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学者姓名：林梅金
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Abstract ：
Photochromic materials and room-temperature phosphorescence (RTP) are essential for applications in optoelectronics and bioimaging. Organic-inorganic hybrid materials, particularly those exhibiting donor-acceptor (D-A) characteristics through supramolecular interactions, have shown significant potential to integrate both photochromic and RTP properties. Among them, the anion-pi and pi-pi interactions have been extensively studied; however, the role of anion-pi-pi interactions in hybrid materials remains largely unexplored. This study investigated three naphthalenediimide-polyoxometalate (NDI-POM) hybrids: (H2DMAP-NDI)(HPW12O40)(NMP)2 (1), (HDMAP-NDI)2(HPW12O40)(NMP)2 (2), and (HDMAP-NDI)2(HPW12O40)(NMP)7 (3), focusing on the impact of anion-pi-pi interactions on their photochromic and RTP properties. The results indicate that hybrid 1 exhibits the fastest photoresponse and highest RTP quantum yield, primarily driven by anion-pi interactions. Hybrid 2, which involves anion-pi-pi interactions, shows slower photochromism and lower RTP yield due to exciton localization and nonradiative decay paths resulting from pi-pi stacking. Hybrid 3, characterized by excessively strong interactions, is unstable and nonemissive. This study provides valuable insights into the role of anion-pi-pi interactions in hybrid materials and offers a framework for designing advanced photoresponsive materials with tunable properties for diverse applications.
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| GB/T 7714 | Di, Yi-Ming , Song, Yu-Ping , Zhang, Shu-Quan et al. Anion-π(-π) Interactions in Donor-Acceptor Hybrid Materials to Control Photochromism and Room-Temperature Phosphorescence [J]. | INORGANIC CHEMISTRY , 2025 , 64 (12) : 6183-6191 . |
| MLA | Di, Yi-Ming et al. "Anion-π(-π) Interactions in Donor-Acceptor Hybrid Materials to Control Photochromism and Room-Temperature Phosphorescence" . | INORGANIC CHEMISTRY 64 . 12 (2025) : 6183-6191 . |
| APA | Di, Yi-Ming , Song, Yu-Ping , Zhang, Shu-Quan , Lin, Mei-Jin . Anion-π(-π) Interactions in Donor-Acceptor Hybrid Materials to Control Photochromism and Room-Temperature Phosphorescence . | INORGANIC CHEMISTRY , 2025 , 64 (12) , 6183-6191 . |
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将嫁接理论引入区域产教融合培养模式的研究,分析单一地区产教融合模式中区域、产业、高校的特质以及三者之间的交互作用.追踪观察福州大学材料学科产教融合模式培养实例,结果表明:产教融合模式对企业增效、科研成果产出、创新人才培养起到了促进作用.产教融合团队作为串联线索,间接推动区域内多类资源良性循环.但此模式还需解决创新赛道开辟、人文教育补充等问题,以便进一步完善区域创新人才产教融合培养模式.
Keyword ：
产教融合 产教融合 区域创新 区域创新 嫁接理论 嫁接理论
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| GB/T 7714 | 梁滢 , 林梅金 , 黄艳 . 区域创新人才产教融合培养模式探索:嫁接理论视角 [J]. | 中国轻工教育 , 2025 , 28 (1) : 19-27 . |
| MLA | 梁滢 et al. "区域创新人才产教融合培养模式探索:嫁接理论视角" . | 中国轻工教育 28 . 1 (2025) : 19-27 . |
| APA | 梁滢 , 林梅金 , 黄艳 . 区域创新人才产教融合培养模式探索:嫁接理论视角 . | 中国轻工教育 , 2025 , 28 (1) , 19-27 . |
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Lanthanide-based metal-organic framework (Ln-MOF) scintillators are promising for X-ray imaging owing to their structural tunability and high X-ray attenuation. However, achieving efficient triplet-sensitized scintillation remains challenging due to the inefficient energy transfer between organic ligand triplets and lanthanide centers, leading to weak radioluminescence and limited imaging resolution. Herein, we propose a dual-antenna ligand strategy by synergizing 4,4 '-oxybis (benzoic acid) (Oba) and phenanthroline derivatives (1,10-phenanthroline = Phen; or Bathophenanthroline = Bphen) with Eu3+ ions, constructing ultrabright Eu-O-Phen and Eu-O-Bphen scintillators. Notably, Eu-O-Bphen demonstrated a record relative light yield of 60331 +/- 28 photons MeV-1, outperforming Eu-O-Phen by 71%. This superior scintillation performance originates from an 86.3 +/- 0.19% photoluminescence quantum yield, attributed to enhanced ligand-to-metal energy transfer efficiency and the suppression of pi-pi stacking among organic chromophore ligands. Besides, the fabrication of flexible Eu-O-Bphen films achieves a spatial resolution of 37.0 lp mm-1 in static imaging and enables real-time dynamic X-ray imaging at 60 fps (2 K). Additionally, it exhibited exceptional water stability, with negligible performance degradation in water for over 100 days, allowing clear underwater visualization of circuit boards under X-ray irradiation. It provides a promising strategy for developing high-performance water-stable scintillators via ligand engineering.
Keyword ：
Dual-antenna ligands Dual-antenna ligands Dynamic X-ray imaging Dynamic X-ray imaging Metal-organic frameworks Metal-organic frameworks Scintillators Scintillators Water-stable Water-stable
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| GB/T 7714 | Chen, Hongming , Yang, Xi , Ye, Yuanji et al. Ultrabright and Water-Stable Eu(III)-Based MOF Scintillators Sensitized by Dual-Antenna Ligands for Real-Time and Underwater X-Ray Imaging [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
| MLA | Chen, Hongming et al. "Ultrabright and Water-Stable Eu(III)-Based MOF Scintillators Sensitized by Dual-Antenna Ligands for Real-Time and Underwater X-Ray Imaging" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2025) . |
| APA | Chen, Hongming , Yang, Xi , Ye, Yuanji , Hong, Hongyang , Wei, Qingsong , Zhu, Yanan et al. Ultrabright and Water-Stable Eu(III)-Based MOF Scintillators Sensitized by Dual-Antenna Ligands for Real-Time and Underwater X-Ray Imaging . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
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Harnessing supramolecular interactions to regulate the structure and performance of functional materials is a key challenge in materials chemistry. Herein, the study utilizes 18-crown-6 (18C6) ether-assisted alkali-metal (Na, K, Cs) copper(I) iodide supramolecular assemblies to precisely regulate the material structures. This approach facilitated the transition from 1D mono-royal crown coordination (18C6@KCuI2, CKCI) to 0D di-royal crown ((18C6)(2)@Na-2(H2O)(3)Cu4I6, CNCI) and tri-royal crown ((18C6)(3)@Cs2Cu2I4, CCCI) structures. Interestingly, the CCCI single-crystal exhibits outstanding scintillation properties, with a high relative light yield of 71 000 photons MeV-1 and an ultralow detection limit of 39.3 nGy s(-1), which can be attributed to the synergistic effects of 18C6 and copper-iodide clusters. It stabilizes the self-trapped exciton state, enhances exciton localization, and reduces non-radiative losses, thus resulting in a large Stokes shift of 193 nm and near-unity photoluminescence quantum yield of 99.4%. Additionally, 18C6 can promote crystal nucleation and growth, making it easy to prepare centimeter-scale transparent single crystals with >80% transmittance, such as CCCI single crystal can achieve an ultrahigh-resolution X-ray imaging of 26.3 lp mm(-1). It demonstrates that the structure and performance of halide scintillators can be regulated through supramolecular interactions, which provides a new approach for developing high-performance scintillator materials.
Keyword ：
18-crown-6 18-crown-6 copper(I) iodide copper(I) iodide self-trapped exciton state self-trapped exciton state supramolecular scintillators supramolecular scintillators X-ray imaging X-ray imaging
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| GB/T 7714 | Ye, Yuanji , Di, Yiming , Zhou, Jiahao et al. Crown Ether-Assisted Alkali-Metal Copper(I) Iodide Supramolecular Scintillators with Near-Unity Emission for Ultrahigh-Resolution X-Ray Imaging [J]. | ADVANCED FUNCTIONAL MATERIALS , 2025 . |
| MLA | Ye, Yuanji et al. "Crown Ether-Assisted Alkali-Metal Copper(I) Iodide Supramolecular Scintillators with Near-Unity Emission for Ultrahigh-Resolution X-Ray Imaging" . | ADVANCED FUNCTIONAL MATERIALS (2025) . |
| APA | Ye, Yuanji , Di, Yiming , Zhou, Jiahao , Qiu, Qiangwen , Chen, Yuhua , Zhong, Shanyuan et al. Crown Ether-Assisted Alkali-Metal Copper(I) Iodide Supramolecular Scintillators with Near-Unity Emission for Ultrahigh-Resolution X-Ray Imaging . | ADVANCED FUNCTIONAL MATERIALS , 2025 . |
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Donor-acceptor crystalline hybrid materials are a new type of photoactive hybrid complex composed of two semiconductor components at the molecular level. Naphthalenediimide (NDI) and perylenediimide (PDI) based donor-acceptor crystalline hybrid materials have garnered significant interest in recent years owing to the structural diversity of the inorganic semiconductors and excellent redox activity in the NDI/PDI, which can effectively achieve long-lived charge separation and transfer under irradiation. In this review, we summarize recent research progress in the construction of NDI/PDI-based crystalline hybrid materials using POMs, metal halides, and transition-metal ions, and their applications in photochromism, photo-controllable fluorescence/ phosphorescence, photocatalytic organic transformations, and photothermal conversion, and as antibacterials, to provide useful guidance for the design, preparation and application of these materials in the future.
Keyword ：
Donor-acceptor Donor-acceptor Hybrid material Hybrid material NDI NDI PDI PDI POMs POMs
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| GB/T 7714 | Liu, Zhengfen , Li, Xiaobo , Dai, Weijun et al. Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications [J]. | COORDINATION CHEMISTRY REVIEWS , 2025 , 526 . |
| MLA | Liu, Zhengfen et al. "Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications" . | COORDINATION CHEMISTRY REVIEWS 526 (2025) . |
| APA | Liu, Zhengfen , Li, Xiaobo , Dai, Weijun , Liu, Jian-Jun , Lin, Mei-Jin . Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications . | COORDINATION CHEMISTRY REVIEWS , 2025 , 526 . |
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Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a widely used anode interlayer (AIL) in organic solar cells (OSCs). However, the intrinsic acidity and hygroscopic nature of PSS ions in PEDOT:PSS have been proven to cause electrode corrosion and deteriorate device performance. Herein, a straightforward method is reported to enhance the water resistance of PEDOT:PSS by incorporating tris[bis(methoxymethyl)amino]-1,3,5-triazine (HM) as a cross-linker. The cross-linking reaction between PSS and HM neutralizes the acidity of PEDOT:PSS and forms a stable, hydrophobic network. Additionally, the aggregation morphology of PEDOT:PSS was regulated by HM, improving the conductivity and work function, thereby resulting in enhanced hole extraction and transport ability. Devices incorporating PEDOT:PSS-HM demonstrated improved power conversion efficiency (PCE) of 19.03% compared to 17.88% for those using standard PEDOT:PSS. The neutral pH and water-resistant nature of PEDOT:PSS-HM effectively improved the long-term stability of OSCs with a T80 of over 400 h under continuous illumination. Moreover, after aging the PEDOT: PSS-HM film for 216 h at 80% relative humidity and 40 degrees C, it can be still used as AIL to fabricate efficient OSC devices. This work presents a simple and effective approach to preparing a non-corrosive and stable PEDOT derivative, offering valuable insights for the development of high-performance AIL materials.
Keyword ：
anode interlayer anode interlayer cross-linking cross-linking organic solar cells organic solar cells PEDOT:PSS PEDOT:PSS water-resistant water-resistant
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| GB/T 7714 | Shan, Xin , Fang, Minghai , Wu, Liang et al. Enhanced water resistance of PEDOT:PSS through crosslinking agent incorporation for efficient and stable organic solar cells [J]. | SCIENCE CHINA-MATERIALS , 2025 , 68 (5) : 1452-1461 . |
| MLA | Shan, Xin et al. "Enhanced water resistance of PEDOT:PSS through crosslinking agent incorporation for efficient and stable organic solar cells" . | SCIENCE CHINA-MATERIALS 68 . 5 (2025) : 1452-1461 . |
| APA | Shan, Xin , Fang, Minghai , Wu, Liang , Rong, Hongchen , Liao, Qing , Qian, Deping et al. Enhanced water resistance of PEDOT:PSS through crosslinking agent incorporation for efficient and stable organic solar cells . | SCIENCE CHINA-MATERIALS , 2025 , 68 (5) , 1452-1461 . |
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Crystalline donor-acceptor (D-A) hybrid materials show a significant potential for photocatalytic applications, but achieving broad light absorption and high photocatalytic efficiency remains a challenge. To address this issue, herein, heteropoly blues, as electron donors, and N,N '-bis(N,N-dimethylaminoethyl)-1,4,5,8-naphthalenediimide (NDIDMA), as electron acceptors, have been introduced to these D-A hybrid materials to enhance their light-harvesting and photocatalytic capabilities. Consequently, heteropoly blue/naphthalenediimide D-A hybrid materials H2NDIDMA[H5PMo8 VIMo4 VO40]2DMF (1) have been synthesized. For comparison, the isostructural fully oxidized polyoxometalate-containing counterpart, H2NDIDMAHPW12O402DMF (2), has also been prepared. As expected, hybrid 1 exhibited a broad light absorption range (300-2500 nm) and demonstrated superior photocatalytic decontamination abilities against mustard gas simulants under full-spectrum and near-infrared (NIR) light irradiation compared to hybrid 2. Remarkably, the heteropoly blues in hybrid 1 demonstrated high stability under catalytic conditions and in ambient environments. Additionally, these stable hybrids exhibited excellent recyclability without a loss of activity after five cycles.
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| GB/T 7714 | Song, Yu-Ping , Di, Yi-Ming , Zhang, Shu-Quan et al. Panchromatic Donor-Acceptor Hybrid Materials for Near-Infrared-Activatable Photocatalytic Detoxification of Mustard Gas Simulants [J]. | INORGANIC CHEMISTRY , 2025 , 64 (18) : 9277-9286 . |
| MLA | Song, Yu-Ping et al. "Panchromatic Donor-Acceptor Hybrid Materials for Near-Infrared-Activatable Photocatalytic Detoxification of Mustard Gas Simulants" . | INORGANIC CHEMISTRY 64 . 18 (2025) : 9277-9286 . |
| APA | Song, Yu-Ping , Di, Yi-Ming , Zhang, Shu-Quan , Lin, Mei-Jin . Panchromatic Donor-Acceptor Hybrid Materials for Near-Infrared-Activatable Photocatalytic Detoxification of Mustard Gas Simulants . | INORGANIC CHEMISTRY , 2025 , 64 (18) , 9277-9286 . |
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Metal-free molecular perovskites have shown great potential for X-ray detection due to their tunable chemical structures, low toxicity, and excellent photophysical properties. However, their limited X-ray absorption and environmental instability restrict their practical application. In this study, cesium-based molecular perovskites (MDABCO-CsX3, X = Cl, Br, I) are developed by introducing Cs+ at the B-site to enhance X-ray absorption while retaining low toxicity. The effects of halide modulation on the physical properties and device performance are systematically investigated. Among the variants, MDABCO-CsBr3 exhibited superior environmental stability, attributed to the optimal ionic radius and high chemical stability of Br-. This stability is further enhanced by a higher tolerance factor, which promotes a stable 3D cubic structure and suppresses ion migration within the crystal. Consequently, MDABCO-CsBr3-based X-ray detectors demonstrated reduced ionic migration, minimal dark current drift, and a stable current response under X-ray exposure, achieving a high sensitivity of 4124 mu C Gy-1 cm-2 and a low detection limit of 0.45 mu Gy s-1. Moreover, the devices exhibit excellent thermal stability, operating effectively at temperatures up to 130 degrees C. These results highlight MDABCO-CsBr3 as a promising candidate for stable and efficient X-ray detection, expanding the applicability of molecular perovskites in advanced radiation detection technologies.
Keyword ：
cesium-substituted cesium-substituted environmental stability environmental stability molecular perovskite molecular perovskite X-ray detection X-ray detection
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| GB/T 7714 | Wu, Liang , Wei, Qingsong , Di, Yiming et al. Cesium-Based Molecular Perovskites With Superior Stability for High-Performance X-Ray Detection [J]. | SMALL , 2025 , 21 (10) . |
| MLA | Wu, Liang et al. "Cesium-Based Molecular Perovskites With Superior Stability for High-Performance X-Ray Detection" . | SMALL 21 . 10 (2025) . |
| APA | Wu, Liang , Wei, Qingsong , Di, Yiming , Chen, Fuhai , Qiu, Qiangwen , Shan, Xin et al. Cesium-Based Molecular Perovskites With Superior Stability for High-Performance X-Ray Detection . | SMALL , 2025 , 21 (10) . |
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Organic thermally activated delayed fluorescent (TADF) scintillators hold promising potential for applications in medical radiography and security detection, but the poor X-ray absorption ability and inferior radioluminescence (RL) hampered their progression. Herein, the study has pioneered the development of high-performance TADF Ag(I)-based scintillators from M2X2(dppb)2 (M = Ag, Cu; X = Cl, Br, I) complexes with 1,2-Bis(diphenylphosphino)benzene (dppb) ligand. In comparison with Cu(I) complexes, the Ag(I) series generally exhibited superior scintillation performance. Notably, Ag2Cl2(dppb)2 (Ag1) stands out with exceptionally high RL intensity (approximate to 125% higher than that of CsI:Tl) and a low detection limit of 59.8 nGy s-1. The outstanding scintillation performance of Ag1 is primarily attributed to the synergistic effect of the high exciton utilization efficiency origin from a small singlet-triplet energy gap, enhanced X-ray absorption capacity by heavy atoms, and the high photoluminescence quantum yield (76.47% in ambient atmosphere). By fabricating a flexible film constructed with Ag1 submicron crystalline powders, a high spatial resolution of 25.0 lp mm-1 for X-ray imaging is obtained. It offers new opportunities for utilizing TADF metal-organic complexes for highly efficient X-ray scintillation and imaging. Scintillators with good radioluminescence performance are prepared by combining the TADF mechanism to optimize the utilization of triplet excitons, coupled with increased X-ray absorption through heavy atoms, verifying the advantages of Ag(I)-halide complexes on radioluminescence. Besides, the influence of halogens on photoluminescence and radioluminescence are investigated. As a practical application, Ag2Cl2(dppb)2 is applied to fabricate flexible scintillator films, achieving high-resolution imaging of 25 lp mm-1. image
Keyword ：
scintillators scintillators silver-based complexes silver-based complexes thermally activated delayed fluorescence thermally activated delayed fluorescence X-ray imaging X-ray imaging
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| GB/T 7714 | Yuan, Siqi , Zhang, Guozhen , Chen, Fuhai et al. Thermally Activated Delayed Fluorescent Ag(I) Complexes for Highly Efficient Scintillation and High-Resolution X-Ray Imaging [J]. | ADVANCED FUNCTIONAL MATERIALS , 2024 , 34 (33) . |
| MLA | Yuan, Siqi et al. "Thermally Activated Delayed Fluorescent Ag(I) Complexes for Highly Efficient Scintillation and High-Resolution X-Ray Imaging" . | ADVANCED FUNCTIONAL MATERIALS 34 . 33 (2024) . |
| APA | Yuan, Siqi , Zhang, Guozhen , Chen, Fuhai , Chen, Jingru , Zhang, Yang , Di, Yiming et al. Thermally Activated Delayed Fluorescent Ag(I) Complexes for Highly Efficient Scintillation and High-Resolution X-Ray Imaging . | ADVANCED FUNCTIONAL MATERIALS , 2024 , 34 (33) . |
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Phosphates are ideal candidates in the search for deep ultraviolet (DUV) nonlinear optical (NLO) materials due to their wide DUV transmission. However, the small optical anisotropy of the highly symmetric [PO4](3-) tetrahedron hinders phase matching (PM) in the DUV wavelength range. In this work, the polar tetrahedron [PO2(NHCONH2)(2)](-), which combines the pi-conjugated urea unit and the non-pi-conjugated [PO4](3-) unit via covalent bonds, is proposed as a new DUV NLO-active unit. [PO2(NHCONH2)(2)](-) tetrahedron exhibits greatly improved polarizability, anisotropy, and hyperpolarizability while maintaining a large highest occupied molecular orbital-lowest unoccupied molecular orbital gap. Accordingly, two DUV transparent alkali metal N, N-bis(aminocarbonyl)-phosphorodiamidates [A[PO2(NHCONH2)(2)] (A = K, Rb)] are screened out, and their nonlinear properties are systematically evaluated by first-principles methods. The results show that K[PO2(NHCONH2)(2)] (KPOU) achieves significant enhancements in multiple properties compared to the existing phosphate DUV NLO materials, including a strong SHG effect (3.44 x KDP) and the largest birefringence (0.088@532 nm) for DUV PM. Moreover, the shortest PM wavelength (lambda(PM)) of KPOU is 196 nm, making it a promising DUV NLO candidate for practical applications. This work proposes an excellent NLO-active unit and offers a new direction for exploring novel high-performance DUV NLO materials.
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| GB/T 7714 | Chen, Fuhai , Mo, Fuxiang , Chen, Hongming et al. KPO2(NHCONH2)2: A Promising Deep-Ultraviolet Nonlinear Optical Phosphate Containing Polar [PO2(NHCONH2)2]- Tetrahedra [J]. | CHEMISTRY OF MATERIALS , 2024 , 36 (6) : 2985-2992 . |
| MLA | Chen, Fuhai et al. "KPO2(NHCONH2)2: A Promising Deep-Ultraviolet Nonlinear Optical Phosphate Containing Polar [PO2(NHCONH2)2]- Tetrahedra" . | CHEMISTRY OF MATERIALS 36 . 6 (2024) : 2985-2992 . |
| APA | Chen, Fuhai , Mo, Fuxiang , Chen, Hongming , Lin, Mei-Jin , Chen, Yong . KPO2(NHCONH2)2: A Promising Deep-Ultraviolet Nonlinear Optical Phosphate Containing Polar [PO2(NHCONH2)2]- Tetrahedra . | CHEMISTRY OF MATERIALS , 2024 , 36 (6) , 2985-2992 . |
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