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author:

Dong, P. (Dong, P..) [1] | Wu, H. (Wu, H..) [2] | Luo, L. (Luo, L..) [3] | Cui, Q. (Cui, Q..) [4] | Li, T. (Li, T..) [5] | Shi, J. (Shi, J..) [6] | Yue, Y. (Yue, Y..) [7]

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Scopus

Abstract:

A low-cost and process-intensified synthesis approach of SSZ-35 zeolite via a seed-assisted method is presented. This approach involves the development of a relatively inexpensive template and the application of seeds to minimize crystallization time and template consumption. Herein, N-Ethyl, N-methyl 2,6-cis-dimethylpiperidinium hydroxide (EMDMPOH) is selected as a template to synthesize SSZ-35 zeolite, and a simplified and optimized scheme for the preparation of such a template is proposed. Specially, the high-purity EMDMPOH is prepared by a sequential alkylation of 2,6-dimethylpiperidine with iodoethane and iodomethane, followed by ion exchange. By employing a seed-assisted strategy, the synthesis process of SSZ-35 zeolite is intensified, resulting in a significant reduction in crystallization time from 7 d to 75 h. Systematic characterizations reveal that the synthesized SSZ-35 zeolite has smaller crystals and larger specific surface area in comparison with the reference sample, leading to enhanced selectivity in n-octane hydroisomerization. Moreover, the cost accounting analysis shows a notable decrease in the synthesis cost of SSZ-35 zeolite by using the synthesis route that combines the simplified process for preparing the template and the reduced amount of template. © 2024

Keyword:

Crystallization intensification Low-cost synthesis Seed-assisted method SSZ-35 zeolite

Community:

  • [ 1 ] [Dong P.]Qingyuan Innovation Laboratory, Fujian Province, Quanzhou, 362801, China
  • [ 2 ] [Wu H.]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Luo L.]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Cui Q.]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Li T.]Qingyuan Innovation Laboratory, Fujian Province, Quanzhou, 362801, China
  • [ 6 ] [Li T.]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 7 ] [Shi J.]Qingyuan Innovation Laboratory, Fujian Province, Quanzhou, 362801, China
  • [ 8 ] [Yue Y.]Qingyuan Innovation Laboratory, Fujian Province, Quanzhou, 362801, China
  • [ 9 ] [Yue Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fuzhou, 350002, China

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Source :

Chemical Engineering and Processing - Process Intensification

ISSN: 0255-2701

Year: 2025

Volume: 208

3 . 8 0 0

JCR@2023

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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