Metal-Organic Frameworks with Phosphonate Monoester Linkers for Catalytic C(sp2)-H Borylation of Alkenes - Details

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Zhong, S.-R. (Zhong, S.-R..) ^[1] | Xie, X.-L. (Xie, X.-L..) ^[2] | Huang, T. (Huang, T..) ^[3] | Zhang, T. (Zhang, T..) ^[4]

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Abstract：

An　isoreticular　metal-organic　framework　(MOF)　series　was　constructed　from　nickel　or　cobalt　nodes,　phosphonate　monoester,　and　bipyridine　linkers.　The　cobalt-containing　MOFs　were　found　to　catalyze　the　dehydrogenative　C-H　borylation　of　alkenes　under　mild　conditions.　This　process　selectively　generates　vinyl　boronate　without　the　formation　of　alkyl　boronate　byproducts　and　is　insensitive　to　air,　enabling　large-scale　preparation　of　the　target　products　with　isolated　yields　of　over　80%.　©　2025　American　Chemical　Society.

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[ 1 ] [Zhong S.-R.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [Zhong S.-R.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 3 ] [Zhong S.-R.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 4 ] [Xie X.-L.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 5 ] [Xie X.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 6 ] [Xie X.-L.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 7 ] [Huang T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 8 ] [Huang T.]University of Chinese Academy of Sciences, Beijing, 100049, China
[ 9 ] [Zhang T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 10 ] [Zhang T.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 11 ] [Zhang T.]University of Chinese Academy of Sciences, Beijing, 100049, China

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Inorganic Chemistry

ISSN： 0020-1669

Year： 2025

Issue： 2

Volume： 64

Page： 801-806

4 . 3 0 0

JCR@2023

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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