Covalent　organic　frameworks　(COFs)　constitute　a　novel　category　of　porous　materials　that　exhibit　considerable　promise　for　photocatalysis,　particularly　in　the　production　of　hydrogen　peroxide　(H2O2).　A　novel　COF　distinguished　by　a　pyrene-anthraquinone　architecture　(denoted　as　Py-DQ-COF)　was　successfully　prepared　through　a　solvothermal　process.　The　pyrene　moiety　acts　as　an　electron-rich　component,　while　the　anthraquinone　moiety　serves　as　its　electron-deficient　counterpart.　The　strategic　integration　of　these　two　moieties　as　essential　building　blocks　in　the　formation　of　a　donor-acceptor　type　Py-DQ-COF　structure　facilitates　the　efficient　separation　of　electron-hole　pairs.　By　employing　benzylamine　as　a　sacrificial　reagent　and　utilizing　water　as　the　solvent,　this　study　meticulously　explores　the　photocatalytic　efficiency　in　the　production　of　H2O2.　Mechanistic　investigations　validate　that　the　reaction　proceeds　through　a　two-step　two-electron　(2e(-))　oxygen　reduction　reaction　pathway,　culminating　in　an　impressive　H2O2　yield　of　15,207　mu　mol　g(-1)　h(-1),　significantly　exceeding　the　yields　associated　with　conventional　sacrificial　alcohols.　Cyclic　experiments　further　elucidate　that　the　materials　exhibit　commendable　stability　and　sustain　high　activity.　This　study　introduces　a　new　method　for　the　identification　of　novel　sacrificial　agents,　and　integrates　anthraquinone　into　COFs,　thereby　offering　an　efficient　strategy　to　optimize　the　industrial　anthraquinone　process　for　H2O2　production.　Ultimately,　it　provides　a　valuable　reference　for　the　advancement　of　efficient　and　sustainable　photocatalytic　systems.