Microwave　absorption　and　thermal　conductivity　compatibility　are　difficult　to　achieve　because　of　the　inevitable　significant　electromagnetic　interference,　heat　buildup,　and　impedance　mismatch　and　decreased　heat　transfer　efficiency　caused　by　the　lightweighting　and　integration　of　electronic　equipment.　In　this　research,　a　polyacrylamide　(PAM)-based　bifunctional　organogel　with　both　microwave　absorption　and　thermal　conductivity　was　created　by　employing　Co-MOF-74　derivatives　as　basic　fillers　and　increasing　interfacial　polarization　and　conduction　loss　with　the　addition　of　MWCNT.　The　inclusion　of　MWCNT　improved　the　conductive　loss,　and　the　loading　of　MWCNT　with　MOF　derivatives　extended　the　heterogeneous　interface,　resulting　in　the　homogeneous　distribution　of　magnetic　nanoparticles　and　the　formation　of　a　magnetic　coupling　network,　which　increases　magnetic　loss　capacity.　The　Co/C-MWCNT@PDA/PAM　gel　has　a　packing　of　10　wt%　in　the　frequency　range　of　2–18　GHz　and　an　RLmin　of　−59.3　dB　at　a　matched　thickness　of　2　mm.　In　addition,　the　magnetic　orientation　on　MOF　derivatives　aligned　the　fillers　in　the　polymer　matrix　to　produce　high-efficiency　thermal　conductive　pathways.　The　potential　of　MOF　derivatives　and　polymers　as　bifunctional　gels　for　thermal　conductivity　and　electromagnetic　wave　absorption　is　highlighted　in　this　work.　©　2025　Elsevier　B.V.