The　reverse　water-gas　shift　(RWGS)　reaction　is　considered　as　one　of　the　promising　routes　for　converting　greenhouse　gases　into　CO　intermediates　and　subsequently　generating　high-value　products.　However,　CO2　is　difficult　to　activate　at　low　temperatures　and　tends　to　form　by-product　CH4,　resulting　in　poor　conversion　and　selectivity.　In　this　work,　a　targeted　strategy　was　developed　to　oriented　deposite　Pt　components　on　in-situ　constructed　CeZrOx　interfaces.　Due　to　the　dispersion　and　anchoring　effect　derived　from　the　oxygen　vacancies　of　the　CeZrOx　interface,　the　supported　Pt　sites　were　dominantly　existed　as　low-nuclearity　configuration.　Moreover,　the　defect-enriched　interface　showed　exceptional　electron　donation　to　Pt　sites　(Pt　delta-　species)　via　an　electronic　metal-support　interaction　(EMSI),　which　was　endowed　with　stronger　H　dissociation　properties.　Combined　with　the　superior　ability　for　the　activation　of　CO2　over　oxygen　vacancies　at　CeZrOx　interface,　the　catalytic　performance　of　low-temperature　RWGS　reaction　was　synergistically　improved.