Cyano-Fluorosulfonylation of Unactivated Alkenes by Photoredox and Copper Dual Catalysis - Details

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Both　fluorosulfonyl　and　cyano　groups　are　important　structural　motifs　in　bioactive　molecules.　Herein,　we　report　a　new　difunctionalization　reaction　of　alkenes　based　on　fluorosulfonyl　radicals,　which　allows　for　the　introduction　of　the　fluorosulfonyl　and　cyano　groups　into　unactivated　alkenes　in　one　step.　This　transformation　is　enabled　by　merging　photoredox　and　copper　catalysis,　featuring　visible　light　catalysis,　mild　conditions,　and　good　functional　group　tolerance.　Further　transformation　of　products　via　SuFEx　reactions　is　also　demonstrated.　©　2024　American　Chemical　Society.

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[ 1 ] [Wei R.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Huang Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Huang Y.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
[ 4 ] [Afanasyev O.I.]A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russian Federation
[ 5 ] [Li Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Chusov D.]A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russian Federation
[ 7 ] [Liao S.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 8 ] [Liao S.]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China

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Organic Letters

ISSN： 1523-7060

Year： 2024

4 . 9 0 0

JCR@2023

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