Owing　to　its　distinctive　structure　and　variable　oxidation　states,　Tungstate-based　oxides　have　become　a　high-potential　electrode　material　for　supercapacitors　(SCs).　However,　the　insufficient　active　sites　and　the　slow　kinetics　of　charge　transport　hinder　its　practical　application　in　SCs　fields.　Doping　anion　has　been　demonstrated　to　be　a　feasible　approach　to　improve　the　electrochemical　performance　of　electrode　materials.　Herein,　F-doped　ZnWO4　(denoted　as　F-ZnWO4)　with　nanosheet　arrays　were　synthesized　on　nickel　foam　by　hydrothermal　method.　The　effects　of　doping　F　on　the　microstructure　and　electrochemical　properties　of　F-ZnWO4　are　systematically　studied.　It　provides　additional　ion　transport　channels　for　redox　reactions,　enhances　the　conductivity　of　the　electrode　material,　and　provides　abundant　active　sites,　thereby　promoting　the　charge　transfer　kinetics　of　the　electrode　material.　It　indicates　that　doping　F　can　reshape　the　morphology　of　F-ZnWO4,　expand　the　lattice　spacing　and　induce　some　oxygen　vacancies　(OV).　Compared　with　ZnWO4,　the　Ov　concentrations　of　F-ZnWO4-2　increase　from　20.10　%　to　36.29　%.　F-ZnWO4-2　electrode　has　a　specific　capacitance　of　1450.0　F/g　at　a　current　density　of　1　A/g　and　retains　a　capacitance　of　1353.1　F/g　even　at　a　higher　current　density　of　10　A/g.　The　assembled　F-ZnWO4-2//RuO2-ZnO　asymmetric　supercapacitor　(ASC)　exhibits　an　energy　density　of　37.4　Wh/kg　and　a　corresponding　power　density　of　831.4　W/kg.　Two　series-connected　ASCs　can　lighten　six　LED　lights　for　6　min.　It　provides　a　way　to　further　develop　low-capacitance　metal　oxide　materials　in　the　field　of　electrochemical　energy　storage.　©　2025