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Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates Scopus
期刊论文 | 2024 , 14 (16) , 4496-4505 | Catalysis Science and Technology
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Abstract :

Incorporation of ionic liquids into metal-organic frameworks (MOFs) offers a new platform to construct heterogeneous bifunctional catalytic systems for the chemical capture and conversion of CO2 with epoxides. Herein, an imidazolium-based ionic liquid decorated UiO-66 type MOF (P3[BCMIm]Br@UiO-66) was successfully constructed via solvothermal assembly of the carboxyl-functionalized imidazolium ionic liquid ligand, terephthalic acid ligand and Zr(iv) ions. It exhibits the highest catalytic activity upon the cycloaddition of CO2 (98.2% conversion of propylene oxide and 99% selectivity to propylene carbonate) under optimized conditions (2.2 Mpa CO2, 1.0 wt%, 110 °C, reaction time 2 h). Notably, P3[BCMIm]Br@UiO-66 outperformed the original UiO-66 materials and [BCMIm]Br. P3[BCMIm]Br@UiO-66 retained its good catalytic performance for up to five recycling runs with only a little loss in catalytic activity. Furthermore, several additional coupling reactions were investigated with other epoxides as substrates. © 2024 The Royal Society of Chemistry.

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GB/T 7714 Lin, J. , Luo, J. , Zhang, M. et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates [J]. | Catalysis Science and Technology , 2024 , 14 (16) : 4496-4505 .
MLA Lin, J. et al. "Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates" . | Catalysis Science and Technology 14 . 16 (2024) : 4496-4505 .
APA Lin, J. , Luo, J. , Zhang, M. , Zhang, L. , Cai, G. , Zou, J. et al. Incorporation of a carboxyl-functionalized imidazolium-based ionic liquid into a UiO-66 type MOF for chemical fixation of CO2 into carbonates . | Catalysis Science and Technology , 2024 , 14 (16) , 4496-4505 .
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支撑工程教育专业认证的化工原理实验考核内容设计
期刊论文 | 2023 , 40 (05) , 111-115,156 | 化工高等教育
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Abstract :

文章在分析化工原理实验考核现状的基础上,基于OBE理念制定了化工原理实验课程目标,对化工原理实验预习、实验操作、实验报告、期末笔试等四个教学环节的考核内容进行重新设计,以期达到以考促教、以考促学的目的,同时支撑工程教育专业认证中毕业要求指标点的达成。

Keyword :

OBE理念 OBE理念 化工原理实验 化工原理实验 工程教育认证 工程教育认证 考核 考核 能力培养 能力培养

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GB/T 7714 张孟佳 , 王晓达 , 蔡国辉 et al. 支撑工程教育专业认证的化工原理实验考核内容设计 [J]. | 化工高等教育 , 2023 , 40 (05) : 111-115,156 .
MLA 张孟佳 et al. "支撑工程教育专业认证的化工原理实验考核内容设计" . | 化工高等教育 40 . 05 (2023) : 111-115,156 .
APA 张孟佳 , 王晓达 , 蔡国辉 , 施小芳 , 叶长燊 , 李玲 . 支撑工程教育专业认证的化工原理实验考核内容设计 . | 化工高等教育 , 2023 , 40 (05) , 111-115,156 .
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一种含咪唑基有机聚合物材料的制备及应用 incoPat
专利 | 2022-06-27 00:00:00 | CN202210733656.9
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本发明属于聚合物材料合成技术领域,公开了一种含咪唑基有机聚合物材料的制备及应用,具体内容是以含咪唑基的化合物和二乙烯基苯单体通过聚合反应制备一种含咪唑基的有机聚合物材料。该材料将具有CO2吸附和活化功能的咪唑基团大量固载到聚合物骨架上,并达到均匀分布的效果。该聚合物材料具有较好的稳定性,且合成过程简单,绿色环保。本发明将制备的含咪唑基的聚合物材料作为催化剂应用于二氧化碳与甲醇合成碳酸二甲酯的反应,在较为温和的反应条件下即表现出优异的催化性能。

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GB/T 7714 李玲 , 钟雄辉 , 李政 et al. 一种含咪唑基有机聚合物材料的制备及应用 : CN202210733656.9[P]. | 2022-06-27 00:00:00 .
MLA 李玲 et al. "一种含咪唑基有机聚合物材料的制备及应用" : CN202210733656.9. | 2022-06-27 00:00:00 .
APA 李玲 , 钟雄辉 , 李政 , 林江慧 , 张孟佳 . 一种含咪唑基有机聚合物材料的制备及应用 : CN202210733656.9. | 2022-06-27 00:00:00 .
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加强实验室安全管理举措执行力的心理因素探讨
期刊论文 | 2022 , 39 (03) , 136-139 | 化工高等教育
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Abstract :

心理因素对高校实验室安全管理会产生一定的影响。文章在分析一线实验人员认知特点和心理状态的基础上,探讨了影响其安全行为模式和安全行为态度的因素,并有针对性地给出了相应的建议,为高校制定有效的安全管理制度、提高实验室安全管理执行力提供参考。

Keyword :

安全心理 安全心理 安全行为 安全行为 执行力 执行力

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GB/T 7714 吴乃昕 , 施小芳 , 张孟佳 et al. 加强实验室安全管理举措执行力的心理因素探讨 [J]. | 化工高等教育 , 2022 , 39 (03) : 136-139 .
MLA 吴乃昕 et al. "加强实验室安全管理举措执行力的心理因素探讨" . | 化工高等教育 39 . 03 (2022) : 136-139 .
APA 吴乃昕 , 施小芳 , 张孟佳 , 陈晓彦 , 李玲 . 加强实验室安全管理举措执行力的心理因素探讨 . | 化工高等教育 , 2022 , 39 (03) , 136-139 .
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5W2H分析法在高校实验室安全管理中的应用
期刊论文 | 2022 , 8 (08) , 166-168 | 西部素质教育
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Abstract :

文章首先分析了5W2H分析法在高校实验室安全管理中应用的思路,然后论述了5W2H分析法在高校实验室安全管理中应用的流程,包括明确安全管理意义(Why),落实安全管理责任主体(Who);制定安全管理职责(What),履行安全管理义务(When&Where);制定安全管理评判标准(How much),形成反馈激励机制(How)。

Keyword :

5W2H分析法 5W2H分析法 实验室安全管理 实验室安全管理 高校 高校

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GB/T 7714 张孟佳 , 施小芳 , 吴乃昕 et al. 5W2H分析法在高校实验室安全管理中的应用 [J]. | 西部素质教育 , 2022 , 8 (08) : 166-168 .
MLA 张孟佳 et al. "5W2H分析法在高校实验室安全管理中的应用" . | 西部素质教育 8 . 08 (2022) : 166-168 .
APA 张孟佳 , 施小芳 , 吴乃昕 , 李玲 . 5W2H分析法在高校实验室安全管理中的应用 . | 西部素质教育 , 2022 , 8 (08) , 166-168 .
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[(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds SCIE
期刊论文 | 2021 , 32 (02) , 109-118 | SYNLETT
WoS CC Cited Count: 10
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Abstract :

In this account, we summarize recent work on the direct introduction of the SCF (3) group by using [(bpy)CuSCF3] as trifluoromethylthiolating reagent. A number of efficient and convenient strategies have been disclosed for the synthesis of trifluoromethylthiolated compounds, including trifluoromethylthiolation of aryl, alkenyl, and alkyl halides, and arylboronic acids. These reactions afford various trifluoromethyl sulfides in good yields. Introduction Synthesis of [(bpy)CuSCF3] Trifluoromethylthiolation of Aryl Halides Trifluoromethylthiolation of Alkenyl Halides Trifluoromethylthiolation of Alkyl Halides Miscellaneous Conclusion

Keyword :

copper copper fluorine fluorine trifluoromethylthiolating reagent trifluoromethylthiolating reagent trifluoromethylthiolation trifluoromethylthiolation

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GB/T 7714 Huang, Yangjie , Zhang, Mengjia , Lin, Qi et al. [(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds [J]. | SYNLETT , 2021 , 32 (02) : 109-118 .
MLA Huang, Yangjie et al. "[(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds" . | SYNLETT 32 . 02 (2021) : 109-118 .
APA Huang, Yangjie , Zhang, Mengjia , Lin, Qi , Weng, Zhiqiang . [(bpy)CuSCF (3) ]: A Practical and Efficient Reagent for the Construction of C-SCF (3) Bonds . | SYNLETT , 2021 , 32 (02) , 109-118 .
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Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles SCIE
期刊论文 | 2019 , 21 (15) , 5838-5842 | ORGANIC LETTERS
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The tandem synthesis of 2-trifluoromethylthio-(seleno)-substituted benzofurans using palladium-catalyzed conditions is reported. Trifluoromethylthio(seleno)lation of 2-(2,2-dibromovinyl)phenols with (bpy)CuSCF3 or [(bpy)-CuSeCF3](2) furnishes several 2-trifluoromethylthio(seleno)-lated benzofurans in acceptable to good yield. Mechanistic investigations were performed to elucidate the reaction pathway, which was involved in the formation of a 2-bromobenzofuran species. The scope of this protocol was further extended to the preparation of 2-trifluoromethylthio(seleno)lated benzothiophenes and indoles.

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GB/T 7714 Zhang, Mengjia , Weng, Zhiqiang . Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles [J]. | ORGANIC LETTERS , 2019 , 21 (15) : 5838-5842 .
MLA Zhang, Mengjia et al. "Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles" . | ORGANIC LETTERS 21 . 15 (2019) : 5838-5842 .
APA Zhang, Mengjia , Weng, Zhiqiang . Palladium-Catalyzed Tandem Synthesis of 2-Trifluoromethylthio(seleno)-Substituted Benzofused Heterocycles . | ORGANIC LETTERS , 2019 , 21 (15) , 5838-5842 .
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Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect SCIE
期刊论文 | 2018 , 16 (24) , 4558-4562 | ORGANIC & BIOMOLECULAR CHEMISTRY
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An efficient catalytic method for the synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) from the reaction of o-bromophenols with trifluoromethanethiolates or selenolates is disclosed. Some of the title compounds exhibited excellent insecticidal activities.

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GB/T 7714 Zhang, Mengjia , Lu, Jiaqing , Weng, Zhiqiang . Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect [J]. | ORGANIC & BIOMOLECULAR CHEMISTRY , 2018 , 16 (24) : 4558-4562 .
MLA Zhang, Mengjia et al. "Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect" . | ORGANIC & BIOMOLECULAR CHEMISTRY 16 . 24 (2018) : 4558-4562 .
APA Zhang, Mengjia , Lu, Jiaqing , Weng, Zhiqiang . Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect . | ORGANIC & BIOMOLECULAR CHEMISTRY , 2018 , 16 (24) , 4558-4562 .
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Copper-Mediated One-Pot Synthesis of 2,2-Difluoro-1,3-benzoxathioles from o-Bromophenols and Trifluoromethanethiolate SCIE
期刊论文 | 2018 , 20 (2) , 481-484 | ORGANIC LETTERS
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A copper-mediated difluoromethylenation of o-bromophenols with trifluoromethanethiolate is described. This one-pot protocol proceeds through an intermolecular addition of S=CF2 (resulting from the decomposition of trifluoromethanethiolate) to o-bromophenols followed by intramolecular C-S coupling to form 2,2-difluoro-1,3-benzoxathioles. This method is compatible with a broad range of substrates and enables the late-stage difluoromethylenation of several functionally dense druglike o-bromophenols.

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GB/T 7714 Zhang, Mengjia , Chen, Shouxiong , Weng, Zhiqiang . Copper-Mediated One-Pot Synthesis of 2,2-Difluoro-1,3-benzoxathioles from o-Bromophenols and Trifluoromethanethiolate [J]. | ORGANIC LETTERS , 2018 , 20 (2) : 481-484 .
MLA Zhang, Mengjia et al. "Copper-Mediated One-Pot Synthesis of 2,2-Difluoro-1,3-benzoxathioles from o-Bromophenols and Trifluoromethanethiolate" . | ORGANIC LETTERS 20 . 2 (2018) : 481-484 .
APA Zhang, Mengjia , Chen, Shouxiong , Weng, Zhiqiang . Copper-Mediated One-Pot Synthesis of 2,2-Difluoro-1,3-benzoxathioles from o-Bromophenols and Trifluoromethanethiolate . | ORGANIC LETTERS , 2018 , 20 (2) , 481-484 .
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A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides SCIE
期刊论文 | 2017 , 193 , 24-32 | JOURNAL OF FLUORINE CHEMISTRY
WoS CC Cited Count: 22
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Abstract :

A mild and efficient trifluoromethylselenolation of acid chlorides with [(bpy)Cu(SeCF3)](2) (1) in the presence of a catalytic amount of metallic iron powder is described. Easily available benzoyl chloride derivatives and alkyl acid chlorides are smoothly converted into the corresponding Se-trifluoromethyl esters in good to excellent yields. This simple transformation demonstrates a broad substrate scope with respect to acid chlorides, and is amenable to being carried out on gram scales. (C) 2016 Elsevier B.V. All rights reserved.

Keyword :

Acid chlorides Acid chlorides Copper Copper Iron Iron Se-trifluoromethyl esters Se-trifluoromethyl esters Trifluoromethylselenolation Trifluoromethylselenolation

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GB/T 7714 Wang, Junwen , Zhang, Mengjia , Weng, Zhiqiang . A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides [J]. | JOURNAL OF FLUORINE CHEMISTRY , 2017 , 193 : 24-32 .
MLA Wang, Junwen et al. "A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides" . | JOURNAL OF FLUORINE CHEMISTRY 193 (2017) : 24-32 .
APA Wang, Junwen , Zhang, Mengjia , Weng, Zhiqiang . A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides . | JOURNAL OF FLUORINE CHEMISTRY , 2017 , 193 , 24-32 .
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