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author:

Hu, Mingqiang (Hu, Mingqiang.) [1] | Ye, Dezhan (Ye, Dezhan.) [2] | Qian, Xing (Qian, Xing.) [3] | Zhan, Yanhu (Zhan, Yanhu.) [4] | Jiang, Xiancai (Jiang, Xiancai.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

Traditional ionic conductive hydrogel was prepared by chemically crosslinking the polymer chains to form network. However, the chemically crosslinked ionic conductive hydrogel usually showed limited elongation at break and high hysteresis during stretching process. Here, a simple strategy of synthesizing fully physically crosslinked ionic conductive supramolecular hydrogel without chemical crosslinker was purposed. Hydrophilic salt not only act as the ion supplier, but also provide the spatial confinement effect to form the completely physically crosslinked hydrogel. Firstly, CaCl2 was used as the representative salt. The optimal PVA/PAM/CaCl2 ionic conductive hydrogel (PPC), showed excellent tensile performance (2400.3 +/- 140.63 %), anti-freezing performance (-28.8 degrees C), high conductivity (4.8 +/- 0.01 S/m), excellent stability at room temperature, low hysteresis, and high transparency. The conductivity of PPC showed no sensitivity to the tensile strain. This innovative combination enables PPC ionic conductive hydrogel to have extraordinary versatility. The flexible allsolid-state supercapacitor assembled with PPC ionic conductive hydrogel as the electrolyte has a high area specific capacitance (136.9 mF/cm2). The prepared supercapacitor can maintain good stability under certain tensile deformation (The capacitance retention rate was 87.7 % when stretched at 200 %). Moreover, other high hydrophilic salts including LiCl, ZnCl2, MgCl2 and AlCl3 were used to prepare ionic conductive PVA/PAM hydrogel to verify the universality of this preparation method.

Keyword:

Flexible all-solid-state supercapacitor High strength Poly(vinyl alcohol) Stretchability Supramolecular hydrogel

Community:

  • [ 1 ] [Hu, Mingqiang]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Qian, Xing]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Jiang, Xiancai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Ye, Dezhan]Wuhan Text Univ, State Key Lab New Text Mat & Adv Proc Technol, Wuhan 430200, Peoples R China
  • [ 5 ] [Zhan, Yanhu]Liaocheng Univ, Sch Mat Sci & Engn, Liaocheng 252000, Peoples R China

Reprint 's Address:

  • [Qian, Xing]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Peoples R China;;[Jiang, Xiancai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Peoples R China;;[Ye, Dezhan]Wuhan Text Univ, State Key Lab New Text Mat & Adv Proc Technol, Wuhan 430200, Peoples R China

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Source :

POLYMER

ISSN: 0032-3861

Year: 2025

Volume: 327

4 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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