Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Lin, W. (Lin, W..) [1] | Chen, J. (Chen, J..) [2] | Zhang, X. (Zhang, X..) [3] | Lin, J. (Lin, J..) [4] | Lin, F. (Lin, F..) [5] | Huang, S. (Huang, S..) [6] | Wang, Y. (Wang, Y..) [7]

Indexed by：

Scopus

Abstract：

N2　reduction　reaction　(NRR)　by　light　is　an　energy-saving　and　sustainable　ammonia　(NH3)　synthesis　technology.　However,　it　faces　significant　challenges,　including　high　energy　barriers　of　N2　activation　and　unclear　catalytic　active　sites.　Herein,　we　propose　a　strategy　of　photo-driven　ammonia　synthesis　via　a　proton-mediated　photoelectrochemical　device.　We　used　redox-catalysis　covalent　organic　framework　(COF),　with　a　redox　site　(−C=O)　for　H+　reversible　storage　and　a　catalytic　site　(porphyrin　Au)　for　NRR.　In　the　proton-mediated　photoelectrochemical　device,　the　COF　can　successfully　store　e−　and　H+　generated　by　hydrogen　oxidation　reaction,　forming　COF−H.　Then,　these　stored　e−　and　H+　can　be　used　for　photo-driven　NRR　(108.97　umol　g−1)　under　low　proton　concentration　promoted　by　the　H-bond　network　formed　between　−OH　in　COF−H　and　N2　on　Au,　which　enabled　N2　hydrogenation　and　NH3　production,　establishing　basis　for　advancing　artificial　photosynthesis　and　enhancing　ammonia　synthesis　technology.　©　2025　Wiley-VCH　GmbH.

Keyword：

Covalent organic framework N2 reduction reaction Photo-driven ammonia synthesis Photoelectrochemical device Proton-mediated

Community：

  • [ 1 ] [Lin W.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 2 ] [Lin W.]University of Chinese Academy of Sciences, Beijing, 100049, China
  • [ 3 ] [Lin W.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 4 ] [Chen J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 5 ] [Chen J.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350116, China
  • [ 6 ] [Zhang X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 7 ] [Zhang X.]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China
  • [ 8 ] [Lin J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Lin J.]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China
  • [ 10 ] [Lin F.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 11 ] [Lin F.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China
  • [ 12 ] [Huang S.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 13 ] [Huang S.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China
  • [ 14 ] [Wang Y.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 15 ] [Wang Y.]University of Chinese Academy of Sciences, Beijing, 100049, China
  • [ 16 ] [Wang Y.]Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China
  • [ 17 ] [Wang Y.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

Angewandte Chemie - International Edition

ISSN： 1433-7851

Year： 2025

Issue： 8

Volume： 64

1 6 . 1 0 0

JCR@2023

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 3

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：420/9704577
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1