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学者姓名：林树坤
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Abstract ：
依托国家人才培养基金项目和福州大学本科生科研训练项目(SRTP),在化学专业本科生中开展科研能力提高训练.为了保证项目的实施和训练的效果,项目提出包括项目的申报,科研精神和内涵的培养、科研能力提高训练过程、项目结果表达与成果总结以及评价体系的制定.为完善本科实践教学环节打下理论基础.
Keyword ：
科研训练 科研训练 能力提高 能力提高 评价体系 评价体系
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| GB/T 7714 | 林树坤 , 林旭聪 . 本科生科研能力提高训练项目与评价体系的制定 [J]. | 教育教学论坛 , 2016 , (52) : 214-215 . |
| MLA | 林树坤 等. "本科生科研能力提高训练项目与评价体系的制定" . | 教育教学论坛 52 (2016) : 214-215 . |
| APA | 林树坤 , 林旭聪 . 本科生科研能力提高训练项目与评价体系的制定 . | 教育教学论坛 , 2016 , (52) , 214-215 . |
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Two new heterometallic inorganic-organic hybrids containing polynuclear halobismuthates anions and ruthenium complex cations, i.e., [Ru(tpy)(2)](2)[(Bi2I7Cl2)center dot I] (1), [Ru(bipy)(2)(bipyo](2)(Bi4I16) (2), (tpy = 2,2':6',2aEuro(3)-terpyridine, bipy = 2,2'-bipyridine, bipyo = 2,2'-bipyridine-6-olato) have been structurally determined. These hybrids are the rare examples of mixed-metal halobismuthates containing photochemically active coordination cations, and 1 consists of mixed halo atoms. C-H center dot center dot center dot I hydrogen bonds among halobismuthates clusters and [Ru(tpy)(2)](2+)/[Ru(bipy)(2)(bipyo](2+) countercations contribute to the formation of a 3-D network. Moreover, their absorption spectra and photoluminescence have also been discussed, and their absorption edges fall in the range of those of semiconductors. Two new heterometallic inorganic-organic hybrids containing polynuclear halobismuthates anions and ruthenium complex cations have been structurally determined, which represent the rare examples of mixed-metal halobismuthates containing photochemically active coordination cation and mixed halo atoms. C-H center dot center dot center dot I hydrogen bonds contribute to the formation of a 3-D network, and their absorption spectra and photoluminescence have also been discussed.
Keyword ：
Iodobismuthate Iodobismuthate Organic-inorganic hybrid Organic-inorganic hybrid Photoluminescence Photoluminescence
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| GB/T 7714 | Lin, Chun-Cai , Wang, Peng , Jin, Lu et al. Heterometallic Inorganic-Organic Hybrids Containing Polynuclear Halobismuthates Anions and d-Metal Coordination Cations: Structure and Physical Properties [J]. | JOURNAL OF CLUSTER SCIENCE , 2015 , 26 (3) : 1011-1022 . |
| MLA | Lin, Chun-Cai et al. "Heterometallic Inorganic-Organic Hybrids Containing Polynuclear Halobismuthates Anions and d-Metal Coordination Cations: Structure and Physical Properties" . | JOURNAL OF CLUSTER SCIENCE 26 . 3 (2015) : 1011-1022 . |
| APA | Lin, Chun-Cai , Wang, Peng , Jin, Lu , Li, Hao-Hong , Lin, Shu-Kun , Chen, Zhi-Rong . Heterometallic Inorganic-Organic Hybrids Containing Polynuclear Halobismuthates Anions and d-Metal Coordination Cations: Structure and Physical Properties . | JOURNAL OF CLUSTER SCIENCE , 2015 , 26 (3) , 1011-1022 . |
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Abstract ：
研究型《综合化学实验》是一门为化学专业本科生开设的开放式研究型实践课程。为了培养学生的创新思维，提高实践能力，课程教学综合了化学、生物学和材料学等学科的知识内容，以及应用了现代研究手段和实验技术。学生通过本课程的学习和训练，达到巩固和提高对基础理论知识的加深理解，全面提高了科学思维、创新意识及创新能力。
Keyword ：
创新思维 创新思维 创新能力 创新能力 研究型实践课程 研究型实践课程
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| GB/T 7714 | 林树坤 . 创新性人才培养中研究型综合化学实验课程的建设 [J]. | 教育教学论坛 , 2015 , (30) : 79-81 . |
| MLA | 林树坤 . "创新性人才培养中研究型综合化学实验课程的建设" . | 教育教学论坛 30 (2015) : 79-81 . |
| APA | 林树坤 . 创新性人才培养中研究型综合化学实验课程的建设 . | 教育教学论坛 , 2015 , (30) , 79-81 . |
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培养本科生的科研意识，鼓励本科生尽早进入研究领域，是培养具有实践和创新能力本科人才一个十分重要的途径。在对国内外本科生开展科研训练的过程和现状进行详细分析基础上，通过对课程体系改革，完善科研训练章程，强化参与激励机制，构建长效的科研训练体系。以科研兴趣和创新意识，课题立项和组织能力，科研动手、实验操作及科研协作，成果表达能力与学术交流能力等基本内容和训练等环节的设计。制定出福州大学化学专业本科生开展科研训练的具体实施方案。
Keyword ：
Ability Cultivation Ability Cultivation Ability Increase Ability Increase Research Training Research Training 科研意识 科研意识 科研训练 科研训练 能力培养 能力培养 能力提高Scientific Awareness 能力提高Scientific Awareness
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| GB/T 7714 | 林树坤 , 王绪绪 , 林旭聪 . 本科生科研能力培养的思考与方案 [J]. | 创新教育研究 , 2015 , 3 (03) : 82-89 . |
| MLA | 林树坤 et al. "本科生科研能力培养的思考与方案" . | 创新教育研究 3 . 03 (2015) : 82-89 . |
| APA | 林树坤 , 王绪绪 , 林旭聪 . 本科生科研能力培养的思考与方案 . | 创新教育研究 , 2015 , 3 (03) , 82-89 . |
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Ga-doped Gd3Fe5O12 (GIG) single-crystals with various doping concentration were successfully grown by the edge-defined film fed growth (EFG) technique. XRD pattern and SEM micrographs confirm that the as-grown crystal is in the single GIG phase with good crystal quality. The success of growing Ga:GIG crystal by using EFG method provide a new way to grow the single crystal of the incongruent melting compound. The magnetic parameters such as the Curie temperature T-c, the saturation magnetization 1145, the magnetic coercivity H-c, the magnetic saturation field H-s, the Faraday rotation angle of as-grown crystals were measured. After as-grown crystal was annealed at 800 degrees C in oxygen atmosphere, the optical transmittance can be significantly enhanced. The reason for the change of the saturation magnetization M-s, before and after annealing is also discussed. (C) 2014 Elsevier B.V. All rights reserved.
Keyword ：
Edge-defined film fed growth (EFG) Edge-defined film fed growth (EFG) Gd-3(GaFe)(5)O-12 Gd-3(GaFe)(5)O-12 Incongruent melting compound Incongruent melting compound Magnetic properties Magnetic properties Magneto-optical properties Magneto-optical properties Transmission spectra Transmission spectra
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| GB/T 7714 | Zhuang, Nai Feng , Wang, Chun Nan , Wei, Qing Ke et al. EFG growth and optical properties of incongruent-melting Ga3+:GIG single crystal [J]. | OPTICAL MATERIALS , 2014 , 36 (7) : 1160-1164 . |
| MLA | Zhuang, Nai Feng et al. "EFG growth and optical properties of incongruent-melting Ga3+:GIG single crystal" . | OPTICAL MATERIALS 36 . 7 (2014) : 1160-1164 . |
| APA | Zhuang, Nai Feng , Wang, Chun Nan , Wei, Qing Ke , Liu, Xiao Feng , Hu, Xiao Lin , Zhao, Bin et al. EFG growth and optical properties of incongruent-melting Ga3+:GIG single crystal . | OPTICAL MATERIALS , 2014 , 36 (7) , 1160-1164 . |
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Keyword ：
(La,Sr)(Al,Ta)O3晶体 (La,Sr)(Al,Ta)O3晶体 提拉法 提拉法 色心 色心
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| GB/T 7714 | 徐前瑞 , 付秋平 , 廖步云 et al. (La,Sr)(Al,Ta)O3晶体的生长及色心形成机理 [C] //中国化学会第29届学术年会摘要集-第13分会:晶体工程 . 2014 . |
| MLA | 徐前瑞 et al. "(La,Sr)(Al,Ta)O3晶体的生长及色心形成机理" 中国化学会第29届学术年会摘要集-第13分会:晶体工程 . (2014) . |
| APA | 徐前瑞 , 付秋平 , 廖步云 , 胡晓琳 , 庄乃锋 , 林树坤 et al. (La,Sr)(Al,Ta)O3晶体的生长及色心形成机理 中国化学会第29届学术年会摘要集-第13分会:晶体工程 . (2014) . |
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A new low-dimensional benzyl viologen/iodoargentate hybrid, [(BV) 2(Ag5I9)]n (1) (BV2+ = benzyl viologen) was prepared. In 1, (Ag6I9) n2- chain exhibits a new type of one-dimensional chain constructed from vertex-sharing of Ag5I10 units, and its two-dimensional layer structure was constructed from C- H···I hydrogen bonds. Strong luminescence at 404 nm can be detected in 1. DFT calculation suggests that 1 displays a reduced bandgap, which is led by a more dispersed LUMO band of BV2+ compared with MV 2+ in [MV(Ag2I4)]n. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keyword ：
Benzyl viologen; DFT calculation; Iodoargentate; Organic-inorganic hybrid Benzyl viologen; DFT calculation; Iodoargentate; Organic-inorganic hybrid
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| GB/T 7714 | Chen, Q.-Y. , Cheng, X. , Wang, T. et al. A low-dimensional viologen/iodoargentate hybrid [(BV)2(Ag 5I9)]n: Structure, properties, and theoretical study [J]. | Zeitschrift fur Anorganische und Allgemeine Chemie , 2014 , 640 (2) : 439-443 . |
| MLA | Chen, Q.-Y. et al. "A low-dimensional viologen/iodoargentate hybrid [(BV)2(Ag 5I9)]n: Structure, properties, and theoretical study" . | Zeitschrift fur Anorganische und Allgemeine Chemie 640 . 2 (2014) : 439-443 . |
| APA | Chen, Q.-Y. , Cheng, X. , Wang, T. , Yu, Z.-H. , Zhang, C. , Lin, S.-K. et al. A low-dimensional viologen/iodoargentate hybrid [(BV)2(Ag 5I9)]n: Structure, properties, and theoretical study . | Zeitschrift fur Anorganische und Allgemeine Chemie , 2014 , 640 (2) , 439-443 . |
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Abstract ：
以石蜡为主要原料，加入一定量的微晶蜡，采用纯氧气进行催化氧化改性，考察了反应温度、反应时间、氧气流速、催化剂用量、助剂用量等因素对氧化蜡性质的影响。结果表明，氧化蜡的结构中出现羰基官能团；在以质量分数为0.52％的硫酸锰为催化剂，质量分数为12％的硬脂酸为助剂，氧气流速为75~85 mL/ min，150℃条件下4 h，可以得到色泽浅、气味轻、酸值为23.44 mg KOH/ g，皂化值为49.13 mg KOH/ g 的优质氧化蜡。
Keyword ：
氧化 氧化 皂化值 皂化值 石蜡 石蜡 酸值 酸值
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| GB/T 7714 | 汪程红 , 林树坤 . 氧化蜡的制备及其性能研究 [J]. | 应用化工 , 2014 , (5) : 890-893 . |
| MLA | 汪程红 et al. "氧化蜡的制备及其性能研究" . | 应用化工 5 (2014) : 890-893 . |
| APA | 汪程红 , 林树坤 . 氧化蜡的制备及其性能研究 . | 应用化工 , 2014 , (5) , 890-893 . |
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Although terbium gallium garnet (TGG) single crystals suitable for practical applications have been grown by the Czochralski technique due to its congruent melting nature, the inter face shape readily deteriorates to spiral growth when grown with a flat inter face or facet formation when grown with a convex interface. The Edge-defined Film-fed Growth (EFG) method was used to grow TGG crystals for the first time. The influence of the raw material sintering temperature, growth atmosphere, growth rate and other growth conditions on the crystal quality were investigated. The Verdet constant of as-grown crystal was measured as 39 rad/T.m at 1064 nm by the extinction method, which was close to the literature value. The source of color centers in the crystals is also discussed. (C) 2013 Elsevier B.V. All rights reserved.
Keyword ：
Crystal defects Crystal defects Edge-defined film-fed growth method Edge-defined film-fed growth method Magneto-optic crystal Magneto-optic crystal TGG crystal TGG crystal XPS XPS
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| GB/T 7714 | Zhuang, Naifeng , Song, Caigen , Guo, Liwei et al. Growth of terbium gallium garnet (TGG) magneto-optic crystals by edge-defined film-fed growth method [J]. | JOURNAL OF CRYSTAL GROWTH , 2013 , 381 : 27-32 . |
| MLA | Zhuang, Naifeng et al. "Growth of terbium gallium garnet (TGG) magneto-optic crystals by edge-defined film-fed growth method" . | JOURNAL OF CRYSTAL GROWTH 381 (2013) : 27-32 . |
| APA | Zhuang, Naifeng , Song, Caigen , Guo, Liwei , Wang, Rongfeng , Hu, Xiaolin , Zhao, Bin et al. Growth of terbium gallium garnet (TGG) magneto-optic crystals by edge-defined film-fed growth method . | JOURNAL OF CRYSTAL GROWTH , 2013 , 381 , 27-32 . |
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Crystalline yttrium iron garnet (YIG) is an important magneto-optical material. However, this crystal is an incongruent melting compound. As is well known, compared to the crystal growth of a congruent melting compound by using the Czochralski method, the crystal growth of an incongruent melting compound is more difficult. In this work, a system for growing Ga:YIG single crystals by the edge-defined film-fed growth (EFG) method was designed and constructed, and the mechanism of crystal growth was also preliminarily studied. The Ga3+ dopant concentration, the Curie temperature and the transmission spectra of as-grown crystals were investigated to evaluate their potential application in magneto-optical devices. The success of growing Ga: YIG crystals by the EFG method provides a new way to grow other incongruent melting compounds.
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| GB/T 7714 | Zhuang, Naifeng , Chen, Wenbing , Shi, Lijun et al. A new technique to grow incongruent melting Ga:YIG crystals: the edge-defined film-fed growth method [J]. | JOURNAL OF APPLIED CRYSTALLOGRAPHY , 2013 , 46 : 746-751 . |
| MLA | Zhuang, Naifeng et al. "A new technique to grow incongruent melting Ga:YIG crystals: the edge-defined film-fed growth method" . | JOURNAL OF APPLIED CRYSTALLOGRAPHY 46 (2013) : 746-751 . |
| APA | Zhuang, Naifeng , Chen, Wenbing , Shi, Lijun , Nie, Jianbiao , Hu, Xiaolin , Zhao, Bin et al. A new technique to grow incongruent melting Ga:YIG crystals: the edge-defined film-fed growth method . | JOURNAL OF APPLIED CRYSTALLOGRAPHY , 2013 , 46 , 746-751 . |
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