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author:

Jiang, Jinlong (Jiang, Jinlong.) [1] | Wang, Didi (Wang, Didi.) [2] | Liu, Huakun (Liu, Huakun.) [3] | Wu, Kuan (Wu, Kuan.) [4] | Yang, Xianzhong (Yang, Xianzhong.) [5] | Shi, Yaru (Shi, Yaru.) [6] | Zhao, Bing (Zhao, Bing.) [7] | Jiang, Yong (Jiang, Yong.) [8] | Sun, Xueliang (Sun, Xueliang.) [9] | Zhang, Jiujun (Zhang, Jiujun.) [10] (Scholars:张久俊) | Dou, Shixue (Dou, Shixue.) [11] | Wu, Chao (Wu, Chao.) [12]

Indexed by:

EI Scopus SCIE

Abstract:

Localized deposition behavior tends to induce the growth of lithium dendrite and hinder the the full utilization of lithium storage space, significantly impeding the practical application of 3D conductive hosts. Here, a novel synchronous deposition mode is proposed for the first time through hierarchical structure design of 3D Li host. The top-down gradually enhanced lithiophilicity and conductivity of 3D scaffold provide sufficient driving force for Li+ to migrate downward, promoting synchronous Li deposition within the entire space of the host. Notably, the novel deposition mode has been theoretically and experimentally validated through finite element simulation and in situ optical microscopy, respectively. The meticulously designed strategy not only maximizes the utilization of the entire 3D scaffold space but also prevents the formation of Li dendrites under high current rate. Consequently, the symmetric Li//Li cell exhibits a long-term cycling lifespan over 3700 h with a low overpotential of 15.6 mV, together with a Coulombic efficiency as high as 99.5% over 300 cycles at 3 mA cm-2. The full cell paired with LiFePO4 cathode demonstrates a cycling lifespan of 1000 cycles with a capacity retention rate of 91.6%. The proposed synchronous deposition strategy opens up a new paradigm for the design and construction of 3D hosts for dendrite-free Li metal anode.

Keyword:

3D current collector density functional theory calculations hierarchical lithiophilic scaffolds Li metal anodes synchronous deposition mode

Community:

  • [ 1 ] [Jiang, Jinlong]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 2 ] [Wang, Didi]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 3 ] [Liu, Huakun]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 4 ] [Wu, Kuan]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 5 ] [Yang, Xianzhong]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 6 ] [Dou, Shixue]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 7 ] [Wu, Chao]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China
  • [ 8 ] [Jiang, Jinlong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 9 ] [Shi, Yaru]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 10 ] [Zhao, Bing]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 11 ] [Jiang, Yong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 12 ] [Sun, Xueliang]Fuzhou Univ, Inst New Energy Mat & Engn, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 13 ] [Zhang, Jiujun]Fuzhou Univ, Inst New Energy Mat & Engn, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Wu, Chao]Univ Shanghai Sci & Technol, Inst Energy Mat Sci, Shanghai 200093, Peoples R China;;[Jiang, Yong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2024

1 8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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