The　use　of　renewable　electricity　to　electrooxidize　the　biomass　feedstock　glucose　and　convert　it　into　valuable　chemicals,　combined　with　water　electrolysis　to　produce　hydrogen,　promises　to　achieve　carbon　neutrality　and　provide　alternative　energy　storage　solutions.　However,　the　commercial　viability　of　glucose　electrooxidation　reaction　(GOR)　to　produce　lactic　acid　(LA)　and　formic　acid　(FA)　remains　challenging　due　to　low　selectivity　and　poor　long-term　stability.　Herein,　a　novel　bifunctional　catalyst　(Pt/Ni-NC),　was　successfully　developed　by　embedding　Ni　into　nitrogen-doped　hollow　carbon　spheres　and　incorporating　low　levels　of　Pt.　The　catalyst　exhibited　excellent　performance　for　glucose　electrooxidation,　selectively　producing　lactic　acid　(with　a　yield　of　59.3　%)　and　formic　acid　(with　a　yield　of　35.2　%),　as　well　as　for　hydrogen　evolution　in　an　integrated　electrolytic　system.　The　glucose　electrolytic　cell　operated　at　a　lower　voltage　(only　1.45　V　at　10　mA　cm−2)　than　conventional　water　splitting,　achieving　significant　yields　of　LA　and　FA.　Density　functional　theory　(DFT)　calculations　provided　insights　into　the　mechanism,　revealing　that　Pt　doping　facilitated　electron　transfer,　enhancing　glucose　molecule　activation　and　promoting　the　conversion　of　intermediates　through　a　thermodynamically　favorable　pathway.　Overall,　this　work　highlights　a　promising　strategy　for　coupling　biomass　conversion　with　hydrogen　production,　contributing　to　the　development　of　sustainable　energy　and　chemical　processes.　©　2025