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学者姓名：马永德
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Abstract ：
High-carbon alcohols are important chemical raw materials and have extensive applications in the fields of chemistry, chemical engineering, and pharmaceuticals. Converting fatty acids or fatty acid methyl esters from waste oil into high-carbon alcohols through hydrogenation has attracted increasing attention. In this study, a series of Cu-ZrO2 catalysts were prepared by a citric acid-assisted sol-gel method. Results reveal that Cu-ZrO2 catalysts prepared by the sol-gel method mainly exist in the form of tetragonal ZrO2with loaded copper species. There is a certain metal-support interaction between metallic Cu and the ZrO2 support, and ZrO2 crystal phase can be retained during the harsh catalytic reaction conditions. X-ray photoelectron spectroscopy results show that Cu0 species are the key active centers. When the Cu0 content is insufficient, the conversion rate of methyl palmitate increases with the increase of Cu0 content. When the Cu0 content is sufficient, Cu+ and Cu0 have a synergistic effect on the hydrogenation reaction. Catalyst dosage, reaction time, reaction temperature and hydrogen pressure were found to have significant effects on the catalytic transformation of methyl palmitate. Increase of reaction temperature can significantly improve the conversion of methyl palmitate. However, excessive temperature can easily induce the dehydration of the generated hexadecanol into by-products such as hexadecane. The conversion of methyl palmitate can be up to 95.1%, and the yield of hexadecanol can reach 91.1% under the conditions of 10% copper loading, 300℃, 6MPa H2 pressure and 2h reaction. © 2025 Chemical Industry Press Co., Ltd.. All rights reserved.
Keyword ：
Acids Acids Hydrogenolysis Hydrogenolysis Metallic compounds Metallic compounds Selenium compounds Selenium compounds
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| GB/T 7714 | Bao, Jie , Yu, Panjie , Ma, Yongde et al. Design of Cu-ZrO2 catalyst and its utilization in hydrogenation of methyl palmitate to fatty alcohols [J]. | Chemical Industry and Engineering Progress , 2025 , 44 (5) : 2997-3008 . |
| MLA | Bao, Jie et al. "Design of Cu-ZrO2 catalyst and its utilization in hydrogenation of methyl palmitate to fatty alcohols" . | Chemical Industry and Engineering Progress 44 . 5 (2025) : 2997-3008 . |
| APA | Bao, Jie , Yu, Panjie , Ma, Yongde , Zhang, Hongwei , Cai, Zhenping , Cao, Yanning et al. Design of Cu-ZrO2 catalyst and its utilization in hydrogenation of methyl palmitate to fatty alcohols . | Chemical Industry and Engineering Progress , 2025 , 44 (5) , 2997-3008 . |
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Developing catalysts enabling reactive separation is a promising strategy to enhance reaction and separation efficiency of esterification processes. Herein, we designed a class of hybrid catalysts with p-toluenesulfonic acid (PTSA) as main catalyst, and hydrogensulfate ILs as support catalyst and extractant. Using the designed catalysts for methyl esterification of long-chain fatty acids, phase splitting can occur, resulting in ester-rich and catalyst-rich phases. Under optimal conditions, the conversion of palmitic acid (PA) gives methyl palmitate (MP) yield of 98.2 % in 3 hat 348.2 K. The catalysts are also applicable for effective conversion of other long-chain fatty acids and can be facilely recycled through liquid-liquid separation without loss of activity. COSMOtherm and Gaussian calculations were performed to rationalize the reactive separation behavior of the designed catalysts. The kinetic and thermodynamic properties of the esterification reaction were also examined using pseudo-homogeneous (PH) model with non-ideality corrections.
Keyword ：
Acidic catalyst Acidic catalyst Biodiesel Biodiesel Esterification Esterification Ionic liquid Ionic liquid Reactive separation Reactive separation
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| GB/T 7714 | Wu, Wenquan , Zhang, Jiayin , Ma, Yongde et al. Ionic liquid-based hybrid acidic catalysts enabling phase splitting and reactive separation for methyl esterification of long-chain fatty acids [J]. | CHEMICAL ENGINEERING SCIENCE , 2025 , 311 . |
| MLA | Wu, Wenquan et al. "Ionic liquid-based hybrid acidic catalysts enabling phase splitting and reactive separation for methyl esterification of long-chain fatty acids" . | CHEMICAL ENGINEERING SCIENCE 311 (2025) . |
| APA | Wu, Wenquan , Zhang, Jiayin , Ma, Yongde , Zhang, Hongwei , Cai, Zhenping , Cao, Yanning et al. Ionic liquid-based hybrid acidic catalysts enabling phase splitting and reactive separation for methyl esterification of long-chain fatty acids . | CHEMICAL ENGINEERING SCIENCE , 2025 , 311 . |
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There is a particular demand to explore low-volatility and structurally tunable absorbents for efficiency, selectivity and reversibility in capturing H2S. For the first time, the performance of deep eutectic solvents (DESs) composed of 1-ethyl-3-methylimidazolium chloride ([Emim]Cl) and acetamide (AA) were examined as physical absorbents for H2S capture. The physical properties of [Emim]Cl-AA DESs, and solubilities of both H2S and CO2 in them were measured. Relevant experimental results demonstrated that the solubilities of H2S in [Emim]Cl-AA DESs (1.1 mol/kg at 298.2 K and 1.023 bar) significantly exceed those of CO2 (0.040 mol/kg at 298.2 K and 1.027 bar). [Emim]Cl-AA DESs exhibit higher H2S solubilities and superior ideal H2S to CO2 selectivities (e.g., the ideal H2S/CO2 selectivity of [Emim]Cl-AA (1:0.5) is 28.5 at 298.2 K) than those physical absorbents ever reported. The recyclability of [Emim]Cl-AA DESs for H2S selective capture was also evaluated, which was found to be very stable in ten continuous absorption and regeneration cycle experiments. The mechanism of H2S capture by [Emim]Cl-AA DESs was finally illustrated at the molecular level with the support of theoretical calculations.
Keyword ：
Absorption selectivity Absorption selectivity Deep eutectic solvent Deep eutectic solvent H2S capture H2S capture Physical solvent Physical solvent Theoretical calculation Theoretical calculation
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| GB/T 7714 | Zheng, Lu , Li, Xiong , Cao, Yanning et al. Efficient, selective and reversible capture of hydrogen sulfide by [Emim] Cl-Acetamide deep eutectic solvents [J]. | JOURNAL OF MOLECULAR LIQUIDS , 2024 , 413 . |
| MLA | Zheng, Lu et al. "Efficient, selective and reversible capture of hydrogen sulfide by [Emim] Cl-Acetamide deep eutectic solvents" . | JOURNAL OF MOLECULAR LIQUIDS 413 (2024) . |
| APA | Zheng, Lu , Li, Xiong , Cao, Yanning , Ma, Yongde , Zhang, Hongwei , Cai, Zhenping et al. Efficient, selective and reversible capture of hydrogen sulfide by [Emim] Cl-Acetamide deep eutectic solvents . | JOURNAL OF MOLECULAR LIQUIDS , 2024 , 413 . |
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The design of novel practical catalysts is critical for the blossoming of biodiesel green-energy, in which Mo-based catalysts are of particular interest. In this work, an in-situ synthesis method was proposed to obtain a combo Mo-based ionic liquid and SAPO-11 catalyst. The catalyst presents both highly dispersed MoS2 as hydrodeoxygenation active sites and acidic sites for isomerization. MoS2 with a few fine layers can be identified based on TEM images and the Bronsted acid sites are dominant based on Pyridine-IR analysis. A great performance of MoS2/C(8)min-15 %SA can be obtained under optimized reaction conditions with 100 % conversion of methyl palmitate, 75.0 mol% hydrodeoxygenation to n-C-15-C-16, and 20.5 mol % isomerization to i-C-15-C-16. The structure and activity of the catalyst can be retained at least for 4 cycles. Thin layers and high sulfurization, large amount of Br & oslash;nsted acid sites, and suitable reaction conditions are key points to achieve a significant performance and avoid over cracking and deactivation. On basis of detected intermediates and kinetic data simulations, a complex reaction pathway was proposed and the specific k values for each elementary reaction were provided for the hydrodeoxygenation and isomerization of methyl palmitate.
Keyword ：
Biodiesel Biodiesel Hydrodeoxygenation Hydrodeoxygenation Isomerization Isomerization Methyl palmitate Methyl palmitate MoS2 MoS2 SAPO-11 SAPO-11
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| GB/T 7714 | Ding, Yongxin , Lin, Jun , Yu, Panjie et al. An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization [J]. | FUEL , 2024 , 362 . |
| MLA | Ding, Yongxin et al. "An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization" . | FUEL 362 (2024) . |
| APA | Ding, Yongxin , Lin, Jun , Yu, Panjie , Zhang, Hongwei , Ma, Yongde , Cai, Zhenping et al. An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization . | FUEL , 2024 , 362 . |
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The efficient deoxygenation of renewable biolipids into liquid alkanes within the diesel range is a key protocol for producing high-quality biofuels. In this work, the conversion of methyl palmitate and raw palm oil were accomplished utilizing a bifunctional catalyst of Ni catalysts supported on B2O3-ZrO2 under solvent-free conditions. Among various Ni loading ratios investigated, the catalyst featuring a 10 % Ni loading achieved 100 % conversion of methyl palmitate and 84.4 % of liquid yield, with approximately 65 % being C15 alkanes. Additionally, more than 91 % of hydrocarbons were also generated from raw palm oil. These results can be attributed to the synergistic interplay between the acid sites, following B2O3 modification, and the presence of Ni species. Furthermore, the analysis of product distribution, gas product detection and the kinetics calculation strongly supports that the deoxygenation process of methyl palmitate primarily follows the hydrodecarbonylation route, leading to the predominant formation of C15 alkane.
Keyword ：
Bifunctional catalyst Bifunctional catalyst Biodiesel Biodiesel Deoxygenation Deoxygenation Liquid alkanes Liquid alkanes Methyl palmitate Methyl palmitate
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| GB/T 7714 | Yu, Panjie , Xu, Jing , Liang, Rengan et al. Solvent-free deoxygenation of biolipid into liquid alkanes over bifunctional Ni/B2O3-ZrO2 catalyst [J]. | FUEL , 2024 , 375 . |
| MLA | Yu, Panjie et al. "Solvent-free deoxygenation of biolipid into liquid alkanes over bifunctional Ni/B2O3-ZrO2 catalyst" . | FUEL 375 (2024) . |
| APA | Yu, Panjie , Xu, Jing , Liang, Rengan , Cai, Zhenping , Ma, Yongde , Zhang, Hongwei et al. Solvent-free deoxygenation of biolipid into liquid alkanes over bifunctional Ni/B2O3-ZrO2 catalyst . | FUEL , 2024 , 375 . |
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In this work, an oil-soluble ionic liquid (IL) was combined with mixed metal oxide for in situ generation of bifunctional catalysts for slurry-phase heavy oil hydrocracking. The oil-soluble IL selected was trihexylmethylammonium molybdate ([N-6661](2)MoO4), and the mixed metal oxide selected was SiO2-ZrO2. The performance of using [N-6661](2)MoO4 and SiO2-ZrO2 for slurry-phase hydrocracking was examined systematically. It is found that the addition of SiO2-ZrO2 can significantly improve the conversion of residue to distillate and the gas and coke yields are also improved. The MoS2/SiO2-ZrO2 bifunctional catalysts in situ generated in the reaction system were collected for detailed characterizations. The MoS2 slabs are in a highly dispersed and sulfurized status in the matrix of SiO2-ZrO2, and there are also abundant acidic sites in resultant bifunctional catalysts. The kinetics of slurry-phase hydrocracking was further investigated to disclose the reaction routes for the conversion of residue and the role of adding SiO2-ZrO2 in promoting the hydrocracking reactions.
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| GB/T 7714 | Ma, Yongde , Wu, Wenquan , Zhang, Jiayin et al. Slurry-Phase Hydrocracking of Heavy Oil with Bifunctional Catalysts In Situ Generated from Oil-Soluble Ionic Liquid and Mixed Metal Oxide [J]. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2023 , 62 (38) : 15459-15468 . |
| MLA | Ma, Yongde et al. "Slurry-Phase Hydrocracking of Heavy Oil with Bifunctional Catalysts In Situ Generated from Oil-Soluble Ionic Liquid and Mixed Metal Oxide" . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 62 . 38 (2023) : 15459-15468 . |
| APA | Ma, Yongde , Wu, Wenquan , Zhang, Jiayin , Zhang, Hongwei , Cai, Zhenping , Cao, Yanning et al. Slurry-Phase Hydrocracking of Heavy Oil with Bifunctional Catalysts In Situ Generated from Oil-Soluble Ionic Liquid and Mixed Metal Oxide . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2023 , 62 (38) , 15459-15468 . |
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Dispersed metal sulfides are promising catalysts for the hydroconversion of biolipids to produce second-generation biodiesel. In this work, oil-soluble Mo-based ionic liquids (ILs) were innovatively utilized as the precursors for in situ generation of MoS2 catalysts for the hydroconversion of biolipids. Taking methyl palmitate as the model compound, the excellent activity of in situ generated MoS2 from ionic liquid Mo-based precursors was obtained. The turnover frequencies (TOFs) reached up to 1.6 x 102 h-1 for methyl palmitate conversion and 83 h-1 for hexadecane (C16) yield at 320 degrees C and 0.5 h (42% conversion) under solvent-dilute conditions. The structures of in situ generated MoS2 catalysts were characterized to pro-vide explanations for the catalytic results. Based on the product distributions, the pathway of methyl palmitate hydroconversion was proposed, and the kinetics of methyl palmitate hydroconversion was analyzed in further detail. Applying the Mo-based ILs in the hydroconversion of methyl palmitate and palm oil under solvent-free condition also granted high conversions of feeds and selectivities of HDO products.(c) 2023 Elsevier Inc. All rights reserved.
Keyword ：
Biodiesel Biodiesel Dispersed catalyst Dispersed catalyst Hydrodeoxygenation Hydrodeoxygenation Ionic liquid Ionic liquid Kinetics Kinetics
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| GB/T 7714 | Cai, Zhenping , Ding, Yongxin , Zhang, Jiayin et al. In situ generation of dispersed MoS2 catalysts from oil-soluble Mo-based ionic liquids for highly effective biolipids hydrodeoxygenation [J]. | JOURNAL OF CATALYSIS , 2023 , 423 : 50-61 . |
| MLA | Cai, Zhenping et al. "In situ generation of dispersed MoS2 catalysts from oil-soluble Mo-based ionic liquids for highly effective biolipids hydrodeoxygenation" . | JOURNAL OF CATALYSIS 423 (2023) : 50-61 . |
| APA | Cai, Zhenping , Ding, Yongxin , Zhang, Jiayin , Yu, Panjie , Ma, Yongde , Cao, Yanning et al. In situ generation of dispersed MoS2 catalysts from oil-soluble Mo-based ionic liquids for highly effective biolipids hydrodeoxygenation . | JOURNAL OF CATALYSIS , 2023 , 423 , 50-61 . |
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Solid adsorbents with high NH3 separation performance and good stability are particularly important for industrial applications. In our work, few-layered hexagonal boron nitrides (h-BNs) were synthesized and proposed as a kind of solid adsorbent by utilizing the abundant Lewis acidic B atoms on h-BNs. The synthesized h-BNs were investigated for NH3 separation both experimentally and theoretically. It is found that the NH3 isotherms of h-BNs slightly deviate from the ideal profiles, suggesting that the h-BNs enable moderate interactions with NH3. At the pressure of 0.1 and 1 bar, the h-BNs can adsorb as much as 2.33 and 8.67 mmol/g of NH3, respectively. The h-BNs also demonstrate highly selective adsorption of NH3 from other gases such as N2, H2, and CO2, regardless of calculated ideal selectivities or breakthrough adsorption of mixed gases. The NH3 adsorption of h-BNs can be completely reversed, and the h-BNs also exhibit high oxidative resistance, which is of vital importance for the long-term application in industry. Density functional theory calculations and molecular dynamics simulations were further conducted to rationalize the effective separation of NH3 by h-BNs and disclose the underlying mechanism at the molecular level.
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| GB/T 7714 | Zhang, Jiayin , Cao, Yanning , Ding, Fengyun et al. Few-Layered Hexagonal Boron Nitrides as Highly Effective and Stable Solid Adsorbents for Ammonia Separation [J]. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2023 . |
| MLA | Zhang, Jiayin et al. "Few-Layered Hexagonal Boron Nitrides as Highly Effective and Stable Solid Adsorbents for Ammonia Separation" . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2023) . |
| APA | Zhang, Jiayin , Cao, Yanning , Ding, Fengyun , Zheng, Lu , Ma, Yongde , Cai, Zhenping et al. Few-Layered Hexagonal Boron Nitrides as Highly Effective and Stable Solid Adsorbents for Ammonia Separation . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2023 . |
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Renewable fatty esters are a class of clean feedstock to produce high value-added fatty alcohols. Herein, the hydrogenation of methyl palmitate (MP) to hexadecanol over defect-rich Cu/m-ZrO2 catalysts was studied systematically. A series of Cu/m-ZrO2 catalysts with different concentrations of oxygen vacancies (Ovs) were fabricated by adjusting the calcination temperature of m-ZrO2 support. Among the catalysts, Cu/m-ZrO2-350 displays the highest Cu dispersion, the largest number of Cu0 sites and surface Ov concentration, which exhibits the best activity for MP hydrogenation. It gives the MP conversion of 94.6% and hexadecanol yield of 93.3% at 300 degrees C and 7.5 MPa of H2. Spectroscopic characterizations and theoretical calculations revealed that the highly dispersed Cu species and abundant Ov sites synergistically boost the hydrogenation of MP. Specifically, the Cu0 sites facilitate the heterolysis of H2, and the Ov sites contribute to the dissociation of MP. The synergistic effect of Cu species and Ov sites disclosed in this work provides deep insights into the design of catalysts for efficient conversion of fatty esters to fatty alcohols.
Keyword ：
Cu catalyst Cu catalyst fatty alcohol fatty alcohol fatty ester fatty ester hydrogenation hydrogenation oxygen vacancy oxygen vacancy
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| GB/T 7714 | Zheng, Xiaohai , Yu, Panjie , Liu, Yaxin et al. Efficient Hydrogenation of Methyl Palmitate to Hexadecanol over Cu/m-ZrO2 Catalysts: Synergistic Effect of Cu Species and Oxygen Vacancies [J]. | ACS CATALYSIS , 2023 : 2047-2060 . |
| MLA | Zheng, Xiaohai et al. "Efficient Hydrogenation of Methyl Palmitate to Hexadecanol over Cu/m-ZrO2 Catalysts: Synergistic Effect of Cu Species and Oxygen Vacancies" . | ACS CATALYSIS (2023) : 2047-2060 . |
| APA | Zheng, Xiaohai , Yu, Panjie , Liu, Yaxin , Ma, Yongde , Cao, Yanning , Cai, Zhenping et al. Efficient Hydrogenation of Methyl Palmitate to Hexadecanol over Cu/m-ZrO2 Catalysts: Synergistic Effect of Cu Species and Oxygen Vacancies . | ACS CATALYSIS , 2023 , 2047-2060 . |
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本发明公开了一种过渡金属掺杂的杂多酸离子液体及其制备方法与应用，其是以杂多酸、过渡金属盐和离子液体为原料，经离子交换制得过渡金属掺杂的油溶性杂多酸离子液体。本发明所得过渡金属掺杂的杂多酸离子液体经原位硫化后具有很高的生物质油转化率和烃类选择性，可实现在温和条件下对棕榈油、植物油等生物质油的加氢脱氧过程，解决了现有生物质油加氢脱氧过程中反应条件苛刻，能耗高，催化剂易失活的问题。
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| GB/T 7714 | 曹彦宁 , 丁永鑫 , 蔡镇平 et al. 一种过渡金属掺杂的杂多酸离子液体及其制备方法与应用 : CN202210663037.7[P]. | 2022-06-13 00:00:00 . |
| MLA | 曹彦宁 et al. "一种过渡金属掺杂的杂多酸离子液体及其制备方法与应用" : CN202210663037.7. | 2022-06-13 00:00:00 . |
| APA | 曹彦宁 , 丁永鑫 , 蔡镇平 , 江莉龙 , 黄宽 , 马永德 . 一种过渡金属掺杂的杂多酸离子液体及其制备方法与应用 : CN202210663037.7. | 2022-06-13 00:00:00 . |
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