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author:

Zhou, Bingxin (Zhou, Bingxin.) [1] | Yang, Zhuo (Yang, Zhuo.) [2] | Lu, Linfang (Lu, Linfang.) [3] | Fang, Baizeng (Fang, Baizeng.) [4] | Wilkinson, David P. (Wilkinson, David P..) [5] | Zhang, Jiujun (Zhang, Jiujun.) [6] | Rao, Zhonghao (Rao, Zhonghao.) [7]

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Abstract:

Lithium metal anode (LMA) corrosion accelerates capacity degradation, increases interfacial resistance, and causes performance failure in all types of LMA-based batteries (LMABs). Given the inevitable calendar aging of batteries, it is imperative to investigate the corresponding lithium corrosion mechanisms and develop tailored mitigation strategies to promote the development and commercialization of LMABs. This review first provides a comprehensive summary of the different types of corrosion in LMABs. In particular, the similarities and differences of lithium anode corrosion between different types of liquid LMABs are analyzed. Secondly, the qualitative and quantitative corrosion characterization methods are summarized, including the characterization techniques, working principles, functions, and limitations. Thirdly, the current corrosion mitigation strategies are categorized and summarized, and their advantages, disadvantages, effectiveness, and applicability are discussed. Finally, the strategies that are highly effective and applicable to different types of LMABs are highlighted and perspectives for further investigation of corrosion are proposed. © 2025 Elsevier Inc.

Keyword:

Community:

  • [ 1 ] [Zhou, Bingxin]School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin; 300401, China
  • [ 2 ] [Yang, Zhuo]School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin; 300401, China
  • [ 3 ] [Lu, Linfang]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Zhejiang, Hangzhou; 311121, China
  • [ 4 ] [Fang, Baizeng]School of Chemical Engineering and Energy Technology, Dongguan University of Technology, Dongguan; 523808, China
  • [ 5 ] [Wilkinson, David P.]Department of Chemical & Biological Engineering, The University of British Columbia, 2360 East Mall, Vancouver; BC; V6T 1Z3, Canada
  • [ 6 ] [Zhang, Jiujun]College of Materials Science and Engineering, Institute of New Energy Materials and Engineering, Fuzhou University, Fujian, Fuzhou; 350108, China
  • [ 7 ] [Rao, Zhonghao]School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin; 300401, China

Reprint 's Address:

  • [fang, baizeng]school of chemical engineering and energy technology, dongguan university of technology, dongguan; 523808, china;;

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Matter

ISSN: 2590-2393

Year: 2025

Issue: 3

Volume: 8

1 8 . 4 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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