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学者姓名：张宏伟
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Abstract ：
Electrocatalytic nitrate reduction reaction (NO3RR) has been capturing immense interest in the industrial application of ammonia synthesis, and it involves complex reaction routes accompanied by multi-electron transfer, thus causing a challenge to achieve high efficiency for catalysts. Herein, we customized the Cu-O-Ti-Ov (oxygen vacancy) structure on the Cu/TiO2 catalyst, identified through density functional theory (DFT) calculations as the synergic active site for NO3RR. It is found that Cu-O-Ti-Ov site facilitates the adsorption/association of NOx– and promotes the hydrogenation of NO3– to NH3 via adsorbed *H species. This effectively suppresses the competing hydrogen evolution reaction (HER) and exhibits a lower reaction energy barrier for NO3RR, with the reaction pathways: NO3* → NO2* → HONO* → NO* → *NOH → *N → *NH → *NH2 → *NH3 → NH3. The optimized Cu/TiO2 catalyst with rich Cu-O-Ti-Ov sites achieves an NH3 yield rate of 3046.5 μg h–1 mgcat–1 at –1.0 V vs. RHE, outperforming most of the reported activities. Furthermore, the construction of Cu-O-Ti-Ov sites significantly mitigates the leaching of Cu species, enhancing the stability of the Cu/TiO2 catalyst. Additionally, a mechanistic study, using in situ characterizations and various comparative experiments, further confirms the strong synergy between Cu, Ti, and Ov sites, which is consistent with previous DFT calculations. This study provides a new strategy for designing efficient and stable electrocatalysts in the field of ammonia synthesis. © 2024 Dalian Institute of Chemical Physics, the Chinese Academy of Sciences
Keyword ：
Ammonia Ammonia Catalyst activity Catalyst activity Copper compounds Copper compounds Density functional theory Density functional theory Electrocatalysts Electrocatalysts Kinetic theory Kinetic theory Nitrates Nitrates Nitrogen oxides Nitrogen oxides Selective catalytic reduction Selective catalytic reduction Titanium compounds Titanium compounds
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| GB/T 7714 | Nie, Yifei , Yan, Hongping , Lu, Suwei et al. Theory-guided construction of Cu-O-Ti-Ov active sites on Cu/TiO2 catalysts for efficient electrocatalytic nitrate reduction [J]. | Chinese Journal of Catalysis , 2024 , 59 : 293-302 . |
| MLA | Nie, Yifei et al. "Theory-guided construction of Cu-O-Ti-Ov active sites on Cu/TiO2 catalysts for efficient electrocatalytic nitrate reduction" . | Chinese Journal of Catalysis 59 (2024) : 293-302 . |
| APA | Nie, Yifei , Yan, Hongping , Lu, Suwei , Zhang, Hongwei , Qi, Tingting , Liang, Shijing et al. Theory-guided construction of Cu-O-Ti-Ov active sites on Cu/TiO2 catalysts for efficient electrocatalytic nitrate reduction . | Chinese Journal of Catalysis , 2024 , 59 , 293-302 . |
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Carbon adsorbents have been widely used to remove indoor volatile organic compounds (VOCs), however, the proliferation of bacteria on the carbon adsorbents may deteriorate the indoor air quality and thus pose a serious threat to human health. Herein, we report the synthesis of antibacterial porous carbon spheres (carbonized aminophenol-formaldehyde resin, CAF) with well-dispersed Cu species via an in situ incorporation of Cu2+ during the polymerization of 3-aminophenol-formaldehyde resin followed by a thermal carbonization and reduction process. Compared with CAF, the Cu/CAF-x nanocomposites with Cu loading show a much higher specific surface area (>700 m2 g−1 vs. 569 m2 g−1 for CAF). In addition, the pore size of Cu/CAF-x is ranging from 0.7 to 1.68 nm, which is exactly conducive to adsorb the toluene molecules. As a result, the toluene adsorption capacity is improved from 123.50 mg g−1 for CAF to >170 mg g−1 for Cu/CAF-x. More importantly, such adsorbents possess excellent antibacterial performance, the Cu/CAF-10 (10 wt% of Cu loading) with a concentration of 50 μg mL−1 can completely kill the E. coli within 30 min. Our work paves the way to the development of bifunctional adsorbents with both efficient VOCs adsorption and excellent antibacterial performance. © 2023
Keyword ：
Adsorption Adsorption Air quality Air quality Carbonization Carbonization Copper compounds Copper compounds Escherichia coli Escherichia coli Formaldehyde Formaldehyde Health risks Health risks Indoor air pollution Indoor air pollution Pore size Pore size Porous materials Porous materials Toluene Toluene Volatile organic compounds Volatile organic compounds
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| GB/T 7714 | Zhang, Hongwei , Wu, Guanghui , Liu, Qunhong et al. Bifunctional Cu-incorporated carbon nanospheres via in-situ complexation strategy as efficient toluene adsorbents and antibacterial agents [J]. | Chemosphere , 2024 , 349 . |
| MLA | Zhang, Hongwei et al. "Bifunctional Cu-incorporated carbon nanospheres via in-situ complexation strategy as efficient toluene adsorbents and antibacterial agents" . | Chemosphere 349 (2024) . |
| APA | Zhang, Hongwei , Wu, Guanghui , Liu, Qunhong , Liu, Zhichen , Yang, Qin , Cui, Qingyan et al. Bifunctional Cu-incorporated carbon nanospheres via in-situ complexation strategy as efficient toluene adsorbents and antibacterial agents . | Chemosphere , 2024 , 349 . |
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面向国家绿色低碳战略目标,变革化石资源合成氨技术路线变得尤为迫切,开发可再生能源制"绿氨"将成为合成氨领域未来的重要发展方向.将工业废水中的硝酸根(NO3-)电催化还原为氨(NO3RR),既可有效回收氨,又能消除硝酸根污染影响.然而,NO3RR涉及缓慢的八电子转移过程,含有多种反应中间体,其反应机理复杂不明.此外,水系电解液中存在的析氢竞争反应也为高效NO3RR催化剂的开发设计带来了巨大的挑战.为突破高效催化剂的发展瓶颈,本文通过理论模拟,在低成本的催化剂上设计了高效的NO3RR催化活性位点,并利用简单的制备策略合成了目标催化剂.同时,结合原位表征技术,阐明了 NO3RR的反应路径及催化机理. 本文通过密度泛函理论(DFT)计算发现,Cu/TiO2催化剂上的Cu-O-Ti-Ov结构具有较好的NO3-还原活性,该结构不仅能够促进反应中间体NOx-的吸附和活化,还能有效抑制竞争析氢反应,从而降低NO3RR的反应能垒.在该结构上,NO3RR的反应路径为:NO3*→NO2*→ HONO*→ NO*→*NOH →*N →*NH →*NH2 →*NH3→NH3.基于理论计算结果,分别采用浸渍法和尿素水解法制备了系列富含Cu-O-Ti-Ov结构的Cu/TiO2催化剂.氮气等温吸附-脱附曲线、拉曼光谱(Raman)、电子顺磁共振波谱、X射线光电子能谱(XPS)和傅立叶红外光谱等结果发现,相比于采用浸渍法制备的系列Cu/TiO2催化剂,采用尿素水解法制备的Cu/TiO2(CT-U)催化剂具有更大的比表面积以及更多的Cu-O-Ti-Ov位点,说明尿素水解法可提高Cu颗粒在TiO2载体表面的分散度,增强Cu颗粒与TiO2载体之间的相互作用,提高Cu/TiO2催化剂表面的Cu-O-Ti-Ov位点含量.将以上制备出的催化剂应用于催化NO3RR中,结果表明,在-1.0 V vs.RHE还原电位下,CT-U催化剂上氨产率可达3046.5μg h-1 mgcat-1,高于大多数文献报道结果.循环稳定性测试结果表明,在Cu/TiO2催化剂上构建Cu-O-Ti-Ov位点还能显著抑制电催化反应过程中Cu物种从Cu/TiO2催化剂上溶出,从而显著增强催化剂的稳定性.此外,设计制备了不含氧空位的Cu/TiO2,TiO2-x,Cu,Cu2O以及CuO催化剂,并将其用于催化NO3RR.结果发现,上述催化剂上的氨产率皆明显低于CT-U催化剂,说明Cu,Ti以及Ov构成的Cu-O-Ti-Ov结构具有较好的催化协同作用,从而显著提升了NO3RR反应活性.最后,通过原位Raman及原位XPS表征检测反应中间体,验证了由DFT模拟出的NO3RR反应路径. 综上,通过在Cu/TiO2催化剂上理论指导构建Cu-O-Ti-Ov活性位点,实现了NO3RR性能的有效提升.Cu-O-Ti-Ov结构中的多位点协同作用不仅促进了 NOx-的吸附和活化,而且抑制了电催化过程中Cu物种从催化剂上的溶出,从而提高了催化剂的稳定性.本研究为设计高效稳定的NO3RR催化剂提供了新思路.
Keyword ：
Cu-O-Ti-Ov位点 Cu-O-Ti-Ov位点 Cu/TiO2催化剂 Cu/TiO2催化剂 协同催化 协同催化 合成氨 合成氨 电催化硝酸盐还原 电催化硝酸盐还原
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| GB/T 7714 | 聂翼飞 , 颜红萍 , 鹿苏微 et al. 理论指导构建Cu-O-Ti-Ov活性位点及其高效电催化还原硝酸根研究 [J]. | 催化学报 , 2024 , 59 (4) : 293-302 . |
| MLA | 聂翼飞 et al. "理论指导构建Cu-O-Ti-Ov活性位点及其高效电催化还原硝酸根研究" . | 催化学报 59 . 4 (2024) : 293-302 . |
| APA | 聂翼飞 , 颜红萍 , 鹿苏微 , 张宏伟 , 齐婷婷 , 梁诗景 et al. 理论指导构建Cu-O-Ti-Ov活性位点及其高效电催化还原硝酸根研究 . | 催化学报 , 2024 , 59 (4) , 293-302 . |
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Water electrolysis for hydrogen production holds great promise as an energy conversion technology. The electrolysis process contains two necessary electrocatalytic reactions, one is the hydrogen evolution reaction (HER) at the cathode, and the other is the oxygen evolution reaction (OER) at the anode. In general, the kinetics of OER is much slower than that of HER, dominating the overall of performance electrolysis. As identified, the slow kinetics of catalytic OER is mainly resulted from multiple electron transfer steps, and the catalysts often undergo compositional, structural, and electronic changes during operation, leading to complicated dynamic reaction mechanisms which have not been fully understood. Obviously, this challenge presents formidable obstacles to the development of highly efficient OER electrocatalysts. To address the issue, it is crucial to unravel the origins of intrinsic OER activity and stability and elucidate the catalytic mechanisms across diverse catalyst materials. In this context, in-situ/operando characterization techniques would play a pivotal role in understanding the catalytic reaction mechanisms by enabling real-time monitoring of catalyst structures under operational conditions. These techniques can facilitate the identification of active sites for OER and provide essential insights into the types and quantities of key reaction intermediates. This comprehensive review explores various catalyst design and synthesis strategies aimed at enhancing the intrinsic OER activity and stability of catalysts and examines the application of advanced in-situ/operando techniques for probing catalyst mechanisms during the OER process. Furthermore, the imperative need for developing innovative in-situ/operando techniques, theoretical artificial intelligence and machine learning and conducting theoretical research to better understand catalyst structural evolution under conditions closely resembling practical OER working states is also deeply discussed. Those efforts should be able to lay the foundation for the improved fabrication of practical OER catalysts.
Keyword ：
Electrocatalysts Electrocatalysts In-situ techniques In-situ techniques Oxygen evolution reaction Oxygen evolution reaction Reaction mechanism Reaction mechanism
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| GB/T 7714 | Hu, Cejun , Hu, Yanfang , Zhang, Bowen et al. Advanced Catalyst Design Strategies and In-Situ Characterization Techniques for Enhancing Electrocatalytic Activity and Stability of Oxygen Evolution Reaction [J]. | ELECTROCHEMICAL ENERGY REVIEWS , 2024 , 7 (1) . |
| MLA | Hu, Cejun et al. "Advanced Catalyst Design Strategies and In-Situ Characterization Techniques for Enhancing Electrocatalytic Activity and Stability of Oxygen Evolution Reaction" . | ELECTROCHEMICAL ENERGY REVIEWS 7 . 1 (2024) . |
| APA | Hu, Cejun , Hu, Yanfang , Zhang, Bowen , Zhang, Hongwei , Bao, Xiaojun , Zhang, Jiujun et al. Advanced Catalyst Design Strategies and In-Situ Characterization Techniques for Enhancing Electrocatalytic Activity and Stability of Oxygen Evolution Reaction . | ELECTROCHEMICAL ENERGY REVIEWS , 2024 , 7 (1) . |
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There is a particular demand to explore low-volatility and structurally tunable absorbents for efficiency, selectivity and reversibility in capturing H2S. For the first time, the performance of deep eutectic solvents (DESs) composed of 1-ethyl-3-methylimidazolium chloride ([Emim]Cl) and acetamide (AA) were examined as physical absorbents for H2S capture. The physical properties of [Emim]Cl-AA DESs, and solubilities of both H2S and CO2 in them were measured. Relevant experimental results demonstrated that the solubilities of H2S in [Emim]Cl-AA DESs (1.1 mol/kg at 298.2 K and 1.023 bar) significantly exceed those of CO2 (0.040 mol/kg at 298.2 K and 1.027 bar). [Emim]Cl-AA DESs exhibit higher H2S solubilities and superior ideal H2S to CO2 selectivities (e.g., the ideal H2S/CO2 selectivity of [Emim]Cl-AA (1:0.5) is 28.5 at 298.2 K) than those physical absorbents ever reported. The recyclability of [Emim]Cl-AA DESs for H2S selective capture was also evaluated, which was found to be very stable in ten continuous absorption and regeneration cycle experiments. The mechanism of H2S capture by [Emim]Cl-AA DESs was finally illustrated at the molecular level with the support of theoretical calculations. © 2024 Elsevier B.V.
Keyword ：
Absorption selectivity Absorption selectivity Deep eutectic solvent Deep eutectic solvent H2S capture H2S capture Physical solvent Physical solvent Theoretical calculation Theoretical calculation
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| GB/T 7714 | Zheng, L. , Li, X. , Cao, Y. et al. Efficient, selective and reversible capture of hydrogen sulfide by [Emim]Cl-Acetamide deep eutectic solvents [J]. | Journal of Molecular Liquids , 2024 , 413 . |
| MLA | Zheng, L. et al. "Efficient, selective and reversible capture of hydrogen sulfide by [Emim]Cl-Acetamide deep eutectic solvents" . | Journal of Molecular Liquids 413 (2024) . |
| APA | Zheng, L. , Li, X. , Cao, Y. , Ma, Y. , Zhang, H. , Cai, Z. et al. Efficient, selective and reversible capture of hydrogen sulfide by [Emim]Cl-Acetamide deep eutectic solvents . | Journal of Molecular Liquids , 2024 , 413 . |
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In recent years, studies focusing on the conversion of renewable lignin-derived oxygenates (LDOs) have emphasized their potential as alternatives to fossil-based products. However, LDOs, existing as complex aromatic mixtures with diverse oxygen-containing functional groups, pose a challenge as they cannot be easily separated via distillation for direct utilization. A promising solution to this challenge lies in the efficient removal of oxygen-containing functional groups from LDOs through hydrodeoxygenation (HDO), aiming to yield biomass products with singular components. However, the high dissociation energy of the carbon–oxygen bond, coupled with its similarity to the hydrogenation energy of the benzene ring, creates a competition between deoxygenation and benzene ring hydrogenation. Considering hydrogen consumption and lignin properties, the preference is directed towards generating aromatic hydrocarbons rather than saturated components. Thus, the goal is to selectively remove oxygen-containing functional groups while preserving the benzene ring structure. Studies on LDOs conversion have indicated that the design of active components and optimization of reaction conditions play pivotal roles in achieving selective deoxygenation, but a summary of the correlation between these factors and the reaction mechanism is lacking. This review addresses this gap in knowledge by firstly summarizing the various reaction pathways for HDO of LDOs. It explores the impact of catalyst design strategies, including morphology modulation, elemental doping, and surface modification, on the adsorption–desorption dynamics between reactants and catalysts. Secondly, we delve into the application of advanced techniques such as spectroscopic techniques and computational modeling, aiding in uncovering the true active sites in HDO reactions and understanding the interaction of reactive reactants with catalyst surface-interfaces. Additionally, fundamental insights into selective deoxygenation obtained through these techniques are highlighted. Finally, we outline the challenges that lie ahead in the design of highly active and selective HDO catalysts. These challenges include the development of detection tools for reactive species with high activity at low concentrations, the study of reaction medium–catalyst interactions, and the development of theoretical models that more closely approximate real reaction situations. Addressing these challenges will pave the way for the development of efficient and selective HDO catalysts, thus advancing the field of renewable LDOs conversion. © 2024 Institute of Process Engineering, Chinese Academy of Sciences
Keyword ：
Catalyst design Catalyst design Hydrodeoxygenation Hydrodeoxygenation Lignin-derived oxygenates Lignin-derived oxygenates Targeted deoxidation Targeted deoxidation Techniques and theoretical calculation Techniques and theoretical calculation
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| GB/T 7714 | Wu, X. , Zhang, H. , Hu, C. et al. Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques [J]. | Green Energy and Environment , 2024 . |
| MLA | Wu, X. et al. "Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques" . | Green Energy and Environment (2024) . |
| APA | Wu, X. , Zhang, H. , Hu, C. , Bao, X. , Yuan, P. . Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques . | Green Energy and Environment , 2024 . |
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The selective catalytic hydrogenation of styrene-butadiene-styrene block copolymer (SBS) is to selectively hydrogenate the unsaturated C C in polybutadiene segment while maintaining the phenyl group in polystyrene segment intact so as to yield high-valued hydrogenated products SEBS with greatly improved performance. In order to eliminate the diffusion limitation, herein, three-dimensional ordered super-macroporous carbon nitride (3DOM g-C3N4) was successfully synthesized via thermal condensation of cyanamide with colloidal SiO2sub-microspheres as the template. Afterwards, the Pd/3DOM g-C3N4 catalyst was obtained by chemical reduction method and applied for selective catalytic hydrogenation of SBS. The results showed that the Pd/3DOM g-C3N4 catalyst possessed a three-dimensional penetrating structure of super-macroporous-macroporous-mesoporous multistage pore with the small-sized and well-dispersed Pd nanoparticles over it. Such catalyst exhibited excellent hydrogenation activity and selectivity under mild reaction conditions. According to the Fourier transform infrared (FTIR) characterization, the total hydrogenation degree of 1,2-C C and 1,4-C C to SBS was 98%, while the benzene ring was not hydrogenated thus the selectivity to C C was 100%. The excellent catalytic performance is mainly attributed to the unique three-dimensional penetrating structure of super-macroporous-macroporous-mesoporous multistage pore of the support, which can effectively eliminate the macromolecules diffusion limitation in pores, thereby greatly improving the accessibility to the active sites. The strong interaction between Pd and pyridinic N in the g-C3N4support is beneficial to anchoring Pd2+ during impregnation process, and then obtains Pd nanoparticles with small particle size and high dispersion and stability. © 2023 Chemical Industry Press. All rights reserved.
Keyword ：
g-C3N4 g-C3N4 hydrogenation hydrogenation SBS SBS super-macroporous support super-macroporous support supported Pd catalyst supported Pd catalyst
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| GB/T 7714 | Liang, M. , Guo, Y. , Wang, S. et al. Study on preparation of Pd catalyst supported on carbon nitride for the selective hydrogenation of SBS [氮化碳负载钯催化剂的制备及对 SBS 选择性催化加氢性能的研究] [J]. | CIESC Journal , 2023 , 74 (2) : 766-775 . |
| MLA | Liang, M. et al. "Study on preparation of Pd catalyst supported on carbon nitride for the selective hydrogenation of SBS [氮化碳负载钯催化剂的制备及对 SBS 选择性催化加氢性能的研究]" . | CIESC Journal 74 . 2 (2023) : 766-775 . |
| APA | Liang, M. , Guo, Y. , Wang, S. , Zhang, H. , Yuan, P. , Bao, X. . Study on preparation of Pd catalyst supported on carbon nitride for the selective hydrogenation of SBS [氮化碳负载钯催化剂的制备及对 SBS 选择性催化加氢性能的研究] . | CIESC Journal , 2023 , 74 (2) , 766-775 . |
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本发明公开了一种用于木质素解聚的Ni‑Zn负载型催化剂的制备方法和应用，首先采用浸渍法制备活性炭负载Ni‑Zn催化剂的前驱体，然后在氮气气氛中焙烧，利用碳还原法将金属还原，得到活性炭负载Ni‑Zn催化剂材料。将该类催化剂应用于禾本科木质素悬浮床氢解生产高附加值化学品，具有较高的氢解反应活性和液体产物收率，当催化剂/木质素=20%时，总单体产率可达18.25 wt%；当催化剂/木质素=40%，酯类化合物和4‑羟基‑3, 5‑二甲氧基苯乙醛的选择性可分别达到36.43%和16.75%左右。对于拓展木质生物质化学品产业化提供了一条新途径。
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| GB/T 7714 | 崔勍焱 , 颜超 , 王廷海 et al. 一种用于木质素解聚的Ni-Zn负载型催化剂的制备方法和应用 : CN202210249077.7[P]. | 2022-03-15 00:00:00 . |
| MLA | 崔勍焱 et al. "一种用于木质素解聚的Ni-Zn负载型催化剂的制备方法和应用" : CN202210249077.7. | 2022-03-15 00:00:00 . |
| APA | 崔勍焱 , 颜超 , 王廷海 , 袁珮 , 张宏伟 . 一种用于木质素解聚的Ni-Zn负载型催化剂的制备方法和应用 : CN202210249077.7. | 2022-03-15 00:00:00 . |
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本发明公开了一种氧空位调控的负载型钯基催化剂的制备及其在聚苯乙烯加氢中的应用，其是以水热法制备的一维钛酸纳米管，然后在其表面形成氧空位，再利用氧空位中的自由电子原位将钯盐锚定并还原，以制得所述负载型钯基催化剂。本发明所制得的催化剂具有一维结构，活性金属钯位于催化剂外表面，不仅有利于聚苯乙烯与活性金属充分接触，还可解决聚合物分子在常规多孔催化剂中扩散速度慢的问题。此外，氧空位可增强金属‑载体相互作用，有利于提高催化剂的稳定性。将该负载型催化剂应用于聚苯乙烯的加氢反应中，可得到高品质的聚环己烷基乙烯，所得产品加氢度高达100%，因而对聚苯乙烯非均相催化的发展具有重要意义。
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| GB/T 7714 | 张宏伟 , 马聪 , 袁珮 et al. 一种氧空位调控的负载型钯基催化剂的制备及其在聚苯乙烯加氢中的应用 : CN202111326588.6[P]. | 2021-11-10 00:00:00 . |
| MLA | 张宏伟 et al. "一种氧空位调控的负载型钯基催化剂的制备及其在聚苯乙烯加氢中的应用" : CN202111326588.6. | 2021-11-10 00:00:00 . |
| APA | 张宏伟 , 马聪 , 袁珮 , 苟雷 . 一种氧空位调控的负载型钯基催化剂的制备及其在聚苯乙烯加氢中的应用 : CN202111326588.6. | 2021-11-10 00:00:00 . |
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本发明设计制备适用于油脂加氢转化制备生物航空煤油的非贵双金属负载型催化剂，将其应用在棕榈油加氢脱氧、裂化/异构化反应中生产C8～C16烃类范围的生物航空煤油。本发明以镍为主要金属，添加第二过渡金属，以碱液沉淀负载在酸性载体上制备而得的双金属负载型催化材料，金属高度分散在载体表面，大大提高了催化剂加氢脱氧性能，在棕榈油的加氢脱氧、裂化异构化反应中，油脂转化率高达100%，生物航空煤油收率可达60%，并减少碳损失，因而在油脂加氢转化生产生物航空煤油工艺上具有良好的应用前景。
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| GB/T 7714 | 崔勍焱 , 杨卓莹 , 王廷海 et al. 一种双金属负载型催化剂及其制备方法和在棕榈油加氢转化制备生物航空煤油中的应用 : CN202210232029.7[P]. | 2022-03-10 00:00:00 . |
| MLA | 崔勍焱 et al. "一种双金属负载型催化剂及其制备方法和在棕榈油加氢转化制备生物航空煤油中的应用" : CN202210232029.7. | 2022-03-10 00:00:00 . |
| APA | 崔勍焱 , 杨卓莹 , 王廷海 , 袁珮 , 张宏伟 . 一种双金属负载型催化剂及其制备方法和在棕榈油加氢转化制备生物航空煤油中的应用 : CN202210232029.7. | 2022-03-10 00:00:00 . |
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