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学者姓名:王星辉
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Along with the constantly evolving functional microsystems toward more diversification, the more rigorous design deliberation of pursuing higher mass-loading of electrode materials and low-temperature fabrication compatibility have imposed unprecedented demand on integrable all-solid-state thin-film microbatteries. While the classic thin-film intercalation cathode prepared by vacuum-based techniques inevitably encountered a post-annealing process, tape-casting technologies hold great merits both in terms of high-mass loading and low-temperature processing. In this work, a novel microbattery configuration is developed by the combination of traditional tape-casting thick electrodes and sputtered inorganic thin-film solid electrolytes (similar to 3 mu m lithium phosphorus oxynitride). Enabled by physically pressed or vapor-deposited Li as an anode, solid-state batteries with tape-casted LiFePO4 electrodes exhibit outstanding cyclability and stability. To meet integration requirements, LiFePO4/LiPON/Si microbatteries were successfully fabricated at low temperatures and found to achieve a wide operating temperature range. This novel configuration has good prospects in promoting the thin-film microbattery enabling a paradigm shift and satisfying diversified requirements.
Keyword :
all-solid-state batteries all-solid-state batteries lithium phosphorus oxynitride lithium phosphorus oxynitride on-chip integration on-chip integration silicon anodes silicon anodes tape-casting electrodes tape-casting electrodes
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GB/T 7714 | Ke, Bingyuan , Zhang, Congcong , Cheng, Shoulin et al. Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries [J]. | INTERDISCIPLINARY MATERIALS , 2024 , 3 (4) : 621-631 . |
MLA | Ke, Bingyuan et al. "Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries" . | INTERDISCIPLINARY MATERIALS 3 . 4 (2024) : 621-631 . |
APA | Ke, Bingyuan , Zhang, Congcong , Cheng, Shoulin , Li, Wangyang , Deng, Renming , Zhang, Hong et al. Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries . | INTERDISCIPLINARY MATERIALS , 2024 , 3 (4) , 621-631 . |
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Micro energy sources as the nucleus of intelligent microdevices guarantee their full autonomy in the dimensions of time and space. However, the state-of-the-art micro energy storage components, like all-solid-state thin-film microbatteries (ASSTFBs), whose direct integration is impeded by the stereotyped vacuum-based manufacturing technologies, for which an inevitable high-temperature annealing step (> 500 degrees C) can exert catastrophic effects on the attached microdevices during the crystallization of manufactured insertion thin-film cathodes, especially in flexible integration. Herein, a prototype construction is created to benchmark concrete feasibility for the low-temperature manufacturing of ASSTFBs via a nonvacuum-based spin-coating electrode architecture. Results show that the spin-coated LiFePO4 films enable low-temperature (approximate to 45 degrees C) manufacturing of ASSTFBs, by which it can deliver excellent cycling performance up to 1000 cycles. Importantly, this technology presents the versatility of integrating various cathode composites into ASSTFBs and is therefore generalized to the LiCoO2- and Li4Ti5O12-based solid-state chemistries. Furthermore, ASSTFBs with such compliant electrodes manifest outstanding flexibility without pronounced capacity degradation by successfully integrating on flexible temperature-sensitive substrates. The spin-coating protocol provides a general solution for excessive processing temperatures and ample opportunities for the development of on-chip integratable and flexible ASSTFBs.
Keyword :
flexible batteries flexible batteries LiPON LiPON microbatteries microbatteries on-chip integration on-chip integration spin-coating spin-coating
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GB/T 7714 | Ke, Bingyuan , Cheng, Shoulin , Zhang, Congcong et al. Low-Temperature Flexible Integration of All-Solid-State Thin-Film Lithium Batteries Enabled by Spin-Coating Electrode Architecture [J]. | ADVANCED ENERGY MATERIALS , 2024 , 14 (12) . |
MLA | Ke, Bingyuan et al. "Low-Temperature Flexible Integration of All-Solid-State Thin-Film Lithium Batteries Enabled by Spin-Coating Electrode Architecture" . | ADVANCED ENERGY MATERIALS 14 . 12 (2024) . |
APA | Ke, Bingyuan , Cheng, Shoulin , Zhang, Congcong , Li, Wangyang , Zhang, Jie , Deng, Renming et al. Low-Temperature Flexible Integration of All-Solid-State Thin-Film Lithium Batteries Enabled by Spin-Coating Electrode Architecture . | ADVANCED ENERGY MATERIALS , 2024 , 14 (12) . |
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The application of 3D printing technology in fabricating quasi-solid-state micro-supercapacitors (MSCs) offers inherent benefits in programmable structural design and high-mass-loading electrode fabrication. Nevertheless, the absence of high-performance printable inks and the sluggish ion transport within thick electrodes present significant challenges to their practical charge storage capabilities. Here, a new NiCo2S4-based nanocomposite ink with excellent rheological properties has been successfully developed and the 3D structure of quasi-solid-state MSCs is rationally engineered through the direct-ink-writing 3D printing technology. Beneficial from the firmly anchored NiCo2S4 nanoparticles on the reduced graphene oxide (rGO) and the ordered 3D micropores, the thick electrodes with serrated architectures provide abundant reaction sites and exhibit enhanced ion transport. Consequently, the MSCs with triple-layer-serrated electrodes can deliver a high areal capacitance up to 416.7 mF cm(-2). In comparison to the latticed counterparts, the areal capacitances of serrated MSCs with single-, double-, and triple-layer electrodes are amplified by 127.1%, 349.8%, and 585.9%, respectively (under 1 mA cm(-2)). This study offers novel insights into the cross-scale design of materials and electrode architectures for quasi-solid-state MSCs with high areal capacitance, promoting their integration into flexible and portable electronic devices.
Keyword :
3D printing 3D printing direct ink writing direct ink writing high-areal capacitance high-areal capacitance micro-supercapacitor micro-supercapacitor quasi-solid-state quasi-solid-state
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GB/T 7714 | Yao, Pinjing , Li, Wangyang , Ke, Bingyuan et al. 3D printing of serrated NiCo2S4-based electrodes for wearable micro-supercapacitors [J]. | SCIENCE CHINA-MATERIALS , 2024 , 67 (6) : 1956-1964 . |
MLA | Yao, Pinjing et al. "3D printing of serrated NiCo2S4-based electrodes for wearable micro-supercapacitors" . | SCIENCE CHINA-MATERIALS 67 . 6 (2024) : 1956-1964 . |
APA | Yao, Pinjing , Li, Wangyang , Ke, Bingyuan , Chen, Lihui , Jian, Yijia , Qiao, Huawei et al. 3D printing of serrated NiCo2S4-based electrodes for wearable micro-supercapacitors . | SCIENCE CHINA-MATERIALS , 2024 , 67 (6) , 1956-1964 . |
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Metal-organic frameworks (MOFs) have emerged as the versatile stage to synthesize carbonaceous materials with unique properties such as large surface area, tunable pore size, and controllable composition. The carbonaceous materials derived from MOFs maintain their excellent structural advantages and enable in situ doping with heteroatoms through a simple process. Numerous effects have been devoted to develop MOF-derived graphitic carbon and heteroatom-doped carbonaceous materials for energy conversion and storage. Herein, we review the nearest progresses of the fabrication, characterization, and application of MOF-derived graphitic carbon with different dimensions. Furthermore, we focus on MOF-derived heteroatom-doped carbon materials and their applications. Finally, we provide a summary and outlook on their future development. © 2024 Elsevier Inc. All rights reserved.
Keyword :
carbonaceous materials carbonaceous materials Carbonization Carbonization heteroatom-doping heteroatom-doping nanocarbon nanocarbon organic materials organic materials
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GB/T 7714 | Wang, X. , Wu, F. . MOF-derived carbonaceous materials [未知]. |
MLA | Wang, X. et al. "MOF-derived carbonaceous materials" [未知]. |
APA | Wang, X. , Wu, F. . MOF-derived carbonaceous materials [未知]. |
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Beyond the high theoretical capacity, conversion-alloying metal chalcogenides (CAMCs) exhibit exceptional high-rate performance as Li-ion battery electrodes. However, the inherent origin of the high-rate performance remains elusive, especially given the lower intrinsic conductivity of CAMCs. Here, the correlation between phase evolution and charge transport dynamics in fully activated CAMCs is systematically investigated, elucidating a current-adaptive Li-ion storage mechanism to explain the anomalous high-rate performance. Briefly, the deconversion reaction manipulated by ion diffusion acts as a “regulator” to adaptively modulate the transition from metal (high electronic conductivity) and lithium chalcogenides (high ionic conductivity) to CAMCs, thus removing the charge transport bottleneck without affecting the formation of the metal feedstock required for the alloying reaction. On this basis, the high capacity can be maintained at high rates through a “fading-free” alloying reaction. This study offers a novel perspective for the design of high-rate electrode materials. © 2024 Wiley-VCH GmbH.
Keyword :
alloying alloying conversion conversion current-adaptive current-adaptive high rate high rate Li-ion battery Li-ion battery
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GB/T 7714 | Li, W. , Deng, L. , Cao, J. et al. Current-Adaptive Li-Ion Storage Mechanism in High-Rate Conversion-Alloying Metal Chalcogenides [J]. | Advanced Functional Materials , 2024 , 34 (44) . |
MLA | Li, W. et al. "Current-Adaptive Li-Ion Storage Mechanism in High-Rate Conversion-Alloying Metal Chalcogenides" . | Advanced Functional Materials 34 . 44 (2024) . |
APA | Li, W. , Deng, L. , Cao, J. , Ke, B. , Wang, X. , Ni, S. et al. Current-Adaptive Li-Ion Storage Mechanism in High-Rate Conversion-Alloying Metal Chalcogenides . | Advanced Functional Materials , 2024 , 34 (44) . |
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为了实现全固态薄膜锂电池中硅薄膜电极的简单、低成本制备,采用旋涂法制备纳米硅薄膜电极,以锂磷氧氮(LiPON)作为固态电解质,锂箔作为对电极制备全固态电池,并进行储锂性能研究。研究发现,针对硅负极循环过程中膨胀问题,采用纳米尺寸的硅是一种有效的解决方案。以旋涂纳米硅悬浊液的制备方法快速完成了具有疏松多孔结构纳米硅薄膜电极的制备。在性能测试中,Si/LiPON/Li电池在30.15μA/cm~2的电流密度下循环11圈后具有51.36μAh/cm~2的放电比容量,在此后循环30圈容量保持率为98.77%,表明通过旋涂法制备的纳米硅薄膜电极在全固态薄膜锂电池的发展中具有较大潜力。
Keyword :
体积膨胀 体积膨胀 全固态薄膜锂电池 全固态薄膜锂电池 旋涂 旋涂 纳米硅 纳米硅
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GB/T 7714 | 程受麟 , 柯秉渊 , 王星辉 . 旋涂制备纳米硅薄膜电极及其性能研究 [J]. | 科技与创新 , 2024 , 4 (04) : 82-84,87 . |
MLA | 程受麟 et al. "旋涂制备纳米硅薄膜电极及其性能研究" . | 科技与创新 4 . 04 (2024) : 82-84,87 . |
APA | 程受麟 , 柯秉渊 , 王星辉 . 旋涂制备纳米硅薄膜电极及其性能研究 . | 科技与创新 , 2024 , 4 (04) , 82-84,87 . |
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“双碳”战略要求新型储能器件具备更高的能量密度和更低的成本。锂硫电池因其低成本、环保和高比能(2600 Wh kg~(-1))等优势,而成为储能领域中最具潜能的电池体系,已受到了广泛的关注及研究。近年来,锂硫电池已取得了系列进展,但仍面临一些问题与挑战,包括硫固有的电荷传输效率差、可溶性多硫化物的“穿梭效应”、充放电过程中的剧烈体积膨胀及锂枝晶的生长等,这些问题会导致锂硫电池性能下降甚至失效。碳基硫宿主具有多孔、高电导、轻质、大比表面积等优点,能够有效解决以上难题,已成为锂硫电池研究领域中的重要方向。而碳材料种类繁多,有碳纳米纤维、碳纳米管、碳纳米片、碳纳米花等,不同形貌或具备不同纳米尺度维度的碳纳米结构对锂硫电池的性能具有不同的影响规律。基于此,本文围绕高性能锂硫电池碳基硫宿主进行综述,分类综述了一维、二维、及多维复合碳材料在锂硫电池领域的应用及其性能,阐述不同维度碳基硫宿主对其电化学性能的影响规律,并对未来的研究方向进行了一定的展望。
Keyword :
硫正极 硫正极 碳材料 碳材料 穿梭效应 穿梭效应 锂硫电池 锂硫电池
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GB/T 7714 | 吴燔 , 谢永辉 , 王星辉 . 高性能锂硫电池碳基硫宿主的研究进展 [J]. | 功能材料与器件学报 , 2024 , 30 (01) : 15-20 . |
MLA | 吴燔 et al. "高性能锂硫电池碳基硫宿主的研究进展" . | 功能材料与器件学报 30 . 01 (2024) : 15-20 . |
APA | 吴燔 , 谢永辉 , 王星辉 . 高性能锂硫电池碳基硫宿主的研究进展 . | 功能材料与器件学报 , 2024 , 30 (01) , 15-20 . |
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Constructing a three-dimensional (3D) skeleton with a sodiophilic-modified layer (SML) has been proven to be an effective strategy to alleviate excessive volumetric deformation and continuous dendrite growth for sodium (Na) metal anodes. However, the weak binding force and violent reaction between the SML and the 3D skeleton lead to numerous cracks/defects and even pulverization of the SML during repeated Na plating/stripping. Herein, a lithiation pathway is presented to construct a sodiophilic Li-Sn alloy layer onto a 3D copper mesh to strengthen the SML for stable Na metal anodes. The lithiation 3D skeleton exhibits superior sodiophilicity, higher charge-transfer efficiency, and lower ion-diffusion barrier, contributing to the homogenization of ion-electronic flux and Na deposition. Simultaneously, the dense Li-Sn alloy is more stable than the monometal Sn-layer, which effectively prevents damage to the SML and enhances the stability of the SML. As a result, the asymmetrical cell exhibits great performance with a negligible nucleation overpotential and a high average Coulombic efficiency of 99.4%. Moreover, the full cell assembled with Na3V2(PO4)3 cathode delivers superior capacity retention of 91.3% after 1000 cycles at a current of 3C. © 2024 American Chemical Society.
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GB/T 7714 | Wang, J. , Li, Z. , Zhang, Y. et al. Lithiation: A Pathway to Strengthen Sodiophilic Metal Interlayer of 3D Metallic Skeleton for High-Performance Sodium Metal Anodes [J]. | Journal of Physical Chemistry Letters , 2024 , 15 (34) : 8853-8860 . |
MLA | Wang, J. et al. "Lithiation: A Pathway to Strengthen Sodiophilic Metal Interlayer of 3D Metallic Skeleton for High-Performance Sodium Metal Anodes" . | Journal of Physical Chemistry Letters 15 . 34 (2024) : 8853-8860 . |
APA | Wang, J. , Li, Z. , Zhang, Y. , Lu, M. , Wang, X. , Xie, Q. et al. Lithiation: A Pathway to Strengthen Sodiophilic Metal Interlayer of 3D Metallic Skeleton for High-Performance Sodium Metal Anodes . | Journal of Physical Chemistry Letters , 2024 , 15 (34) , 8853-8860 . |
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GB/T 7714 | Xie, Yonghui , Zheng, Wenrui , Ao, Juan et al. Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell (vol 62, 102925, 2023) [J]. | ENERGY STORAGE MATERIALS , 2024 , 67 . |
MLA | Xie, Yonghui et al. "Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell (vol 62, 102925, 2023)" . | ENERGY STORAGE MATERIALS 67 (2024) . |
APA | Xie, Yonghui , Zheng, Wenrui , Ao, Juan , Shao, Yeqing , Huang, Xing , Li, Hong et al. Multifunctional Ni-doped CoSe2 nanoparticles decorated bilayer carbon structures for polysulfide conversion and dendrite-free lithium toward high-performance Li-S full cell (vol 62, 102925, 2023) . | ENERGY STORAGE MATERIALS , 2024 , 67 . |
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Two-dimensional (2D) metal oxides (2DMOs), such as MoO2, have made impressive strides in recent years, and their applicability in a number of fields such as electronic devices, optoelectronic devices and lasers has been demonstrated. However, 2DMOs present challenges in their synthesis using conventional methods due to their non-van der Waals nature. We report that KCl acts as a flux to prepare large-area 2DMOs with sub-millimeter scale. We systematically investigate the effects of temperature, homogeneous time and cooling rate on the products in the flux method, demonstrating that in this reaction a saturated homogenous solution is obtained upon the melting of the salt and precursor. Afterward, the cooling rate was adjusted to regulate the thickness of the target crystals, leading to the precipitation of 2D non-layered material from the supersaturated solution; by applying this method, the highly crystalline non-layered 2D MoO2 flakes with so far the largest lateral size of up to sub-millimeter scale (~ 464 μm) were yielded. Electrical studies have revealed that the 2D MoO2 features metallic properties, with an excellent sheet resistance as low as 99 Ω·square−1 at room temperature, and exhibits a property of charge density wave in the measurement of resistivity as a function of temperature. Graphical abstract: TOC (Table of Content) (Figure presented.) © The Author(s) 2024.
Keyword :
2D non-layered materials 2D non-layered materials Flux method Flux method Metallic Metallic Metal oxide Metal oxide Thickness modulation Thickness modulation
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GB/T 7714 | Deng, L.-Y. , Zhang, Q. , Li, W.-Y. et al. KCl acts as a flux to assist the growth of sub-millimeter-scale metallic 2D non-layered molybdenum dioxide [J]. | Rare Metals , 2024 , 44 (1) : 404-416 . |
MLA | Deng, L.-Y. et al. "KCl acts as a flux to assist the growth of sub-millimeter-scale metallic 2D non-layered molybdenum dioxide" . | Rare Metals 44 . 1 (2024) : 404-416 . |
APA | Deng, L.-Y. , Zhang, Q. , Li, W.-Y. , Ye, X.-Y. , Zhao, Y.-F. , Chen, S.-Z. et al. KCl acts as a flux to assist the growth of sub-millimeter-scale metallic 2D non-layered molybdenum dioxide . | Rare Metals , 2024 , 44 (1) , 404-416 . |
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