmax obtained from PS2 and PS3 tend to increase linearly. For a given Kv, the maximum and minimum amplitudes of pmax are measured by PS1 and PS3, respectively. Specifically, the greater the distance between the pressure sensor and the upper opening, the greater the amplitude of pmax. The relationship between the maximum reduced explosion pressure (pred) and Kv is investigated, where pred is defined as the highest pmaxfor a specific Kv. As Kv increases from 2.2 to 11.9, pred increases from 26.25 kPa to 88 kPa. The maximum external flame velocity (Vext) increases from 83 m/s to 454 m/s with increasing Kvfrom 2.2 to 11.9. The amplitude of the maximum external overpressure (pext) first increases and decreases with an increase in Kvfrom 2.2 to 11.9. The formation time (Delta t) of pext decreases and then increases and finally decreases with increasing Kvfrom 2.2 to 11.9. When Kv is increased from 2.2 to 4.1, all external fireballs are presented as mushroom shapes, but the external fireballs are gradually transformed into jet shapes for Kv >= 7.8. Two pressure oscillations, including Helmholtz oscillations and acoustic oscillations, are found. Acoustic oscillations are found in all tests, but Helmholtz oscillations are only observed for Kv <= 4.1.
Keyword ：
External explosion External explosion Flame Flame Nitrogen inerting Nitrogen inerting Vent size Vent size
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| GB/T 7714 | Huang, Shikai , Wang, Fang , Xu, Caijun et al. Effect of vent size on vented H2/N2/air deflagration [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 84 : 881-888 . |
| MLA | Huang, Shikai et al. "Effect of vent size on vented H2/N2/air deflagration" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 84 (2024) : 881-888 . |
| APA | Huang, Shikai , Wang, Fang , Xu, Caijun , Guo, Jin , Mei, Liang , Yang, Zexuan . Effect of vent size on vented H2/N2/air deflagration . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 84 , 881-888 . |
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Explosion venting is the most commonly used technique to reduce the hazard from accidental deflagration of combustible gases. Since less attention is paid to the influence of inertial vent on vented H2/CH4/air deflagration, the effects of area density (Ws) of a hinged inertial cover on the pressure profile and flame behavior during H2/ CH4/air deflagration, with hydrogen volume fraction in fuel (chi H2) being 0.5 and 0.8, were investigated by covering the vent using aluminum plates with various thicknesses. The results show that the interval between ignition and the moment the flame just travels through the vent (tout) is almost independent of Ws, but the opening angle of the panel at the time of tout is closely related to Ws. For a given chi H2, the opening angle at the time of tout decreases with an increase in Ws. For a certain Ws, the opening angle of the panel is smaller for chi H2 = 0.8 in comparison with the tests at chi H2 = 0.5. In the test with higher Ws, the external fireball becomes more flattened. In tests at chi H2 = 0.5, p3 induced by acoustic oscillations dominates the internal overpressure, but p2 resulting from the external explosion becomes the dominant pressure peak at chi H2 = 0.8. The maximum reduced overpressure (pred) and maximum external overpressure (pext) are almost independent of Ws at chi H2 = 0.5. However, in tests at chi H2 = 0.8, pred and pext increase sharply with an increase in Ws from 0 kg/m2 to 2.7 kg/m2, but there is relatively little variation in pred and pext as Ws continues to increase from 2.7 kg/m2 to 24.3 kg/m2. Except for the test with Ws = 0 kg/m2, for a specific Ws, pred and pext at chi H2 = 0.8 are always greater than those at chi H2 = 0.5.
Keyword ：
Flame Flame Hinged vent panel Hinged vent panel Hydrogen/methane/air explosion Hydrogen/methane/air explosion Overpressure Overpressure
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| GB/T 7714 | Guo, Jin , Huang, Shikai , Wang, Fang et al. Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber [J]. | FUEL , 2024 , 374 . |
| MLA | Guo, Jin et al. "Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber" . | FUEL 374 (2024) . |
| APA | Guo, Jin , Huang, Shikai , Wang, Fang , Xu, Caijun , Wu, Zelong , Zhang, Fan et al. Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber . | FUEL , 2024 , 374 . |
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