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author:

Su, Wenze (Su, Wenze.) [1] | Lu, Jiahao (Lu, Jiahao.) [2] | Xiao, Lei (Xiao, Lei.) [3] | Fu, Gang (Fu, Gang.) [4] | Shi, Dawei (Shi, Dawei.) [5] | Wang, Chen (Wang, Chen.) [6] | Yu, Zhiyang (Yu, Zhiyang.) [7] | Wu, Peng (Wu, Peng.) [8]

Indexed by:

EI

Abstract:

In this work, efficient grain boundary diffusion (GBD) of Tb can be achieved in fine-grained sintered Nd-Fe-B magnet through the addition of Zr. The magnets were prepared using Nd-Fe-B powder with an average particle size of 2.6 μm. Compared with the magnet without Zr addition, the intrinsic coercivity of the Zr-added magnet increases by 3.55 kOe after GBD with the increment of 15.0 %, and the squareness of the demagnetization curve is improved by 5.7 %. The Zr element can combine with the C element in the magnet to form block-like ZrC precipitates, which inhibits the formation of harmful rare-earth carbon phase and reduces the ineffective depletion of rare earth elements. In addition, the Zr element can also combine with the B element to form needle-like ZrB2 precipitates. The consumption of B element increases the volume fraction of RE-rich phase, thus providing more liquid-phase channels for the diffusion of Tb. The ZrC and ZrB2 precipitates distributed at the grain boundary (GB) can broaden the width of the GB phase, which not only provide broader channels for Tb diffusion, but also improve the magnetic isolation of the main phase grains. By the addition of Zr, the diffusion depth of Tb in the magnet is increased. Meanwhile, the accumulation of Tb on the diffusion surface of the magnet reduces significantly, and the thin and uniform Tb-rich shell is formed on the exterior of the main phase grains in the magnet. © 2025 Elsevier Inc.

Keyword:

Accelerator magnets Coercive force Iron alloys Liquid phase sintering Neodymium alloys Zirconium powder metallurgy

Community:

  • [ 1 ] [Su, Wenze]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Lu, Jiahao]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Xiao, Lei]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Fu, Gang]Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan; 366300, China
  • [ 5 ] [Shi, Dawei]Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan; 366300, China
  • [ 6 ] [Wang, Chen]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Yu, Zhiyang]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 8 ] [Wu, Peng]College of Chemistry and Materials, Longyan University, Longyan; 364012, China
  • [ 9 ] [Wu, Peng]Longyan Nonferrous Metal Industry Research Institute, Longyan; 364012, China

Reprint 's Address:

  • [wang, chen]college of materials science and engineering, fuzhou university, fuzhou; 350108, china

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Source :

Materials Characterization

ISSN: 1044-5803

Year: 2025

Volume: 224

4 . 8 0 0

JCR@2023

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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