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学者姓名:黄兴
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2D layered Sb2Te3 has emerged as a promising material for thermoelectric and optoelectronic applications. However, fabricating single-crystalline Sb2Te3 flakes with the desired size, shape, and orientation remains challenging due to limited understanding of their growth mechanisms. In this study, how the substrate, growth time, carrying gas, and its flow rate influence the growth behavior of Sb2Te3 flakes through a chemical vapor deposition (CVD) approach combined with van der Waals epitaxy (vdWE) is elucidated. By fine-tuning these growth parameters, Sb2Te3 flakes with controlled size, morphology, and crystal orientation on mica substrates are successfully achieved. Notably, a record-high anisotropy ratio in Sb2Te3 flakes exceeding 10,000 is obtained. Photodetectors fabricated from these flakes demonstrate excellent optoelectronic performance, achieving a responsivity of 1.34 A W-1, a large external quantum efficiency (EQE) of 332%, and a high external specific detectivity (D*) of 1.38 x 10(10) Jones under a light power density of 10 mW cm(-2). Moreover, the device exhibits modulated photocurrent under pulsed light, suggesting potential applications in optoelectronic synapses. This work provides detailed insights into the controlled growth of single-crystalline Sb2Te3 flakes, offering unprecedented opportunities for exploring their fundamental properties in the development of next-generation thermoelectric and optoelectronic devices.
Keyword :
2D Sb2Te3 2D Sb2Te3 controlled growth controlled growth optoelectronic devices optoelectronic devices single-crystalline single-crystalline van der waals epitaxy van der waals epitaxy
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GB/T 7714 | Yang, Shunhang , Liu, Mengyu , Yue, Shengnan et al. Unveiling Controlled Growth of Single-Crystalline Layered Sb2Te3 Via Van Der Waals Epitaxy for Visible-Light Photodetectors and Optoelectronic Synapses [J]. | ADVANCED FUNCTIONAL MATERIALS , 2025 . |
MLA | Yang, Shunhang et al. "Unveiling Controlled Growth of Single-Crystalline Layered Sb2Te3 Via Van Der Waals Epitaxy for Visible-Light Photodetectors and Optoelectronic Synapses" . | ADVANCED FUNCTIONAL MATERIALS (2025) . |
APA | Yang, Shunhang , Liu, Mengyu , Yue, Shengnan , Liu, Panpan , Lin, Huiting , Gao, Tongtong et al. Unveiling Controlled Growth of Single-Crystalline Layered Sb2Te3 Via Van Der Waals Epitaxy for Visible-Light Photodetectors and Optoelectronic Synapses . | ADVANCED FUNCTIONAL MATERIALS , 2025 . |
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The mechanism of nacre formation in gastropods involves a vesicular system that transports organic and mineral precursors from the mantle epithelium to the mineralization chamber. Between them lies the surface membrane, a thick organic structure that covers the mineralization chamber and the forming nacre. The surface membrane is a dynamic structure that grows by the addition of vesicles on the outer side and recedes by the formation of interlamellar membranes on the inner side. By using a combination of electron microscopy imaging and spectroscopy, we have monitored the journey of the vesicles from the mantle epithelium to the mineralization chamber, focusing on the elemental composition of the organic structures at each stage. Our data reveal that transport occurs in lipid bilayer vesicles through exocytosis from the outer mantle epithelium. After release into the surface membrane, chitin undergoes a process of self-assembly and interaction with proteins, resulting in progressive changes of the internal structure of the surface membrane until the final structure of the interlamellar membranes is acquired. Finally, these detach from the inner side of the surface membrane. Elemental analysis revealed the transport of a considerable amount of calcium bound to proteins, likely forming calcium-protein complexes. Statement of significance: The formation of nacre tablets occurs through the incorporation of organic and mineral precursors extruded from the mantle epithelium. Although much attention has been paid to the presence of amorphous phases in recent decades, the calcium transport system has not yet been elucidated. We have monitored the packaging of organic and mineral precursors in the form of vesicles from the mantle epithelium to the mineralization chamber. We have shown that the surface membrane represents the zone where chitin and protein polymerization takes place, acquiring the final structure for the formation of interlamellar membranes. Interestingly, these organic structures transport a considerable amount of organic calcium into the mineralization chamber, which support a transport system based on acidic calcium-binding proteins.
Keyword :
Biomineralization Biomineralization Calcium transport Calcium transport Nacre Nacre Surface membrane Surface membrane Vesicles Vesicles
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GB/T 7714 | Macias-Sanchez, Elena , Huang, Xing , Willinger, Marc G. et al. Organic macromolecules transport a significant proportion of the calcium precursor for nacre formation [J]. | ACTA BIOMATERIALIA , 2025 , 191 : 140-148 . |
MLA | Macias-Sanchez, Elena et al. "Organic macromolecules transport a significant proportion of the calcium precursor for nacre formation" . | ACTA BIOMATERIALIA 191 (2025) : 140-148 . |
APA | Macias-Sanchez, Elena , Huang, Xing , Willinger, Marc G. , Rodriguez-Navarro, Alejandro , Checa, Antonio . Organic macromolecules transport a significant proportion of the calcium precursor for nacre formation . | ACTA BIOMATERIALIA , 2025 , 191 , 140-148 . |
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Alkali-metal doped perovskite oxides have emerged as promising materials due to their unique properties and broad applications in various fields, including photovoltaics and catalysis. Understanding the complex interplay between alkali metal doping, structural modifications, and their impact on performance remains a crucial challenge. In this study, this challenge is addressed by investigating the synthesis and properties of Rb-doped perovskite oxides. These results reveal that the doping of Rb into perovskite oxides function as a structural modifier in the as-synthesized samples and during the oxygen evolution reaction (OER) as well. Electron microscopy and first-principles calculations confirm the enrichment of Rb on the surface of the as-synthesized sample. Further investigations into the electrocatalytic reaction revealed that the Rb-doped perovskite underwent drastic restructuring with Rb leaching and formation of strontium oxide. Rb-doped perovskite oxides are successfully fabricated in this study. However, an excessive introduction of Rb does not entirely mitigate Rb volatilization during synthesis at elevated temperatures. A surface enrichment of Rb is observed within the perovskite structure. During the oxygen evolution reaction, a significant structural evolution occurs, along with the detection of Rb leaching and the formation of strontium oxide. image
Keyword :
alkali metal doping alkali metal doping oxygen evolution reaction oxygen evolution reaction perovskite oxide perovskite oxide surface enrichment surface enrichment surface reconstruction surface reconstruction
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GB/T 7714 | Xie, Huachao , Zhang, Yuxuan , Liu, Panpan et al. Rb-Doped Perovskite Oxides: Surface Enrichment and Structural Reconstruction During the Oxygen Evolution Reaction [J]. | SMALL , 2024 , 20 (42) . |
MLA | Xie, Huachao et al. "Rb-Doped Perovskite Oxides: Surface Enrichment and Structural Reconstruction During the Oxygen Evolution Reaction" . | SMALL 20 . 42 (2024) . |
APA | Xie, Huachao , Zhang, Yuxuan , Liu, Panpan , Duo, Xuyao , Hu, Zhonghui , Yu, Jia et al. Rb-Doped Perovskite Oxides: Surface Enrichment and Structural Reconstruction During the Oxygen Evolution Reaction . | SMALL , 2024 , 20 (42) . |
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Atomically precise low-nuclearity (n<10) silver nanoclusters (AgNCs) have garnered significant interest due to their size-dependent optical properties and diverse applications. However, their synthesis has remained challenging, primarily due to their inherent instability. The present study introduces a new feasible approach for clustering silver ions utilizing highly negative and redox-inert polyoxoniobates (PONbs) as all-inorganic ligands. This strategy not only enables the creation of novel Ag-PONb composite nanoclusters but also facilitates the synthesis of stable low-nuclearity AgNCs. Using this method, we have successfully synthesized a small octanuclear rhombic [Ag-8](6+) AgNC stabilized by six highly negative [LiNb27O75](14-) polyoxoanions. This marks the first PONb-protected superatomic AgNC, designated as {Ag-8@(LiNb27O75)(6)} (Ag-8@Nb-162), with an aesthetically spherical core-shell structure. The crystalline Ag-8@Nb-162 is stable under ambient conditions, What's more, it is water-soluble and able to maintain its molecular cluster structure intact in water. Further, the stable small [Ag-8](6+) AgNC has interesting temperature- and pH-dependent reversible fluorescence response, based on which a multiple optical encryption mode for anti-counterfeit technology was demonstrated. This work offers a promising avenue for the synthesis of fascinating and stable PONb-protected AgNCs and sheds light on the development of new-type optical functional materials.
Keyword :
fluorescence fluorescence macromolecules macromolecules nanoclusters nanoclusters polyoxoniobate polyoxoniobate silver silver
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GB/T 7714 | Hong, Li-Hao , Yue, Sheng-Nan , Huang, Xing et al. Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 63 (29) . |
MLA | Hong, Li-Hao et al. "Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 63 . 29 (2024) . |
APA | Hong, Li-Hao , Yue, Sheng-Nan , Huang, Xing , Sun, Cai , Cai, Ping-Wei , Sun, Yan-Qiong et al. Development of Stable Water-Soluble Supratomic Silver Clusters Utilizing A Polyoxoniobate-Protected Strategy: Giant Core-Shell-Type Ag8@Nb162 Fluorescent Nanocluster . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 63 (29) . |
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Developing active, stable, and cost-efficient electrocatalysts to replace platinum for the alkaline hydrogen evolution reaction (HER) is highly desirable yet represents a great challenge. Here, it is reported on a facile one-pot synthesis of RuxNi layered double hydroxides (RuxNi-LDHs) that exhibit remarkable HER activity and stability after an in-situ activation treatment, surpassing most state-of-the-art Ru-based catalysts as well as commercial Ru/C and Pt/C catalysts. The structural and chemical changes triggered by in-situ activation are systematically investigated, and the results clearly show that the pristine, less-active RuxNi-LDHs are transformed into a highly active catalyst characterized by raft-like, defect-rich Ru degrees particles decorated on the surface of RuxNi-LDHs. Density functional theory (DFT) calculations reveal that the defective Ru sites can effectively optimize the reaction pathway and lower the free energies of the elemental steps involved, leading to enhanced intrinsic activity. This work highlights the importance of the currently understudied strategy of defect engineering in boosting the HER activity of Ru-based catalysts and offers an effective approach involving in-situ electrochemical activation for the development of high-performance alkaline HER catalysts.
Keyword :
alkaline HER alkaline HER defect engineering defect engineering defective Ru-degrees NPs defective Ru-degrees NPs first-principles calculations first-principles calculations RuxNi-LDHs RuxNi-LDHs
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GB/T 7714 | Shi, Ningning , Ma, Ruijie , Lin, Linghui et al. In-Situ Derived Defective Ru Particles Anchored on Ru-Ni Layered Double Hydroxides for Enhanced Alkaline Hydrogen Evolution [J]. | SMALL , 2024 , 20 (27) . |
MLA | Shi, Ningning et al. "In-Situ Derived Defective Ru Particles Anchored on Ru-Ni Layered Double Hydroxides for Enhanced Alkaline Hydrogen Evolution" . | SMALL 20 . 27 (2024) . |
APA | Shi, Ningning , Ma, Ruijie , Lin, Linghui , Xie, Wangjing , Liu, Panpan , Li, Peng et al. In-Situ Derived Defective Ru Particles Anchored on Ru-Ni Layered Double Hydroxides for Enhanced Alkaline Hydrogen Evolution . | SMALL , 2024 , 20 (27) . |
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Alloying metals to form intermetallics has been proven effective in tuning the chemical properties of metal-based catalysts. However, intermetallic alloys can undergo structural and chemical transformations under reactive conditions, leading to changes in their catalytic function. Elucidating and understanding these transformations are crucial for establishing relevant structure-performance relationships and for the rational design of alloy-based catalysts. In this work, we used CuZn alloy nanoparticles (NPs) as a model material system and employed in situ transmission electron microscopy (TEM) to investigate the structural and chemical changes of CuZn NPs under H-2, O-2 and their mixture. Our results show how CuZn NPs undergo sequential transformations in the gas mixture at elevated temperatures, starting with gradual leaching and segregation of Zn, followed by oxidation at the NP surface. The remaining copper at the core of particles can then engage in dynamic behavior, eventually freeing itself from the zinc oxide shell. The structural dynamics arises from an oscillatory phase transition between Cu and Cu2O and is correlated with the catalytic water formation, as confirmed by in situ mass spectrometry (MS). Under pure H-2 or O-2 atmosphere, we observe different structural evolution pathways and final chemical states of CuZn NPs compared to those in the gas mixture. These results clearly demonstrate that the chemical state of alloy NPs can vary considerably under reactive redox atmospheres, particularly for those containing elements with distinct redox properties, necessitating the use of in situ or detailed ex situ characterizations to gain relevant insights into the states of intermetallic alloy-based catalysts and structure-activity relationships.
Keyword :
CuZn alloy CuZn alloy In situ transmission electron microscopy (TEM) In situ transmission electron microscopy (TEM) redox atmosphere redox atmosphere structural and chemical transformations structural and chemical transformations
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GB/T 7714 | Yue, Shengnan , Li, Qian , Zeng, Chaobin et al. Structural and chemical transformations of CuZn alloy nanoparticles under reactive redox atmospheres: An in situ TEM study [J]. | NANO RESEARCH , 2024 , 17 (7) : 6265-6273 . |
MLA | Yue, Shengnan et al. "Structural and chemical transformations of CuZn alloy nanoparticles under reactive redox atmospheres: An in situ TEM study" . | NANO RESEARCH 17 . 7 (2024) : 6265-6273 . |
APA | Yue, Shengnan , Li, Qian , Zeng, Chaobin , Klyushin, Alexander , Farra, Ramzi , Willinger, Marc-Georg et al. Structural and chemical transformations of CuZn alloy nanoparticles under reactive redox atmospheres: An in situ TEM study . | NANO RESEARCH , 2024 , 17 (7) , 6265-6273 . |
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Catalysts based on palladium are among the most effective in the complete oxidation of methane. Despite extensive studies and notable advances, the nature of their catalytically active species and conceivable structural dynamics remains only partially understood. Here, we combine operando transmission electron microscopy (TEM) with near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and density functional theory (DFT) calculations to investigate the active state and catalytic function of Pd nanoparticles (NPs) under methane oxidation conditions. We show that the particle size, phase composition and dynamics respond appreciably to changes in the gas-phase chemical potential. In combination with mass spectrometry (MS) conducted simultaneously with in situ observations, we uncover that the catalytically active state exhibits phase coexistence and oscillatory phase transitions between Pd and PdO. Aided by DFT calculations, we provide a rationale for the observed redox dynamics and demonstrate that the emergence of catalytic activity is related to the dynamic interplay between coexisting phases, with the resulting strained PdO having more favorable energetics for methane oxidation. Palladium-based catalysts are highly effective for the complete oxidation of methane. Here, the authors employ operando transmission electron microscopy, near-ambient pressure X-ray photoelectron spectroscopy, and density functional theory calculations to investigate the active state and catalytic function of Pd nanoparticles in methane oxidation.
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GB/T 7714 | Yue, Shengnan , Praveen, C. S. , Klyushin, Alexander et al. Redox dynamics and surface structures of an active palladium catalyst during methane oxidation [J]. | NATURE COMMUNICATIONS , 2024 , 15 (1) . |
MLA | Yue, Shengnan et al. "Redox dynamics and surface structures of an active palladium catalyst during methane oxidation" . | NATURE COMMUNICATIONS 15 . 1 (2024) . |
APA | Yue, Shengnan , Praveen, C. S. , Klyushin, Alexander , Fedorov, Alexey , Hashimoto, Masahiro , Li, Qian et al. Redox dynamics and surface structures of an active palladium catalyst during methane oxidation . | NATURE COMMUNICATIONS , 2024 , 15 (1) . |
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Integrating Fenton chemistry and nanomedicine into cancer therapy has significantly promoted the development of chemodynamic therapy (CDT). Nanoscale polyoxometalates (POMs), with their reversible redox properties, exhibit promising potential in developing outstanding CDT drugs by exploring their Fenton-like catalytic reactivity in tumor environments. However, such research is still in its infancy due to the challenges of acquiring POMs that are both easily prepared and possess ideal therapeutic effects, physiological solubility, biocompatibility and safety. In this work, we report the synthesis of a new crystalline antimonotungstate {Dy2Sb2W7O23(OH)(DMF)2(SbW9O33)2} (1, DMF=N, N-dimethylformamide) with gram-scale high yield via a facile "one-pot" solvothermal reaction. 1 exhibits not only a soluble and water-stable POM nanocluster, but also excellent catalytic activity for hydroxyl radical-generating Fenton-like reactions. Further biomedical studies reveal that 1 can trigger cell apoptosis and promote lipid peroxidation, exhibiting high cytotoxicity and selectivity towards B16-F10 mouse melanoma cancer cells with an IC50 value of 4.75 mu M. Especially, 1 can inhibit melanoma growth in vivo with favorable biosafety, achieving a 5.2-fold reduction in tumor volume and a weight loss of 76.0 % at the dose of 70 mu g/kg. This research not only demonstrates the immense potential of antimonotungstates in CDT drug development for the first time but also provides new insights and directions for the development of novel anticancer drugs.
Keyword :
antitumor antitumor chemodynamic therapy chemodynamic therapy nanocluster nanocluster polyoxometalate polyoxometalate polyoxotungstate polyoxotungstate
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GB/T 7714 | Xiao, Hui-Ping , Du, Man-Yi , Sun, Xian-Bin et al. A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 64 (8) . |
MLA | Xiao, Hui-Ping et al. "A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 64 . 8 (2024) . |
APA | Xiao, Hui-Ping , Du, Man-Yi , Sun, Xian-Bin , Xu, Ruo-Fei , Li, Dong-Miao , Yue, Sheng-Nan et al. A Highly Biocompatible Polyoxotungstate with Fenton-like Reaction Activity for Potent Chemodynamic Therapy of Tumors . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2024 , 64 (8) . |
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Platinum nanoparticles (NPs) supported by titania exhibit a strong metal-support interaction (SMSI)([1]) that can induce overlayer formation and encapsulation of the NP's with a thin layer of support material. This encapsulation modifies the catalyst's properties, such as increasing its chemoselectivity([2]) and stabilizing it against sintering.([3]) Encapsulation is typically induced during high-temperature reductive activation and can be reversed through oxidative treatments.([1]) However, recent findings indicate that the overlayer can be stable in oxygen.([4, 5]) Using in situ transmission electron microscopy, we investigated how the overlayer changes with varying conditions. We found that exposure to oxygen below 400 degrees C caused disorder and removal of the overlayer upon subsequent hydrogen treatment. In contrast, elevating the temperature to 900 degrees C while maintaining the oxygen atmosphere preserved the overlayer, preventing platinum evaporation when exposed to oxygen. Our findings demonstrate how different treatments can influence the stability of nanoparticles with or without titania overlayers. expanding the concept of SMSI and enabling noble metal catalysts to operate in harsh environments without evaporation associated losses during burn-off cycling.
Keyword :
Electron Microscopy Electron Microscopy Heterogeneous Catalysis Heterogeneous Catalysis Metal-Support Interaction Metal-Support Interaction Platinum Platinum
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GB/T 7714 | Beck, Arik , Frey, Hannes , Huang, Xing et al. Controlling the Strong Metal-Support Interaction Overlayer Structure in Pt/TiO2 Catalysts Prevents Particle Evaporation [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2023 . |
MLA | Beck, Arik et al. "Controlling the Strong Metal-Support Interaction Overlayer Structure in Pt/TiO2 Catalysts Prevents Particle Evaporation" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023) . |
APA | Beck, Arik , Frey, Hannes , Huang, Xing , Clark, Adam H. , Goodman, Emmett D. , Cargnello, Matteo et al. Controlling the Strong Metal-Support Interaction Overlayer Structure in Pt/TiO2 Catalysts Prevents Particle Evaporation . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2023 . |
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The commercial application of lithium-sulfur batteries is severely hampered by polysulfide shuttle effects, sluggish redox kinetics, and uncontrollable lithium dendrite growth. Herein, a unique Ni-doped CoSe2 nanoparticle decorated bilayer carbon (Ni-CoSe2/BC) structure is synthesized for both the sulfur cathode and lithium anode, which introduces bi-functionalities including I) the internal carbon conductive network skeleton of carbon nanotubes is capable of physically confining, storing, and alleviating volume expansion of sulfur; and II) Ni-CoSe2 nanoparticles decorated on the external carbon nanoarrays contribute to efficient chemical anchoring and accelerated polysulfide conversion for the cathode, and serve as lithiophilic sites to induce homogeneous lithium deposition for the anode. As a result, Ni-CoSe2/BC effectively inhibits the shuttle effect and induces dendrite-free lithium deposition. The Ni-CoSe2/BC-S delivers a high discharge specific capacity of 806 mAh g- 1 after 400 cycles at 1 C, with a low capacity decay rate of 0.07% per cycle. Moreover, the Ni-CoSe2/BC-Li exhibits an impressively long cycle life of 2000 h at 10 mA cm-2/10 mAh cm-2. Notably, the lithium-sulfur full cell assembled with Ni-CoSe2/BC as universal hosts for both anode and cathode possesses an average discharge capacity of 6.07 mAh cm-2 in 50 cycles (Sulfur loading=12.8 mg cm-2, Electrolyte/Sulfur=7.8 & mu;L mg-1, and Negative/Positive=1.56). This work provides novel structural design and mechanism insights for the practical application of lithium-sulfur batteries.
Keyword :
Carbon nanostructure Carbon nanostructure Catalysis Catalysis Li -S batteries Li -S batteries Lithium metal anode Lithium metal anode Lithium polysulfides Lithium polysulfides Metal-organic frameworks Metal-organic frameworks Metal selenide Metal selenide
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GB/T 7714 | Xie, Yonghui , Zheng, Wenrui , Ao, Juan et al. Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell [J]. | ENERGY STORAGE MATERIALS , 2023 , 62 . |
MLA | Xie, Yonghui et al. "Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell" . | ENERGY STORAGE MATERIALS 62 (2023) . |
APA | Xie, Yonghui , Zheng, Wenrui , Ao, Juan , Shao, Yeqing , Huang, Xing , Li, Hong et al. Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell . | ENERGY STORAGE MATERIALS , 2023 , 62 . |
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