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学者姓名：沈超君
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Abstract ：
Two isostructural metal-organic frameworks formulated as [Gd-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(6)(H2O)]center dot DMF center dot H2O (1) and [Tb-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(5)(H2O)]center dot DMF center dot H2O (2) (H3L=3,5-di(4'-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln(7)(mu(3)-OH)(8)](13+) (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied.
Keyword ：
fluorescent fluorescent heptanuclear lanthanide cluster heptanuclear lanthanide cluster magnetic magnetic MOFs MOFs
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| GB/T 7714 | Liu, Lianchao , Shen, Chaojun , Dong, Fangfang et al. Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln(7)(mu(3)-OH)(8)](13+) Cluster [J]. | CHINESE JOURNAL OF CHEMISTRY , 2016 , 34 (2) : 210-214 . |
| MLA | Liu, Lianchao et al. "Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln(7)(mu(3)-OH)(8)](13+) Cluster" . | CHINESE JOURNAL OF CHEMISTRY 34 . 2 (2016) : 210-214 . |
| APA | Liu, Lianchao , Shen, Chaojun , Dong, Fangfang , Wang, Wenjing , Yuan, Daqiang . Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln(7)(mu(3)-OH)(8)](13+) Cluster . | CHINESE JOURNAL OF CHEMISTRY , 2016 , 34 (2) , 210-214 . |
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