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author:

Fu, H. (Fu, H..) [1] | Chen, Y. (Chen, Y..) [2] | Zhang, T. (Zhang, T..) [3] | Wang, X. (Wang, X..) [4] | Zhang, S. (Zhang, S..) [5] | Huang, J. (Huang, J..) [6] | Zhang, D. (Zhang, D..) [7] | Qian, X. (Qian, X..) [8] | Lai, Y. (Lai, Y..) [9]

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Abstract:

The frequent occurrence of oil spills not only results in the waste of petroleum resources, but also poses a serious threat to the marine ecological environment. Considering the large amount of crude oils with high viscosity, it is urgent to develop a sorbent capable of efficiently reducing the viscosity for the cleanup of oil spills. Inspired by the “lotus effect” and “poikilotherm which utilize the solar energy for thermoregulation”, the low surface energy material polydimethylsiloxane (PDMS) and polypyrrole (PPy) were loaded over the island nonwoven fabric to fabricate a novel crude oil sorbent material. The nonwoven fabric achieved an efficient photothermal conversion. Wherein, the fluorine-free PDMS was used to hydrophobically modify the nonwoven fabric, endowing it with excellent oil-water separation performance, with a separation efficiency of up to 95%. After 10 cycles, the separation efficiency of PPy/PDMS modified nonwoven fabric (PPy/PDMS@NF) was still above 90%, demonstrating superior recyclability. In addition, the PPy/PDMS@NF possessed the self-cleaning capabilities. Under light conditions, the PPy/PDMS@NF was rapidly heated up, reducing the viscosity of crude oil and enabling the effective recovery of oil spills. Under one sun illumination (1.0 kW·m–2), the surface temperature of the PPy/PDMS@NF reached 60.7 °C, and its sorption capacity for high-viscosity crude oil reached 7 gcrude oil·gsorbent–1. Thanks to its environmental friendliness and excellent sorption capacity, this work provides a new option for dealing with the high-viscosity marine oil spills. © 2024 SIOC, CAS, Shanghai, & WILEY-VCH GmbH.

Keyword:

Bionics Crude oil sorption Hydrophobic effect Multifunctional Nonwoven fabric Oil-water separation Photothermal conversion Self-cleaning

Community:

  • [ 1 ] [Fu H.]State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes/Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China
  • [ 2 ] [Fu H.]Huafon Microfibre (Jiangsu) Co., Ltd., Jiangsu, Nantong, 226000, China
  • [ 3 ] [Chen Y.]State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes/Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China
  • [ 4 ] [Zhang T.]State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes/Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China
  • [ 5 ] [Wang X.]Jiangxi Center for Modern Apparel Engineering and Technology, Jiangxi Institute of Fashion Technology, Jiangxi, Nanchang, 330201, China
  • [ 6 ] [Zhang S.]State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes/Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China
  • [ 7 ] [Huang J.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou, 350116, China
  • [ 8 ] [Zhang D.]School of Chemical Engineering and Technology, Tiangong University, Tianjin, 300387, China
  • [ 9 ] [Qian X.]State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes/Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China
  • [ 10 ] [Lai Y.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou, 350116, China

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Source :

Chinese Journal of Chemistry

ISSN: 1001-604X

Year: 2024

Issue: 7

Volume: 43

Page: 759-768

5 . 5 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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