Silicon　(Si)　has　gained　popularity　as　a　potential　anodic　material　for　Li-ion　batteries　(LIBs)　due　to　its　large　theoretical　capacity.　However,　low　conductivity,　large　volume　expansion,　and　side　reactions　during　alloying　and　de-alloying　lead　to　poor　cyclic　and　bad　high-rate　performance,　which　has　severely　hindered　its　practical　large-scale　application.　Herein,　a　novel　stamen-structured　Si-based　anode　material　with　a　protective　SiOx　layer　and　dual　carbon　layers　(Si@SiOx/C@C)　is　designed　for　high-performance　LIBs.　The　protective　SiOx　layer　reduces　side　reactions　and　dual　carbon　layers　enhance　charge　transport　to　improve　reaction　kinetics,　while　the　unique　structure　provides　buffering　space　for　volume　expansion.　Such　Si@SiOx/C@C　anode　demonstrates　impressive　Li　storage　properties　for　a　half-battery,　including　a　discharge　capacity　of　2935　mA　h　g−1　at　a　current　density　0.1　A　g−1,　cyclic　performance　(814　mA　h　g−1　at　2　A　g−1　over　500　cycles　and　988　mA　h　g−1　over　200　cycles　at　1　A　g−1)　and　a　rate　performance　(609　mA　h　g−1　at　5　A　g−1).　It　also　maintains　a　high　reversible　capacity　of　131　mA　h　g−1　at　0.25　C　after　100　cycles　for　a　full　battery.　This　work　provides　insights　into　the　novel　design　of　multiple　protective　layers　on　Si-based　anode　materials　for　fast-charging　and　highly　stable　LIBs.　©　2025　Science　Press