Query：
学者姓名：鲍晓军
Refining：
Year
Type
Indexed by
Source
Complex
Co-
Language
Clean All
Abstract ：
以苯胺和N-羟基邻苯二甲酰亚胺(NHPI)为原料,经缩合偶联反应得到N-苯基邻苯二甲酰亚胺,产物经核磁共振氢谱确证.缩合偶联反应的优化条件为:以2,2'-联吡啶为助催化剂,氯化亚铜(CuCl)为催化剂,物料比n(2,2'-联吡啶)∶n(氯化亚铜)∶n(苯胺)∶n(N-羟基邻苯二甲酰亚胺)=0.1∶0.2∶1.0∶1.0,乙腈为溶剂、温度为70 ℃、反应时间为4 h,反应气体环境为氧气,产物收率达82.0％.
Keyword ：
2 2 2’-联吡啶 2’-联吡啶 N-羟基邻苯二甲酰亚胺 N-羟基邻苯二甲酰亚胺 N-苯基邻苯二甲酰亚胺 N-苯基邻苯二甲酰亚胺 氯化亚铜 氯化亚铜 苯胺 苯胺
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | 南沛然 , 王博闻 , 李世云 et al. N-苯基邻苯二甲酰亚胺的合成 [J]. | 精细石油化工 , 2025 , 42 (2) : 48-51 . |
| MLA | 南沛然 et al. "N-苯基邻苯二甲酰亚胺的合成" . | 精细石油化工 42 . 2 (2025) : 48-51 . |
| APA | 南沛然 , 王博闻 , 李世云 , 文彬 , 陈兴权 , 鲍晓军 . N-苯基邻苯二甲酰亚胺的合成 . | 精细石油化工 , 2025 , 42 (2) , 48-51 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Electrochemical biomass upgrading is a promising substitute for oxygen evolution reaction (OER) to generate valuable chemicals in conjunction with hydrogen generation. Pursuing highly efficient and durable electrocatalysts for significant concentration levels (≥ 50 mM) of biomass electrooxidation remains an enduring challenge. Herein, we introduce a robust Cu-supported CoFe Prussian blue analogue (CoFe PBA/CF) electrocatalyst, adept at facilitating high-concentration (50 mM) 5-hydroxymethylfurfural (HMF) oxidation into 2,5-furandicarboxylic acid (FDCA), achieving an exceptional HMF conversion (100%) with a notable FDCA yield of 98.4%. The influence of copper substrate and adsorption energy are therefore discussed. Impressively, the CoFe PBA/CF electrode sustains considerable durability in a continuous-flow electrochemical reactor designed for consecutive FDCA production, showcasing FDCA yields of 100/94% at flow rates of 0.4/0.8 mL·min-1 over 60 h’ uninterrupted electrolysis. This work provides a promising strategy to develop highly efficient and robust electrocatalysts for the consecutive production of high-value products coupled with green H2 production. © The Author(s) 2025.
Keyword ：
5-hydroxymethylfurfural oxidation 5-hydroxymethylfurfural oxidation CoFe Prussian blue analogues CoFe Prussian blue analogues electrochemical conversion electrochemical conversion high concentration high concentration structural reconstruction structural reconstruction
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Zhang, B. , Xiao, T. , Hu, C. et al. Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues [J]. | Chemical Synthesis , 2025 , 5 (1) . |
| MLA | Zhang, B. et al. "Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues" . | Chemical Synthesis 5 . 1 (2025) . |
| APA | Zhang, B. , Xiao, T. , Hu, C. , Liu, Z. , Chen, P. , Zhao, Z. et al. Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues . | Chemical Synthesis , 2025 , 5 (1) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
采用Sandmeyer法以3-氯-2-甲基苯胺为原料,亚硝酸钠为重氮化试剂,在低温、酸性环境下得到重氮盐,再利用铜基催化剂、不同温度的条件下分解,得到2-氯-6-溴甲苯.适宜合成条件为:以30％硫酸溶解胺,以亚硝酸钠的硫酸溶液成盐,以氢溴酸为溴源、铜粉为催化剂、在0 ℃分解.其中,酸用量为原料的5倍,n(3-氯-2-甲基苯胺)∶n(亚硝酸钠)∶n(铜粉)∶n(工业氢溴酸)=1∶1.2∶0.1∶1.2,2-溴-6-氯甲苯的收率可达95％.
Keyword ：
2-溴-6-氯甲苯 2-溴-6-氯甲苯 3-氯-2-甲基苯胺 3-氯-2-甲基苯胺 Sandmeyer反应 Sandmeyer反应 亚硝酸钠 亚硝酸钠 重氮盐 重氮盐
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | 王博闻 , 南沛然 , 李世云 et al. Sandmeyer法合成2-溴-6-氯甲苯 [J]. | 精细石油化工 , 2025 , 42 (1) : 23-26 . |
| MLA | 王博闻 et al. "Sandmeyer法合成2-溴-6-氯甲苯" . | 精细石油化工 42 . 1 (2025) : 23-26 . |
| APA | 王博闻 , 南沛然 , 李世云 , 文彬 , 陈兴权 , 鲍晓军 . Sandmeyer法合成2-溴-6-氯甲苯 . | 精细石油化工 , 2025 , 42 (1) , 23-26 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Alkaline water electrolysis is one of the most prospective technologies for large-scale production of green hydrogen. Nevertheless, current porous membranes face the problem of weak ion transport or poor gas barrier performance. Here, we demonstrate a facile yet massive two-step casting and phase separation strategy to design a thin, asymmetric pore-structure modulated composite membrane for efficient, safe, and industrial-grade alkaline water electrolysis. The prepared composite membrane shows better electrolytic performance (1.71 V at 1 A cm-2) and stability (working for 6352 h). In addition, an industrial-grade electrolyzer equipped with composite membranes exhibits higher hydrogen production efficiency (1.03 Nm3h-1), H2 purity (99.9%), and faster dynamic response (less than 20 min) compared to mainstream commercial membranes. Ultimately, we propose a semi-empirical model based on the operational characteristics of an electrolyzer equipped with composite membranes and predicting its matching behavior with dynamic renewable energy sources. This work explores the viability of manufacturing high-performance alkaline water electrolysis membranes for green hydrogen production under industrial conditions.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | You, Jian , Lu, Jinyu , Liu, Chuanli et al. A rationally thin composite membrane with differentiated pore structure for industrial-scale alkaline water electrolysis [J]. | NATURE COMMUNICATIONS , 2025 , 16 (1) . |
| MLA | You, Jian et al. "A rationally thin composite membrane with differentiated pore structure for industrial-scale alkaline water electrolysis" . | NATURE COMMUNICATIONS 16 . 1 (2025) . |
| APA | You, Jian , Lu, Jinyu , Liu, Chuanli , Wang, Wei , Li, Yongzhao , Gao, Yuanzhong et al. A rationally thin composite membrane with differentiated pore structure for industrial-scale alkaline water electrolysis . | NATURE COMMUNICATIONS , 2025 , 16 (1) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Polyethylene oxide (PEO)-based electrolytes are essential to advance all-solid-state lithium batteries (ASSLBs) with high safety/energy density due to their inherent flexibility and scalability. However, the inefficient Li+ transport in PEO often leads to poor rate performance and diminished stability of the ASSLBs. The regulation of intermolecular H-bonds is regarded as one of the most effective approaches to enable efficient Li+ transport, while the practical performances are hindered by the electrochemical instability of free H-bond donors and the constrained mobility of highly ordered H-bonding structures. To overcome these challenges, we develop a surface-confined disordered H-bond system with stable donor-acceptor interactions to construct a loosened chain segments/ions arrangement in the bulk phase of PEO-based electrolytes, realizing the crystallization inhibition of PEO, weak coordination of Li+ and entrapment of anions, which are conducive to efficient Li+ transport and stable Li+ deposition. The rationally designed LiFePO4-based ASSLB demonstrates a long cycle-life of over 400 cycles at 1.0 C and 65 degrees C with a capacity retention rate of 87.5 %, surpassing most of the currently reported polymer-based ASSLBs. This work highlights the importance of confined disordered H-bonds on Li+ transport in an all-solid-state battery system, paving the way for the future design of polymer-based ASSLBs.
Keyword ：
all-solid-state Li batteries all-solid-state Li batteries H-bond H-bond Li+ transport Li+ transport polyethylene oxide polyethylene oxide polymer electrolytes polymer electrolytes
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Fan, You , Malyi, Oleksandr I. , Wang, Huicai et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 , 64 (11) . |
| MLA | Fan, You et al. "Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 64 . 11 (2025) . |
| APA | Fan, You , Malyi, Oleksandr I. , Wang, Huicai , Cheng, Xiangxin , Fu, Xiaobin , Wang, Jingshu et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 , 64 (11) . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
In order to gain insight into the influence of SiO2 support particle size on the vacuum residue (VR) slurry-phase hydrocracking performance of Fe-based catalysts, a series of FeZn/SiO2 catalysts with varying SiO2 particle sizes were prepared. Characterization results show that the surface area and pore volume of the FeZn/SiO2 catalysts increase with the reduction of SiO2 particle sizes. The metals Fe and Zn species on FeZn/SiO2-S catalyst are more readily reducible via H2-TPR analysis. Notably, FeZn/SiO2-S catalyst presents higher metal dispersion and a greater degree of sulfurization compared to the other catalysts by XRD and XPS. Hydrocracking results demonstrate that the FeZn/SiO2-S catalyst achieves the lowest coke and gas yields (11.9 wt% and 0.4 wt%), respectively, and the highest VR conversion among these catalysts. The superior performance of the FeZn/SiO2-S catalyst in VR slurry-phase hydrocracking is ascribed to its enhanced hydrogenation activity, deriving from the higher dispersion and sulfurization of metals species. This suppresses the aggregation of polycyclic aromatic hydrocarbons in VR and the over-cracking of intermediate products. Additionally, the increased mesopore associated with smaller SiO2 particles facilitates to the diffusion of large VR molecules, further promoting the hydrocracking reaction.
Keyword ：
FeZn catalyst FeZn catalyst Hydrogenation activity Hydrogenation activity SiO2 particle size SiO2 particle size Slurry-phase hydrocracking Slurry-phase hydrocracking Vacuum residue Vacuum residue
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking [J]. | CATALYSIS TODAY , 2025 , 449 . |
| MLA | Wang, Jianbo et al. "Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking" . | CATALYSIS TODAY 449 (2025) . |
| APA | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan , Li, Tiesen , Shi, Jie , Wang, Tinghai et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking . | CATALYSIS TODAY , 2025 , 449 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Deep hydrogenation of dicyclopentadiene resin (DCPD resin) plays an important role in enhancing its performance and broadening its applications. However, designing suitable catalysts for promoting DCPD resin deep hydrogenation remains a challenge due to the high steric hindrance and abundant unsaturated bonds in DCPD resin, requiring strong binding to C=C double bonds. We herein propose a strategy for simultaneously constructing highly-dispersed Ni particles for hydrogen dissociation and interfacial Ni0/Ni(OH)+ sites for C=C adsorption by controlled reduction of Ni phyllosilicate (Ni PS). The catalyst, after reduction at 400 degrees C, demonstrated balanced ratio between Ni0 and interfacial Ni0/Ni(OH)+ sites, and achieved a hydrogenation degree of 99.8% (TOF: 68.8 h-1) while maintaining 99.3% efficiency after seven consecutive cycles. Through in-situ DRIFTS analysis and density functional theory (DFT) calculations, it is confirmed that the introduction of Ni0/Ni(OH)+ interfacial sites results in superior activity compared to pure Ni0 or unreduced PS due to optimized charge transfer and electronic configuration. This work not only establishes a simple and environmentally-friendly approach to design efficient catalysts for polymer hydrogenation, but also provides insights into the mechanism of unsaturated bond hydrogenation through the synergistic effects of Ni0 and Ni0/Ni(OH)+ interfacial sites.
Keyword ：
DCPD resin DCPD resin Hydrogenation Hydrogenation Ni(OH) plus Ni(OH) plus Ni phyllosilicate Ni phyllosilicate
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Liu, Qunhong , Liu, Zhen , Yang, Zongxuan et al. Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 512 . |
| MLA | Liu, Qunhong et al. "Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin" . | CHEMICAL ENGINEERING JOURNAL 512 (2025) . |
| APA | Liu, Qunhong , Liu, Zhen , Yang, Zongxuan , Wu, Qingchen , Li, Zimeng , Liu, Zhichen et al. Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin . | CHEMICAL ENGINEERING JOURNAL , 2025 , 512 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Diffusion behavior of catalyst pores plays a crucial influence in polymer heterogeneous hydrogenation reactions. However, experimental methods on how to accurately measure the diffusion coefficient of polymer molecules are still lacking. Herein, we develop an in-situ infrared-based method combined with mathematical models to accurately obtain the diffusion coefficients of polymers and investigate the effect of pore size on the diffusion and hydrogenation performance. Taking dicyclopentadiene resin as the model polymer, the results show that the selected Pd/Al2O3 catalyst with a pore size of 14.7 nm possesses an apparent diffusion coefficient of 3.83 x 10-15 m2/s and exhibits the best catalytic hydrogenation activity with a hydrogenation degree of 98.4%. This study provides a universal method for measuring the diffusion coefficients of polymer molecules, which holds significant guiding importance for the further development of more efficient polymer hydrogenation catalysts.
Keyword ：
DCPD resin DCPD resin Diffusion coefficient Diffusion coefficient Heterogeneous hydrogenation Heterogeneous hydrogenation In-situ infrared spectroscopy In-situ infrared spectroscopy Pore size Pore size
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Liu, Qunhong , Song, Zhaohui , Zhang, Hongwei et al. Determination of diffusion coefficients of polymer molecules in porous Pd/ Al2O3 catalyst and their impact on the hydrogenation performance [J]. | CHEMICAL ENGINEERING SCIENCE , 2025 , 310 . |
| MLA | Liu, Qunhong et al. "Determination of diffusion coefficients of polymer molecules in porous Pd/ Al2O3 catalyst and their impact on the hydrogenation performance" . | CHEMICAL ENGINEERING SCIENCE 310 (2025) . |
| APA | Liu, Qunhong , Song, Zhaohui , Zhang, Hongwei , Hu, Dezheng , Hu, Cejun , Bao, Xiaojun et al. Determination of diffusion coefficients of polymer molecules in porous Pd/ Al2O3 catalyst and their impact on the hydrogenation performance . | CHEMICAL ENGINEERING SCIENCE , 2025 , 310 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
Elucidating the microstructure of hard carbon is essential for uncovering the sodium storage mechanism and constructing state-of-the-art hard carbon anodes for sodium-ion batteries. Guided by an understanding of the crystallization process and inverse materials design principles, we design hard carbon anodes with different local fragments to understand the correlation between the microstructure of hard carbon and sodium storage behavior from the commercialization perspective. The sodiation transformation of hard carbon from slope- to plateau-type is realized via a series of local structure rearrangements, including tuning of the interlayer distance, average crystallite width of graphitic domains, and defect density. We found that the increase in plateau capacity is mainly related to the transition from the critical interlayer distance to the average crystallite width of graphitic domain control, and is limited by the closed pore volume of hard carbon. During sodiation, the formation of NaF and Na2O in the slope region, as well as Na2O2 and NaO2 in the plateau region, is always accompanied by the production of Na2CO3. This work provides insights into understanding the sodium storage behavior in hard carbon anodes and defines general structural design principles for transitioning from slope-type to plateau-type hard carbon.
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Wang, Feng , Chen, Lian , Wei, Jiaqi et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement [J]. | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) : 4312-4323 . |
| MLA | Wang, Feng et al. "Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement" . | ENERGY & ENVIRONMENTAL SCIENCE 18 . 9 (2025) : 4312-4323 . |
| APA | Wang, Feng , Chen, Lian , Wei, Jiaqi , Diao, Caozheng , Li, Fan , Du, Congcong et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement . | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) , 4312-4323 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Abstract ：
In recent years, studies focusing on the conversion of renewable lignin-derived oxygenates (LDOs) have emphasized their potential as alternatives to fossil-based products. However, LDOs, existing as complex aromatic mixtures with diverse oxygen-containing functional groups, pose a challenge as they cannot be easily separated via distillation for direct utilization. A promising solution to this challenge lies in the efficient removal of oxygen-containing functional groups from LDOs through hydrodeoxygenation (HDO), aiming to yield biomass products with singular components. However, the high dissociation energy of the carbon-oxygen bond, coupled with its similarity to the hydrogenation energy of the benzene ring, creates a competition between deoxygenation and benzene ring hydrogenation. Considering hydrogen consumption and lignin properties, the preference is directed towards generating aromatic hydrocarbons rather than saturated components. Thus, the goal is to selectively remove oxygen-containing functional groups while preserving the benzene ring structure. Studies on LDOs conversion have indicated that the design of active components and optimization of reaction conditions play pivotal roles in achieving selective deoxygenation, but a summary of the correlation between these factors and the reaction mechanism is lacking. This review addresses this gap in knowledge by firstly summarizing the various reaction pathways for HDO of LDOs. It explores the impact of catalyst design strategies, including morphology modulation, elemental doping, and surface modification, on the adsorption-desorption dynamics between reactants and catalysts. Secondly, we delve into the application of advanced techniques such as spectroscopic techniques and computational modeling, aiding in uncovering the true active sites in HDO reactions and understanding the interaction of reactive reactants with catalyst surface-interfaces. Additionally, fundamental insights into selective deoxygenation obtained through these techniques are highlighted. Finally, we outline the challenges that lie ahead in the design of highly active and selective HDO catalysts. These challenges include the development of detection tools for reactive species with high activity at low concentrations, the study of reaction medium-catalyst interactions, and the development of theoretical models that more closely approximate real reaction situations. Addressing these challenges will pave the way for the development of efficient and selective HDO catalysts, (c) 2024 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Keyword ：
Catalyst design Catalyst design Hydrodeoxygenation Hydrodeoxygenation Lignin-derived oxygenates Lignin-derived oxygenates Targeted deoxidation Targeted deoxidation Techniques and theoretical calculation Techniques and theoretical calculation
Cite：
Copy from the list or Export to your reference management。
| GB/T 7714 | Wu, Xinru , Zhang, Hongwei , Hu, Cejun et al. Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques [J]. | GREEN ENERGY & ENVIRONMENT , 2025 , 10 (2) : 292-321 . |
| MLA | Wu, Xinru et al. "Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques" . | GREEN ENERGY & ENVIRONMENT 10 . 2 (2025) : 292-321 . |
| APA | Wu, Xinru , Zhang, Hongwei , Hu, Cejun , Bao, Xiaojun , Yuan, Pei . Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques . | GREEN ENERGY & ENVIRONMENT , 2025 , 10 (2) , 292-321 . |
| Export to | NoteExpress RIS BibTex |
Version ：
Export
| Results： |
Selected to |
| Format： |
