A chiral MOF membrane for enantioselective amino acid separation - Details

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author：

Xu, J. (Xu, J..) ^[1] | Zhang, J. (Zhang, J..) ^[2] | Zhang, W. (Zhang, W..) ^[3] | Xie, S. (Xie, S..) ^[4] | Zhang, L. (Zhang, L..) ^[5]

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Abstract：

A　chiral　metal-organic　framework　membrane　was　constructed　through　coordination　between　copper　ions　and　R/S-tryptophan.　The　membrane　exhibits　exceptional　enantioselectivity　towards　amino　acids　(ee　value:　99.38%)　through　synergistic　effects　of　hydrogen　bonding　and　spatial　hindrance.　This　strategy　demonstrates　the　potential　of　amino　acid-based　chiral　centers　for　high-performance　separation　membranes.　©　2025　The　Royal　Society　of　Chemistry.

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[ 1 ] [Xu J.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Province Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350116, China
[ 2 ] [Zhang J.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Province Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350116, China
[ 3 ] [Zhang W.]Department of Chemistry and Biotechnology, Minjiang Teachers College, Fujian, Fuzhou, 350108, China
[ 4 ] [Xie S.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Province Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350116, China
[ 5 ] [Zhang L.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Province Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350116, China

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Chemical Communications

ISSN： 1359-7345

Year： 2025

Issue： 44

Volume： 61

Page： 8015-8018

4 . 3 0 0

JCR@2023

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 3

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