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author:

Hua, Y. (Hua, Y..) [1] | Chen, J. (Chen, J..) [2] | Guo, C. (Guo, C..) [3] | Chen, S.-C. (Chen, S.-C..) [4] | He, Y. (He, Y..) [5] | Yang, H. (Yang, H..) [6]

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Abstract:

In recent years, metal halide perovskites have garnered significant attention in the field of X-ray detection due to their outstanding photoelectric properties, high X-ray attenuation coefficients, and the advantage of being able to be fabricated by low-cost solution processing methods. However, a major challenge in developing perovskite X-ray detectors lies in the low quality of films produced through solution processing. In this work, we introduce an efficient method that employs a straightforward blade-coating technique to successfully prepare MAPbI3 perovskite films with a thickness of tens of microns under ambient conditions. To further improve the quality of the MAPbI3 films, we incorporate the polymer polyvinylpyrrolidone (PVP) into the perovskite precursor solution. The addition of PVP promotes crystal growth, resulting in an enlarged grain size and a more uniform arrangement within the perovskite film. This enhancement leads to a reduction in defect density and subsequent improvement in the charge collection efficiency. Consequently, the detector manufactured using the PVP-optimized film exhibits an enhanced X-ray sensitivity of 2.6 × 103 μC Gyair−1 cm−2 and achieves a low detection limit of 11 nGyair s−1 under 10 keV X-ray energy, surpassing those achieved with the original perovskite film which measured 0.60 × 103 μC Gyair−1 cm−2 and 139 nGyair s−1 under the same conditions. This work unlocks new prospects for the straightforward and cost-effective manufacture of high-performance X-ray detectors. © 2025 The Royal Society of Chemistry.

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  • [ 1 ] [Hua Y.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Chen J.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Guo C.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Chen S.-C.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [He Y.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Yang H.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 7 ] [Yang H.]New Cornerstone Science Laboratory, MOE Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou, 350002, China

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Source :

Journal of Materials Chemistry C

ISSN: 2050-7526

Year: 2025

Issue: 18

Volume: 13

Page: 9365-9373

5 . 7 0 0

JCR@2023

CAS Journal Grade:2

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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