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author:

Dong, X. (Dong, X..) [1] | Lu, Y. (Lu, Y..) [2] | Gong, X. (Gong, X..) [3] | Liu, L. (Liu, L..) [4] | Yuan, F. (Yuan, F..) [5] | Huang, Y. (Huang, Y..) [6] | Zhang, L. (Zhang, L..) [7] | Lin, Z. (Lin, Z..) [8]

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Scopus

Abstract:

The development of high-performance near-infrared (NIR) phosphor-converted LEDs (pc-LEDs) demands phosphors that exhibit broadband emission, high quantum yield, and excellent thermal stability—a combination that is rarely achieved in existing systems. Herein, we report a novel Cr3+-activated Y3MgAl3SiO12 (YMASO) phosphor synthesized via an efficient sol-gel route. Crystal field analysis reveals the coexistence of Cr3+ ions in both strong-field [AlO6] and weak-field [MgO6] octahedra, facilitating broadband emission with a full width at half maximum (FWHM) of 167 nm through dual-site engineering. The optimized YMASO:0.015Cr exhibits a remarkable internal quantum efficiency of 92.73 % and demonstrates favorable thermal stability. When integrated with a 410 nm blue LED chip, the fabricated NIR pc-LED achieves an output power of 27.55 mW and a photoelectric conversion efficiency of 8.7 % at 100 mA, surpassing most reported chromium (Cr3+)-based systems. This positions YMASO:Cr as a promising candidate for high-efficiency NIR pc-LED applications. © 2025 Elsevier B.V.

Keyword:

High-efficiency pc-LEDs phosphors Near-infrared phosphor Sol-gel method Y3MgAl3SiO12 phosphor

Community:

  • [ 1 ] [Dong X.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Dong X.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Dong X.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 4 ] [Lu Y.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Lu Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Lu Y.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 7 ] [Gong X.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 8 ] [Gong X.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 9 ] [Liu L.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 10 ] [Liu L.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 11 ] [Liu L.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 12 ] [Yuan F.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 13 ] [Yuan F.]Xiamen Tungsten Co., Ltd, Xiamen, 361000, China
  • [ 14 ] [Yuan F.]Rare Earth Advanced Materials Technology Innovation Center, Baotou, 014030, China
  • [ 15 ] [Huang Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 16 ] [Huang Y.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 17 ] [Zhang L.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 18 ] [Zhang L.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 19 ] [Zhang L.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 20 ] [Lin Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 21 ] [Lin Z.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2025

Volume: 1032

5 . 8 0 0

JCR@2023

Cited Count:

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ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 1

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