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author:

Huang, Y. (Huang, Y..) [1] | Huang, J. (Huang, J..) [2] | Wang, P. (Wang, P..) [3] | Liao, S. (Liao, S..) [4]

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Abstract:

In this study, a visible-light-mediated two-component β-fluoro-fluorosulfonamidation reaction of styrenes is demonstrated. The bench-stable reagent, N-fluorosulfamoyl-pyridinium tetrafluoroborate can be used as a photoredox-active nitrogen-centered radical precursor and also as the fluoride source. This transformation can convert a series of styrenes to functional group-enriched products, including substrates with electron-donating or withdrawing groups, as well as di- and tri-substituents on the CC double bond. © 2025 Wiley-VCH GmbH.

Keyword:

fluorination fluorosulfamidation photoredox catalysis radical reactions sulfamoyl fluorides

Community:

  • [ 1 ] [Huang Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Huang Y.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 3 ] [Huang J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Huang J.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 5 ] [Wang P.]Key Laboratory of Green and Precise Synthetic Chemistry and Application, Ministry of Education, College of Chemistry and Materials Science, Huaibei Normal University, Anhui, Huaibei, 235000, China
  • [ 6 ] [Liao S.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China

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Source :

European Journal of Organic Chemistry

ISSN: 1434-193X

Year: 2025

Issue: 22

Volume: 28

2 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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