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author：

Bao, T. (Bao, T..) [1] | Wu, Y. (Wu, Y..) [2] | Tang, C. (Tang, C..) [3] | Xi, Y. (Xi, Y..) [4] | Zou, Y. (Zou, Y..) [5] | Shan, P. (Shan, P..) [6] | Zhang, C. (Zhang, C..) [7] | Drożd, W. (Drożd, W..) [8] | Stefankiewicz, A.R. (Stefankiewicz, A.R..) [9] | Yuan, P. (Yuan, P..) [10] | Yu, C. (Yu, C..) [11] | Liu, C. (Liu, C..) [12]

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Abstract：

The　design　of　bifunctional　and　high-performance　electrocatalysts　that　can　be　used　as　both　cathodes　and　anodes　for　the　two-electron　oxygen　reduction　reaction　(2e−　ORR)　and　biomass　valorization　is　attracting　increasing　attention.　Herein,　a　conserved　ligand　replacement　strategy　is　developed　for　the　synthesis　of　highly　ordered　conductive　metal-organic　frameworks　(Ni-HITP,　HITP　=　2,　3,　6,　7,　10,　11-hexaiminotriphenylene)　with　chemically　confined　phosphotungstic　acid　(PW12)　nanoclusters　in　the　nanopores.　The　newly　formed　Ni−O−W　bonds　in　the　resultant　Ni-HITP/PW12　electrocatalysts　modulate　the　electronic　structures　of　both　Ni　and　W　sites,　which　are　favorable　for　cathodic　2e−　ORR　to　H2O2　production　and　anodic　5-hydroxymethylfurfural　oxidation　reaction　(HMFOR)　to　2,　5-furandicarboxylic　acid　(FDCA),　respectively.　In　combination　with　the　deliberately　retained　conductive　frameworks　and　ordered　pores,　the　dual-functional　Ni-HITP/PW12　composites　enable　a　H2O2　production　rate　of　9.51 mol gcat−1 h−1　and　an　FDCA　yield　of　96.8%　at　a　current　density　of　100 mA cm−2/cell　voltage　of　1.38 V　in　an　integrated　2e−　ORR/HMFOR　system,　significantly　improved　than　the　traditional　2e−　ORR/oxygen　evolution　reaction　system.　This　work　has　provided　new　insights　into　the　rational　design　of　advanced　electrocatalysts　and　electrocatalytic　systems　for　the　green　synthesis　of　valuable　chemicals.　©　2025　Wiley-VCH　GmbH.

Keyword：

biomass valorization conductive metal-organic frameworks electrocatalysis polyoxometalates two-electron reduction reaction

Community：

  • [ 1 ] [Bao T.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 2 ] [Wu Y.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 3 ] [Tang C.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 4 ] [Xi Y.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 5 ] [Zou Y.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 6 ] [Shan P.]Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing, 210096, China
  • [ 7 ] [Zhang C.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 8 ] [Drożd W.]Center for Advanced Technologies, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland
  • [ 9 ] [Drożd W.]Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland
  • [ 10 ] [Stefankiewicz A.R.]Center for Advanced Technologies, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland
  • [ 11 ] [Stefankiewicz A.R.]Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland
  • [ 12 ] [Yuan P.]College of Chemical Engineering, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, 350002, China
  • [ 13 ] [Yu C.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 14 ] [Yu C.]State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, East China Normal University, Shanghai, 200062, China
  • [ 15 ] [Yu C.]Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, 4072, QLD, Australia
  • [ 16 ] [Liu C.]School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241, China
  • [ 17 ] [Liu C.]State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, East China Normal University, Shanghai, 200062, China

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Advanced Materials

ISSN： 0935-9648

Year： 2025

2 7 . 4 0 0

JCR@2023

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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