Query：
学者姓名：蔡平伟
Refining：
Year
Type
Indexed by
Source
Complex
Former Name
Co-
Language
Clean All
Abstract ：
Herein, cobalt ammine complexes are combined with alkali-resistant polyoxoniobates (PONbs) at the molecular level to obtain two new organic-inorganic hybrid Co-containing PONbs with the same polyanions but different Co contents. The Co-containing PONb with higher Co content exhibits superior hydrogen evolution reaction (HER) activity under highly alkaline conditions, which is better than the results for the similar Cu-containing PONb, highlighting the critical role of cobalt in improving HER performance. This study provides a new insight into the relationship between the structural properties of metal complexes during electrocatalysis.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Chen, Chun-Xia , Duan, Shui-Lin , Zhang, Xiao-Yue et al. Organic-inorganic hybrid Co-containing polyoxoniobates as hydrogen evolution catalysts in alkaline media [J]. | DALTON TRANSACTIONS , 2025 , 54 (9) : 3591-3596 . |
| MLA | Chen, Chun-Xia et al. "Organic-inorganic hybrid Co-containing polyoxoniobates as hydrogen evolution catalysts in alkaline media" . | DALTON TRANSACTIONS 54 . 9 (2025) : 3591-3596 . |
| APA | Chen, Chun-Xia , Duan, Shui-Lin , Zhang, Xiao-Yue , Sun, Rong-Zhi , Cai, Ping-Wei , Sun, Cai et al. Organic-inorganic hybrid Co-containing polyoxoniobates as hydrogen evolution catalysts in alkaline media . | DALTON TRANSACTIONS , 2025 , 54 (9) , 3591-3596 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
A series of novel cage-like transition-metal (TM) incorporated heteropolyoxoniobates {TM4Nb64O200} (1-TM, TM = Ni, Cu, Mn, Cd) were hydrothermally synthesized and isolated as salts of mixed K+ and [CN3H6]+. As a result of transition metal ions incorporation, the charge distribution, redox potential, and active sites of the formed polyoxoniobates (PONbs) are variants, leading to differences in their electrocatalytic hydrogen evolution reaction (HER). Among these compounds, 1-Ni showed the best HER activity with an overpotential of 560 mV at 10 mA cm-2 and a minimum Tafel slope of 405.8 mV dec-1.
Keyword ：
Cage-like Cage-like Hydrogen evolution reaction Hydrogen evolution reaction Polyoxometalate Polyoxometalate Transition metal substitution Transition metal substitution
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Wu, Lan , Hu, Fen , Sun, Rong-Zhi et al. Development of cage-like transition-metal incorporated polyoxoniobates for hydrogen evolution reaction electrocatalysts [J]. | JOURNAL OF SOLID STATE CHEMISTRY , 2025 , 345 . |
| MLA | Wu, Lan et al. "Development of cage-like transition-metal incorporated polyoxoniobates for hydrogen evolution reaction electrocatalysts" . | JOURNAL OF SOLID STATE CHEMISTRY 345 (2025) . |
| APA | Wu, Lan , Hu, Fen , Sun, Rong-Zhi , Xia, Wen-Jun , Zeng, Qing-Xin , Cai, Ping-Wei et al. Development of cage-like transition-metal incorporated polyoxoniobates for hydrogen evolution reaction electrocatalysts . | JOURNAL OF SOLID STATE CHEMISTRY , 2025 , 345 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Electrochemical carbon dioxide reduction to multi-carbon (C2+) products presents a significant opportunity for converting greenhouse gases into valuable fuels and feedstocks. The development of highly active and stable catalysts remains a critical challenge. In this study, we report the design and synthesis of cyclodextrin-modified Cu/Cu2O electrocatalysts, which exhibit remarkable efficiency in driving the CO2 electroreduction process towards C2+ products. Our optimized catalyst achieves a C2+ Faradaic efficiency exceeding 50 % at a high current density of over 200 mA cm(-2). Experimental findings, supported by density functional theory (DFT) calculations, reveal that cyclodextrin plays a dual role in stabilizing Cu+ and increasing the surface density of hydroxyl radicals. This dual function greatly benefits for enhancing *CO intermediate adsorption and promotes *CHO formation, thereby facilitating the crucial dimerization step for the formation of C2+ products. This work provides valuable insights into the development of highly active and selective electrocatalysts by carefully tuning the local catalytic environment, potentially opening new avenues for functionalizing electrocatalysts for future research in this area.
Keyword ：
C2+ Selectivity C2+ Selectivity Carbon dioxide reduction Carbon dioxide reduction *CO adsorption *CO adsorption Cu/Cu2O Cu/Cu2O Cyclodextrin-modification Cyclodextrin-modification
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Cai, Pingwei , Weng, Wanting , Han, Yue et al. Boosting multi-carbon products selectivity of carbon dioxide reduction via bifunctional cyclodextrin-modification on copper/copper(I) oxide electrocatalysts [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 680 : 453-458 . |
| MLA | Cai, Pingwei et al. "Boosting multi-carbon products selectivity of carbon dioxide reduction via bifunctional cyclodextrin-modification on copper/copper(I) oxide electrocatalysts" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 680 (2025) : 453-458 . |
| APA | Cai, Pingwei , Weng, Wanting , Han, Yue , Li, Xin , Lu, Zhiwen , Wen, Zhenhai . Boosting multi-carbon products selectivity of carbon dioxide reduction via bifunctional cyclodextrin-modification on copper/copper(I) oxide electrocatalysts . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 680 , 453-458 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Rechargeable Zn-air batteries (ZABs) are considered highly competitive technologies for meeting the energy demands of the next generation, whether for energy storage or portable power. However, their practical application is hindered by critical challenges such as low voltage, CO2 poisoning at the cathode, low power density, and poor charging efficiency Herein, a rechargeable hybrid alkali/acid Zn-air battery (h-RZAB) that effectively separates the discharge process in an acidic environment from the charging process in an alkaline environment, utilizing oxygen reduction reaction (ORR) and glycerol oxidation reaction (GOR) respectively is reported. Compared to previously reported ZABs, this proof-of-concept device demonstrates impressive performance, exhibiting a high power density of 562.7 mW cm-2 and a high operating voltage during discharging. Moreover, the battery requires a significantly reduced charging voltage due to the concurrent utilization of biomass-derived glycerol, resulting in practical and cost-effective advantages. The decoupled system offers great flexibility for intermittently generated renewable power sources and presents cost advantages over traditional ZABs. As a result, this technology holds significant promise in opening avenues for the future development of renewable energy-compatible electrochemical devices. A rechargeable hybrid Zn-air battery (h-RZAB) is proposed by decoupling charging and discharging processes in separate alkaline and acidic electrolytes. which demonstrates a remarkable power density of 562.7 mW cm-2 and maintains a high operating voltage during discharging. Additionally, the battery requires a significantly reduced charging voltage due to the concurrent utilization of biomass-derived glycerol. image
Keyword ：
alkali/acid electrolytes alkali/acid electrolytes glycerol oxidation reaction glycerol oxidation reaction high power density high power density hybrid Zn-air battery hybrid Zn-air battery reduced charging voltage reduced charging voltage
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Yin, Ximeng , Sun, Wei , Chen, Kai et al. High-Power-Density Rechargeable Hybrid Alkali/Acid Zn-Air Battery Performance Through Value-Added Conversion Charging [J]. | ADVANCED SCIENCE , 2024 , 11 (23) . |
| MLA | Yin, Ximeng et al. "High-Power-Density Rechargeable Hybrid Alkali/Acid Zn-Air Battery Performance Through Value-Added Conversion Charging" . | ADVANCED SCIENCE 11 . 23 (2024) . |
| APA | Yin, Ximeng , Sun, Wei , Chen, Kai , Lu, Zhiwen , Chen, Junxiang , Cai, Pingwei et al. High-Power-Density Rechargeable Hybrid Alkali/Acid Zn-Air Battery Performance Through Value-Added Conversion Charging . | ADVANCED SCIENCE , 2024 , 11 (23) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
In this work, a novel organodiphosphate-containing inorganic-organic hybrid polyoxoniobate (PONb) ring {(PO3CH2CH2PO3H)(4)Nb8O16}(4-) (Nb8P8) has been achieved by a one-pot hydrothermal method. The ring is constructed from a tetragonal {Nb8O36} motif and four {PO3CH2CH2PO3H} ligands. Interestingly, Nb8P8 can be joined together via K-H2O clusters {K-2(H2O)(4)(OH)(2)} to form one-dimensional chains {[K-2(H2O)(4)(OH)(2)]Nb8P8}(n) and further linked by {Cu(en)(2)}(2+) (en = ethylenediamine) complexes, resulting in a three-dimensional supramolecular framework {[Cu(en)(2)](2)[K-2(H2O)(4)(OH)(2)]Nb8P8}3enH2O (1). 1 exhibits good chemical and thermal stability and has a high water vapor adsorption capacity of <= 224 cm(3) g(-1) (22.71 molmol(-1)) at 298 K, outperforming most of the known polyoxometalate-based materials. Impedance measurements prove that 1 can transfer protons with moderate conductivity. This study not only contributes to the structural diversity of organodiphosphate-containing PONbs and PONb rings but also provides a reference for the development of PONb-based materials with unique performance.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Cong, Yu-Chen , Xiao, Hui-Ping , Cai, Ping-Wei et al. An Organodiphosphate-Containing Polyoxoniobate Ring and Its Assembly into a Three-Dimensional Framework through Hydrogen Bonding [J]. | INORGANIC CHEMISTRY , 2024 , 63 (20) : 9204-9211 . |
| MLA | Cong, Yu-Chen et al. "An Organodiphosphate-Containing Polyoxoniobate Ring and Its Assembly into a Three-Dimensional Framework through Hydrogen Bonding" . | INORGANIC CHEMISTRY 63 . 20 (2024) : 9204-9211 . |
| APA | Cong, Yu-Chen , Xiao, Hui-Ping , Cai, Ping-Wei , Sun, Cai , Sun, Yan-Qiong , Qi, Ming-Qiang et al. An Organodiphosphate-Containing Polyoxoniobate Ring and Its Assembly into a Three-Dimensional Framework through Hydrogen Bonding . | INORGANIC CHEMISTRY , 2024 , 63 (20) , 9204-9211 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Selective uptake and elution of trace amounts of hazardous radioactive Sr-90 from large-scale high-level liquid waste (HLW) is crucial for sustainable development. Here, we propose a site differentiation strategy, based on the presence of distinct selective metal capture sites (concavity site and tweezer site) within the giant polyoxoniobate (PONb) nanoclusters of an all-inorganic PONb framework (FZU-1). Through this strategy, FZU-1 can not only effectively remove 98.9% of Sr2+ from simulated nuclear liquid waste, performing best among the reported Sr adsorbents, but also achieve desorption of adsorbed Sr2+ ions by selectively loading Na+ ions, thus enabling the recycling of FZU-1. Based on the well-defined single-crystal structures and theoretical studies, it can be revealed that the rapid and selective uptake of Sr2+ is attributed to the strong binding energy between the Sr2+ ions and the concavity sites. The effective elution of Sr2+, on the other hand, stems from the preferential binding of Na+ ions at the tweezer sites, elevating the cluster's electrostatic potential and indirectly facilitating the elution of Sr2+ ions. The exceptional stability of FZU-1, along with its rapid and selective Sr2+ capture and elution capabilities, positions it as a promising candidate for large-scale nuclear waste treatment and groundwater remediation applications.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Liu, Yi-Xin , Wu, Ping-Xin , Dai, Jing-Yi et al. Site differentiation strategy for selective strontium uptake and elution within an all-inorganic polyoxoniobate framework [J]. | NATURE COMMUNICATIONS , 2024 , 15 (1) . |
| MLA | Liu, Yi-Xin et al. "Site differentiation strategy for selective strontium uptake and elution within an all-inorganic polyoxoniobate framework" . | NATURE COMMUNICATIONS 15 . 1 (2024) . |
| APA | Liu, Yi-Xin , Wu, Ping-Xin , Dai, Jing-Yi , Cai, Ping-Wei , Sun, Cai , Zheng, Shou-Tian . Site differentiation strategy for selective strontium uptake and elution within an all-inorganic polyoxoniobate framework . | NATURE COMMUNICATIONS , 2024 , 15 (1) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Nature seems to favor the formation of closed anion-templated silver clusters. How precisely to create non-closed sliver clusters remains an interesting challenge. In this work, we propose that the use of transition-metal-coordination-cluster substituted polyoxometalates (TMCC-substituted POMs) as templates is an effective synthetic strategy for creating the non-closed silver clusters, as demonstrated by the obtainment of four types of rare non-closed silver cluster species of Ag38-TM (TM = Co, Ni or Zn), Ag37-Zn, {Ag37-Zn}infinity and Ag36-TM (TM = Co, Ni). The idea of the strategy is to employ the TMCC-substituted POMs containing cluster modules with different bond interactions with Ag+ ions as templates to guide the formation of the non-closed silver clusters. For example, TMCC-substituted POM clusters are used as templates in this work, which contain POM modules that can coordinate with the Ag+ ions and TMCC moieties that are difficult to coordinate with the Ag+ ions, leading to the Ag+ ions being unable to form closed clusters around TMCC-substituted POM templates. The work demonstrates a promising approach to developing intriguing and unexplored non-closed silver clusters. Using transition-metal-coordination-cluster-substituted polyoxometalates as templates, four kinds of rare non-closed silver cluster species are obtained, demonstrating a promising strategy for the development of uncommon non-closed silver clusters.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Rui, Ge , Cai, Ping-Wei , Cai, Sun et al. Development of non-closed silver clusters by transition-metal-coordination-cluster substituted polyoxometalate templates [J]. | CHEMICAL SCIENCE , 2024 , 15 (31) : 12543-12549 . |
| MLA | Rui, Ge et al. "Development of non-closed silver clusters by transition-metal-coordination-cluster substituted polyoxometalate templates" . | CHEMICAL SCIENCE 15 . 31 (2024) : 12543-12549 . |
| APA | Rui, Ge , Cai, Ping-Wei , Cai, Sun , Sun, Yan-Qiong , Li, Xin-Xiong , Zheng, Shou-Tian . Development of non-closed silver clusters by transition-metal-coordination-cluster substituted polyoxometalate templates . | CHEMICAL SCIENCE , 2024 , 15 (31) , 12543-12549 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Efficient electrocatalysts for the oxygen evolution reaction (OER) are paramount to the development of electrochemical devices for clean energy and fuel conversion. However, due to the complicated structures of heterogeneous electrocatalysts, it is a great challenge to elucidate the intrinsic activity of the catalytic sites on their surfaces. In this work, we report the synthesis and characterisation of a 9-Co(ii)-containing trimetric cyclic polyoxogermanotungstate cluster, K9Na3H7[Co9(H2O)6(OH)3(SeO3)2(B-alpha-GeW9O34)3]39H2O (Co9-POT), which exhibits distinct physicochemical properties and a well-defined single-crystal structure. The triangular nonacobalt(ii)-oxo cluster {Co9(H2O)6(OH)3(SeO3)2} ({Co9Se2}) in Co9-POT consists of three identical quasi-cubane {Co3O4} subunits capped by two SeO32- anions. Co9-POT exhibits electrocatalytic activity for the alkaline OER, with a turnover frequency (TOF) of the catalytically active site Co of 0.18 s-1 at an overpotential of 400 mV. In situ operational Raman and electrochemical impedance spectroscopy techniques explicitly capture the dynamic evolution of the OER process. This work provides insights into the structure-performance relationship in the OER process and the design of electrocatalysts with high atomic activity. A structurally well-defined 9-Co(ii)-containing trimetric cyclic polyoxogermanotungstate, K9Na3H7[Co9(H2O)6(OH)3(SeO3)2(B-alpha-GeW9O34)3]39H2O (Co9-POT), exhibits electrocatalytic activity for the oxygen evolution reaction (OER) in alkaline media.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Li, Da-Huan , Jia, Lei , Liu, Yi-Xin et al. A Co-containing polyoxogermanotungstate for alkaline electrocatalytic water oxidation [J]. | INORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (20) : 7049-7057 . |
| MLA | Li, Da-Huan et al. "A Co-containing polyoxogermanotungstate for alkaline electrocatalytic water oxidation" . | INORGANIC CHEMISTRY FRONTIERS 11 . 20 (2024) : 7049-7057 . |
| APA | Li, Da-Huan , Jia, Lei , Liu, Yi-Xin , Sun, Cai , Li, Xin-Xiong , Cai, Ping-Wei et al. A Co-containing polyoxogermanotungstate for alkaline electrocatalytic water oxidation . | INORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (20) , 7049-7057 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Atomically precise low-nuclearity (n<10) silver nanoclusters (AgNCs) have garnered significant interest due to their size-dependent optical properties and diverse applications. However, their synthesis has remained challenging, primarily due to their inherent instability. The present study introduces a new feasible approach for clustering silver ions utilizing highly negative and redox-inert polyoxoniobates (PONbs) as all-inorganic ligands. This strategy not only enables the creation of novel Ag-PONb composite nanoclusters but also facilitates the synthesis of stable low-nuclearity AgNCs. Using this method, we have successfully synthesized a small octanuclear rhombic [Ag-8](6+) AgNC stabilized by six highly negative [LiNb27O75](14-) polyoxoanions. This marks the first PONb-protected superatomic AgNC, designated as {Ag-8@(LiNb27O75)(6)} (Ag-8@Nb-162), with an aesthetically spherical core-shell structure. The crystalline Ag-8@Nb-162 is stable under ambient conditions, What's more, it is water-soluble and able to maintain its molecular cluster structure intact in water. Further, the stable small [Ag-8](6+) AgNC has interesting temperature- and pH-dependent reversible fluorescence response, based on which a multiple optical encryption mode for anti-counterfeit technology was demonstrated. This work offers a promising avenue for the synthesis of fascinating and stable PONb-protected AgNCs and sheds light on the development of new-type optical functional materials.
Keyword ：
fluorescence fluorescence macromolecules macromolecules nanoclusters nanoclusters polyoxoniobate polyoxoniobate silver silver
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Hong, Li-Hao , Yue, Sheng-Nan , Huang, Xing et al. Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 63 (29) . |
| MLA | Hong, Li-Hao et al. "Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 63 . 29 (2024) . |
| APA | Hong, Li-Hao , Yue, Sheng-Nan , Huang, Xing , Sun, Cai , Cai, Ping-Wei , Sun, Yan-Qiong et al. Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 63 (29) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Integrating Fenton chemistry and nanomedicine into cancer therapy has significantly promoted the development of chemodynamic therapy (CDT). Nanoscale polyoxometalates (POMs), with their reversible redox properties, exhibit promising potential in developing outstanding CDT drugs by exploring their Fenton-like catalytic reactivity in tumor environments. However, such research is still in its infancy due to the challenges of acquiring POMs that are both easily prepared and possess ideal therapeutic effects, physiological solubility, biocompatibility and safety. In this work, we report the synthesis of a new crystalline antimonotungstate {Dy2Sb2W7O23(OH)(DMF)2(SbW9O33)2} (1, DMF=N, N-dimethylformamide) with gram-scale high yield via a facile "one-pot" solvothermal reaction. 1 exhibits not only a soluble and water-stable POM nanocluster, but also excellent catalytic activity for hydroxyl radical-generating Fenton-like reactions. Further biomedical studies reveal that 1 can trigger cell apoptosis and promote lipid peroxidation, exhibiting high cytotoxicity and selectivity towards B16-F10 mouse melanoma cancer cells with an IC50 value of 4.75 mu M. Especially, 1 can inhibit melanoma growth in vivo with favorable biosafety, achieving a 5.2-fold reduction in tumor volume and a weight loss of 76.0 % at the dose of 70 mu g/kg. This research not only demonstrates the immense potential of antimonotungstates in CDT drug development for the first time but also provides new insights and directions for the development of novel anticancer drugs.
Keyword ：
antitumor antitumor chemodynamic therapy chemodynamic therapy nanocluster nanocluster polyoxometalate polyoxometalate polyoxotungstate polyoxotungstate
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Xiao, Hui-Ping , Du, Man-Yi , Sun, Xian-Bin et al. A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 64 (8) . |
| MLA | Xiao, Hui-Ping et al. "A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 64 . 8 (2024) . |
| APA | Xiao, Hui-Ping , Du, Man-Yi , Sun, Xian-Bin , Xu, Ruo-Fei , Li, Dong-Miao , Yue, Sheng-Nan et al. A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 64 (8) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Export
| Results： |
Selected to |
| Format： |
