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Improving the performance of lithium-ion batteries by micron-sized silicon particles coated with nano-ZnS anode materials SCIE
期刊论文 | 2024 , 81 | JOURNAL OF ENERGY STORAGE
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Abstract :

Micron-sized Si-based materials have attracted extensive attention for lithium-ion batteries due to their high theoretical capacity and low cost. However, its large volume expansion and low conductivity limit its further development. Here, a Si/ZnS anode material is prepared, in which ZnS nanoparticles are uniformly attached to the surface of micro-Si particles. The conversion reaction of ZnS generates metal Zn and Li2S, and the alloying reaction of Zn generates LixZn, the metal Zn and LixZn are used as conductive additives to improve the conductivity of the composites, while Li2S is used as an artificial solid electrolyte interfacial phase to promote the stability of the solid electrolyte interface of the composites, so that the prepared micron-sized Si-based anode exhibits excellent cycling stability. At a current density of 0.5 A g-1, the initial coulombic efficiency reaches 78.67 % and the discharge specific capacity is 1540.2 mAh g-1 after 200 cycles.

Keyword :

Anode material Anode material lithium-ion batteries lithium-ion batteries Micron-sized silicon particles Micron-sized silicon particles ZnS ZnS

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GB/T 7714 Zhang, Yong , Zhang, Yijin , Deng, Qingsong et al. Improving the performance of lithium-ion batteries by micron-sized silicon particles coated with nano-ZnS anode materials [J]. | JOURNAL OF ENERGY STORAGE , 2024 , 81 .
MLA Zhang, Yong et al. "Improving the performance of lithium-ion batteries by micron-sized silicon particles coated with nano-ZnS anode materials" . | JOURNAL OF ENERGY STORAGE 81 (2024) .
APA Zhang, Yong , Zhang, Yijin , Deng, Qingsong , Kuang, Ge , Lin, Rongying . Improving the performance of lithium-ion batteries by micron-sized silicon particles coated with nano-ZnS anode materials . | JOURNAL OF ENERGY STORAGE , 2024 , 81 .
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Improving the conductivity of silicon anode and the stability of solid electrolyte interface by Si/Bi2S3 nanocomposite SCIE
期刊论文 | 2024 , 84 | JOURNAL OF ENERGY STORAGE
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In the field of lithium battery research, silicon has received extensive attention due to its high specific capacity and abundant reserves, but the factors such as large volume expansion and low electrical conductivity limit its further development. In this work, Si/Bi2S3 composites with a heterogeneous structure is obtained by using a hydrothermal reaction. The heterogeneous structure can promote the rapid transfer of charge, and the interfacial coupling effect of the heterogeneous structure has an adsorption effect on Li2S generated by the conversion reaction of Bi2S3, and Li2S is distributed on the surface of the Si/Bi2S3 composite to become an effective component of solid electrolyte interface (SEI), promoting the stability of the SEI film. The Bi and LixBi (x = 1, 3) produced during the conversion and alloying reactions of Bi2S3 can reduce the internal resistance of the Si/Bi2S3 composite. Thus, at a current density of 500 mA g-1, the initial charge -discharge specific capacity of Si/Bi2S3 is 2240.5/2767.8 mAh g-1. After 200 cycles, the discharge specific capacity can achieve 1443.3 mAh g-1, with a capacity retention of 52.1 %.

Keyword :

Heterogeneous structure Heterogeneous structure Lithium-ion battery Lithium-ion battery Silicon anode Silicon anode

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GB/T 7714 Yang, Tao , Zhang, Yong , Zhang, Yijin et al. Improving the conductivity of silicon anode and the stability of solid electrolyte interface by Si/Bi2S3 nanocomposite [J]. | JOURNAL OF ENERGY STORAGE , 2024 , 84 .
MLA Yang, Tao et al. "Improving the conductivity of silicon anode and the stability of solid electrolyte interface by Si/Bi2S3 nanocomposite" . | JOURNAL OF ENERGY STORAGE 84 (2024) .
APA Yang, Tao , Zhang, Yong , Zhang, Yijin , Lin, Rongying . Improving the conductivity of silicon anode and the stability of solid electrolyte interface by Si/Bi2S3 nanocomposite . | JOURNAL OF ENERGY STORAGE , 2024 , 84 .
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Si/SnS2 Nanocomposite for Lithium Ion Battery Anodes SCIE
期刊论文 | 2023 , 6 (24) , 22767-22773 | ACS APPLIED NANO MATERIALS
WoS CC Cited Count: 3
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We introduced a Si/SnS2 anode material with a high energy density and excellent cycle stability. The structure of this Si/SnS2 composite material is nanosized SnS2 coated on the surface of nanosilicon. Using the structural advantages of the coating structure, combined with the lithium storage mechanism of tin disulfide, the performance of silicon materials has been improved from three aspects: alleviating the volume expansion effect, improving the stability of the solid electrolyte interface (SEI), and enhancing the electrical conductivity. The material exhibits very excellent performance when applied to lithium-ion battery anodes. At the current density of 0.5 Ag(-1), the specific discharge capacity of the electrode material is maintained at 2217 mAhg(-1) after 100 cycles, and the capacity retention rate reached 65.3%. It also has high Coulombic efficiency of 86.1% for the first cycle and 96-99.9% for the following cycles.

Keyword :

Anode material Anode material Li2S Li2S Lithium-ionbattery Lithium-ionbattery Silicon Silicon SnS2 SnS2

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GB/T 7714 Yang, Tao , Zhu, Junchao , Zhang, Yijin et al. Si/SnS2 Nanocomposite for Lithium Ion Battery Anodes [J]. | ACS APPLIED NANO MATERIALS , 2023 , 6 (24) : 22767-22773 .
MLA Yang, Tao et al. "Si/SnS2 Nanocomposite for Lithium Ion Battery Anodes" . | ACS APPLIED NANO MATERIALS 6 . 24 (2023) : 22767-22773 .
APA Yang, Tao , Zhu, Junchao , Zhang, Yijin , Zhang, Yong , Lin, Rongying . Si/SnS2 Nanocomposite for Lithium Ion Battery Anodes . | ACS APPLIED NANO MATERIALS , 2023 , 6 (24) , 22767-22773 .
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Improving the electrochemical performance of silicon materials by SnO2 through structural design and conductivity SCIE
期刊论文 | 2022 , 581 | APPLIED SURFACE SCIENCE
WoS CC Cited Count: 8
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The Si material of the highest theoretical capacity (4200 mAh.g(-1)) cannot be commercially applied in real life owing to its vast volume expansion during the charge-discharge process and low electrical conductivity. Here, we introduce a Si@SnO2 material with a coating structure, in which SnO2 is coated on the surface of the silicon material. The coating structure can effectively alleviate the volume expansion stress of the silicon material. The Sn produced by the reaction of SnO2 with Li during the first cycle has good conductivity, thereby improving the electrochemical performance of the silicon material. The electrochemical performance of the material is excel-lent. At the current density of 0.2A.g(-1), the first coulombic efficiency of the battery reaches 84.1%, and the specific discharge capacity of the battery can be reached at 1926mAh.g(-1) after 200 cycles.

Keyword :

Anode material Anode material Coat Coat Lithium -ion battery Lithium -ion battery Silicon Silicon SnO2 SnO2

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GB/T 7714 Zhu, Junchao , Wang, Hui , Lin, Rongying . Improving the electrochemical performance of silicon materials by SnO2 through structural design and conductivity [J]. | APPLIED SURFACE SCIENCE , 2022 , 581 .
MLA Zhu, Junchao et al. "Improving the electrochemical performance of silicon materials by SnO2 through structural design and conductivity" . | APPLIED SURFACE SCIENCE 581 (2022) .
APA Zhu, Junchao , Wang, Hui , Lin, Rongying . Improving the electrochemical performance of silicon materials by SnO2 through structural design and conductivity . | APPLIED SURFACE SCIENCE , 2022 , 581 .
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SnS nanoparticles as an artificial solid electrolyte interphase and effective conductive additive in silicon anodes SCIE
期刊论文 | 2021 , 399 | ELECTROCHIMICA ACTA
WoS CC Cited Count: 2
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Abstract :

Using a simple hydrothermal method, we developed a Si@SnS anode material with SnS nanoparticles uni-formly attached to the surface of silicon nanoparticles. Utilizing the first charge-discharge reaction mech-anism of SnS, combined with the artificial solid electrolyte interphase to improve the solid electrolyte interphase stability of silicon-based materials and the introduction of conductive additives to improve the conductive properties of silicon-based materials, the Si@SnS material exhibits very excellent perfor-mance when applied to lithium-ion battery anodes. At a current density of 0.5A.g-1,after two cycles, the overall resistance of the Si@SnS material battery is reduced by nearly 55% relative to the resistance of the pure silicon battery. As a half-cell anode material, the first coulombic efficiency of Si@SnS at a current density of 1A.g -1 reached 85%, and after 200 cycles, it provided a reversible capacity of 1790 mAh.g -1 and a capacity retention rate of 74.6%. (c) 2021 Elsevier Ltd. All rights reserved.

Keyword :

Anode material Anode material Artificial SEI film Artificial SEI film Conductive additive Conductive additive Lithium-ion battery Lithium-ion battery SnS SnS

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GB/T 7714 Zhu, Junchao , Yang, Tao , Fu, Yunhan et al. SnS nanoparticles as an artificial solid electrolyte interphase and effective conductive additive in silicon anodes [J]. | ELECTROCHIMICA ACTA , 2021 , 399 .
MLA Zhu, Junchao et al. "SnS nanoparticles as an artificial solid electrolyte interphase and effective conductive additive in silicon anodes" . | ELECTROCHIMICA ACTA 399 (2021) .
APA Zhu, Junchao , Yang, Tao , Fu, Yunhan , Sheng, Bibo , Lin, Rongying . SnS nanoparticles as an artificial solid electrolyte interphase and effective conductive additive in silicon anodes . | ELECTROCHIMICA ACTA , 2021 , 399 .
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Well-dispersed double carbon layers coated on Si nanoparticles and the enhanced electrochemical performance for lithium ion batteries SCIE
期刊论文 | 2020 , 31 (17) , 14912-14920 | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
WoS CC Cited Count: 7
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The amorphous carbon was coated on the surface of the nano-silicon with citric acid by a simple mechanical stirring in water bath method and high temperature pyrolysis method, and then the carbon-coated silicon composite material(Si@C) was coated with polyvinyl alcohol by the secondary mechanical stirring and high temperature pyrolysis to obtain double carbon layer-coated silicon composite material (Si@C@C). The microstructure and surface morphology of Si@C@C were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical properties of Si@C@C were investigated by constant current charge-discharge, cyclic voltammetry, and electrochemical impedance spectra techniques. The study found that the first reversible specific capacity of Si@C@C was 1669 mAh/g at the current density of 0.1 C. The specific capacity remained at 1300 mAh/g, while the capacity retention rate was 77.9% after 200 cycles. The cyclic stability of Si@C@C was higher than that of Si@C, which greatly improved the electrochemical performance of silicon-based materials as anode materials for lithium ion batteries.

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GB/T 7714 Man, Yi , Lin, Rong-ying . Well-dispersed double carbon layers coated on Si nanoparticles and the enhanced electrochemical performance for lithium ion batteries [J]. | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS , 2020 , 31 (17) : 14912-14920 .
MLA Man, Yi et al. "Well-dispersed double carbon layers coated on Si nanoparticles and the enhanced electrochemical performance for lithium ion batteries" . | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 31 . 17 (2020) : 14912-14920 .
APA Man, Yi , Lin, Rong-ying . Well-dispersed double carbon layers coated on Si nanoparticles and the enhanced electrochemical performance for lithium ion batteries . | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS , 2020 , 31 (17) , 14912-14920 .
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锂离子电池碳包硅/石墨复合材料的制备及其电化学性能研究 CSCD PKU
期刊论文 | 2020 , 48 (6) , 72-76 | 化工新型材料
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采用简单的机械球磨法和高温热解法将热解碳包覆在纳米硅表面,再通过二次球磨制备出碳包硅/石墨复合材料.采用X射线衍射(XRD)、扫描电镜(SEM)对复合材料的微观结构和表面形貌进行表征,并将该复合材料制成扣式电池,对其进行恒流充放电循环性能测试和交流阻抗测试.研究发现,碳包硅/石墨复合材料首次可逆比容量为1026mAh/g,经过50次循环后,比容量仍然保持在875.4mAh/g,容量保持率为82.27%.循环稳定性远高于单一的碳包硅材料,极大地提高了硅基材料作为锂离子电池负极材料的电化学性能.

Keyword :

循环稳定性 循环稳定性 机械球磨法 机械球磨法 锂离子电池 锂离子电池 锂离子电池碳包硅/石墨复合材料 锂离子电池碳包硅/石墨复合材料

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GB/T 7714 李媛媛 , 满意 , 林荣英 et al. 锂离子电池碳包硅/石墨复合材料的制备及其电化学性能研究 [J]. | 化工新型材料 , 2020 , 48 (6) : 72-76 .
MLA 李媛媛 et al. "锂离子电池碳包硅/石墨复合材料的制备及其电化学性能研究" . | 化工新型材料 48 . 6 (2020) : 72-76 .
APA 李媛媛 , 满意 , 林荣英 , 洪若瑜 . 锂离子电池碳包硅/石墨复合材料的制备及其电化学性能研究 . | 化工新型材料 , 2020 , 48 (6) , 72-76 .
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铝钙复合物对福建低灰熔点煤灰的影响 PKU
期刊论文 | 2020 , 48 (1) , 116-121 | 福州大学学报(自然科学版)
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选取龙岩(LY)和上京(SJ)两种福建低灰熔点煤,利用灰熔点测定仪研究氧化铝、氧化钙及铝钙复合物对两种煤灰熔融温度的影响规律.研究结果表明:加入Al2O3(4%~18%,质量分数,下同)可以一直提高灰熔点,加入CaO(2%~8%)使灰熔点降低.但LY灰、SJ灰中添加较多Al2O3后再加少量CaO可使灰熔点比对应只加Al2 O3的高,表现出铝钙协同作用.通过XRD和SEM-EDX分析煤灰在高温下的矿物转化行为、表面微观形貌及化学组成,研究铝钙协同作用对低灰熔点煤的影响规律及其机理.结果发现:加入氧化铝后,煤灰在高温下生成的耐熔矿物莫来石是提高灰熔点的主要因素;加入较高含量的氧化铝和少量的氧化钙后,灰中先生成莫来石矿物,其中的氧化钙则会生成钙长石;在有莫来石存在时,钙长石与莫来石一起导致其熔融温度升高,从而提高灰熔点.

Keyword :

协同作用 协同作用 灰熔融温度 灰熔融温度 煤灰 煤灰 铝钙复合物 铝钙复合物

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GB/T 7714 林荣英 , 林晨昊 , 周家华 et al. 铝钙复合物对福建低灰熔点煤灰的影响 [J]. | 福州大学学报(自然科学版) , 2020 , 48 (1) : 116-121 .
MLA 林荣英 et al. "铝钙复合物对福建低灰熔点煤灰的影响" . | 福州大学学报(自然科学版) 48 . 1 (2020) : 116-121 .
APA 林荣英 , 林晨昊 , 周家华 , 张柏茂 . 铝钙复合物对福建低灰熔点煤灰的影响 . | 福州大学学报(自然科学版) , 2020 , 48 (1) , 116-121 .
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Process design for production of tetrahydrothiophene from hydrogen sulfide waste gas [硫化氢废气生产四氢噻吩工艺设计] Scopus CSCD PKU
期刊论文 | 2019 , 39 (2) , 207-210 and 212 | Modern Chemical Industry
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Hydrogen sulfide, the main component in the waste gas source from viscose fiber factory, is used as raw material after purification through the rectisol process to react with 1, 4-butanediol. The reactive products are separated and refined to obtain 99wt% tetrahydrothiophene. The whole process is simulated by means of Aspen Plus software, the process conditions such as the number of trays, feed position and reflux ratio are optimized, and the optimal process conditions are determined. In addition, electric energy can be saved by 37.7% and rectification operation cost can cut by 14% through improving the traditional technology and optimizing design of energy-saving scheme. © 2019, China National Chemical Information Center. All right reserved.

Keyword :

Aspen Plus; Hydrogen sulfide; Rectisol; Tetrahydrothiophene Aspen Plus; Hydrogen sulfide; Rectisol; Tetrahydrothiophene

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GB/T 7714 Luo, Z.-Y. , Li, Y.-Y. , Hong, R.-Y. et al. Process design for production of tetrahydrothiophene from hydrogen sulfide waste gas [硫化氢废气生产四氢噻吩工艺设计] [J]. | Modern Chemical Industry , 2019 , 39 (2) : 207-210 and 212 .
MLA Luo, Z.-Y. et al. "Process design for production of tetrahydrothiophene from hydrogen sulfide waste gas [硫化氢废气生产四氢噻吩工艺设计]" . | Modern Chemical Industry 39 . 2 (2019) : 207-210 and 212 .
APA Luo, Z.-Y. , Li, Y.-Y. , Hong, R.-Y. , Lin, R.-Y. . Process design for production of tetrahydrothiophene from hydrogen sulfide waste gas [硫化氢废气生产四氢噻吩工艺设计] . | Modern Chemical Industry , 2019 , 39 (2) , 207-210 and 212 .
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硫化氢废气生产四氢噻吩工艺设计 CSCD PKU
期刊论文 | 2019 , 39 (2) , 207-210,212 | 现代化工
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以黏胶纤维厂废气源中主要成分硫化氢为原料,采用低温甲醇洗工艺,硫化氢气体经分离提纯后与1,4-丁二醇反应,反应后产物经过分离及精制得到质量分数为99%的四氢噻吩产品.采用Aspen Plus软件对该工艺进行了全流程模拟,并对塔的塔板数、进料位置、回流比等工艺条件进行了优化,确定了最佳的工艺操作条件.同时通过对传统工艺改进和节能方案的优化设计可以节约电能37.7%及精馏操作成本14%.

Keyword :

Aspen Plus Aspen Plus 低温甲醇洗 低温甲醇洗 四氢噻吩 四氢噻吩 硫化氢 硫化氢

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GB/T 7714 罗祖云 , 李媛媛 , 洪若瑜 et al. 硫化氢废气生产四氢噻吩工艺设计 [J]. | 现代化工 , 2019 , 39 (2) : 207-210,212 .
MLA 罗祖云 et al. "硫化氢废气生产四氢噻吩工艺设计" . | 现代化工 39 . 2 (2019) : 207-210,212 .
APA 罗祖云 , 李媛媛 , 洪若瑜 , 林荣英 . 硫化氢废气生产四氢噻吩工艺设计 . | 现代化工 , 2019 , 39 (2) , 207-210,212 .
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