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Abstract:
The escalating threats posed by industrial wastewater discharge and offshore crude oil spills necessitate the development of cost-effective, environmentally friendly adsorbents. In this study, stearic acid-modified (SA) magnetic porous hydroxyapatite (HAP) microspheres were prepared by hydrothermal synthesis. Abalone shell particles were employed as the calcium source, and Fe3O4 nanoparticles (nFe3O4) or industrial iron tetraoxide particles (Fe3O4) were selected as the magnetic source. The microsphere (SA/nFe3O4-HAP) demonstrated enhanced superhydrophobicity, lipophilicity and increased specific surface area, with an oil absorption capacity of 6.518 g/g. Notably, compared to SA/Fe3O4-HAP, the magnetic particles on SA/nFe3O4-HAP exhibited more even dispersion. The excellent superparamagnetism and hydrophobicity of SA/nFe3O4-HAP facilitated its dispersion in crude oil, enabling efficient magnetic separation. After five cycles, the adsorption efficiency remained high 4.213 g/g, signifying its good recyclability. In conclusion, this environmentally friendly adsorbent demonstrates synergistic efficacy in addressing marine oil spills and discarded shell pollution, offering a potential balance between environmental and economic benefits. © 2025
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Journal of Environmental Chemical Engineering
Year: 2025
Issue: 2
Volume: 13
7 . 4 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 5
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